721 research outputs found
Biomass burning and urban air pollution over the Central Mexican Plateau
Observations during the 2006 dry season of highly elevated concentrations of cyanides in the atmosphere above Mexico City (MC) and the surrounding plains demonstrate that biomass burning (BB) significantly impacted air quality in the region. We find that during the period of our measurements, fires contribute more than half of the organic aerosol mass and submicron aerosol scattering, and one third of the enhancement in benzene, reactive nitrogen, and carbon monoxide in the outflow from the plateau. The combination of biomass burning and anthropogenic emissions will affect ozone chemistry in the MC outflow
Analysis of ozone and nitric acid in spring and summer Arctic pollution using aircraft, ground-based, satellite observations and MOZART-4 model: source attribution and partitioning
In this paper, we analyze tropospheric O_3 together with HNO_3 during the POLARCAT (Polar Study using Aircraft, Remote Sensing, Surface Measurements and Models, of Climate, Chemistry, Aerosols, and Transport) program, combining observations and model results. Aircraft observations from the NASA ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) and NOAA ARCPAC (Aerosol, Radiation and Cloud Processes affecting Arctic Climate) campaigns during spring and summer of 2008 are used together with the Model for Ozone and Related Chemical Tracers, version 4 (MOZART-4) to assist in the interpretation of the observations in terms of the source attribution and transport of O_3 and HNO_3 into the Arctic (north of 60Ā° N). The MOZART-4 simulations reproduce the aircraft observations generally well (within 15%), but some discrepancies in the model are identified and discussed. The observed correlation of O_3 with HNO_3 is exploited to evaluate the MOZART-4 model performance for different air mass types (fresh plumes, free troposphere and stratospheric-contaminated air masses).
Based on model simulations of O_3 and HNO_3 tagged by source type and region, we find that the anthropogenic pollution from the Northern Hemisphere is the dominant source of O3 and HNO3 in the Arctic at pressures greater than 400 hPa, and that the stratospheric influence is the principal contribution at pressures less 400 hPa. During the summer, intense Russian fire emissions contribute some amount to the tropospheric columns of both gases over the American sector of the Arctic. North American fire emissions (California and Canada) also show an important impact on tropospheric ozone in the Arctic boundary layer.
Additional analysis of tropospheric O_3 measurements from ground-based FTIR and from the IASI satellite sounder made at the Eureka (Canada) and Thule (Greenland) polar sites during POLARCAT has been performed using the tagged contributions. It demonstrates the capability of these instruments for observing pollution at northern high latitudes. Differences between contributions from the sources to the tropospheric columns as measured by FTIR and IASI are discussed in terms of vertical sensitivity associated with these instruments. The first analysis of O_3 tropospheric columns observed by the IASI satellite instrument over the Arctic is also provided. Despite its limited vertical sensitivity in the lowermost atmospheric layers, we demonstrate that IASI is capable of detecting low-altitude pollution transported into the Arctic with some limitations
Global and regional effects of the photochemistry of CH_3O_2NO_2: evidence from ARCTAS
Using measurements from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) experiment, we show that methyl peroxy nitrate (CH_3O_2NO_2) is present in concentrations of ~5ā15 pptv in the springtime arctic upper troposphere. We investigate the regional and global effects of CH_3O_2NO_2 by including its chemistry in the GEOS-Chem 3-D global chemical transport model. We find that at temperatures below 240 K inclusion of CH_3O_2NO_2 chemistry results in decreases of up to ~20 % in NO_x, ~20 % in N_2O_5, ~5 % in HNO3, ~2 % in ozone, and increases in methyl hydrogen peroxide of up to ~14 %. Larger changes are observed in biomass burning plumes lofted to high altitude. Additionally, by sequestering NO_x at low temperatures, CH_3O_2NO_2 decreases the cycling of HO_2 to OH, resulting in a larger upper tropospheric HO_2 to OH ratio. These results may impact some estimates of lightning NO_x sources as well as help explain differences between models and measurements of upper tropospheric composition
-Decay Spectrum, Response Function and Statistical Model for Neutrino Mass Measurements with the KATRIN Experiment
The objective of the Karlsruhe Tritium Neutrino (KATRIN) experiment is to
determine the effective electron neutrino mass with an
unprecedented sensitivity of (90\% C.L.) by precision electron
spectroscopy close to the endpoint of the decay of tritium. We present
a consistent theoretical description of the electron energy spectrum in
the endpoint region, an accurate model of the apparatus response function, and
the statistical approaches suited to interpret and analyze tritium
decay data observed with KATRIN with the envisaged precision. In addition to
providing detailed analytical expressions for all formulae used in the
presented model framework with the necessary detail of derivation, we discuss
and quantify the impact of theoretical and experimental corrections on the
measured . Finally, we outline the statistical methods for
parameter inference and the construction of confidence intervals that are
appropriate for a neutrino mass measurement with KATRIN. In this context, we
briefly discuss the choice of the energy analysis interval and the
distribution of measuring time within that range.Comment: 27 pages, 22 figures, 2 table
Technical design and commissioning of the KATRIN large-volume air coil system
The KATRIN experiment is a next-generation direct neutrino mass experiment
with a sensitivity of 0.2 eV (90% C.L.) to the effective mass of the electron
neutrino. It measures the tritium -decay spectrum close to its endpoint
with a spectrometer based on the MAC-E filter technique. The -decay
electrons are guided by a magnetic field that operates in the mT range in the
central spectrometer volume; it is fine-tuned by a large-volume air coil system
surrounding the spectrometer vessel. The purpose of the system is to provide
optimal transmission properties for signal electrons and to achieve efficient
magnetic shielding against background. In this paper we describe the technical
design of the air coil system, including its mechanical and electrical
properties. We outline the importance of its versatile operation modes in
background investigation and suppression techniques. We compare magnetic field
measurements in the inner spectrometer volume during system commissioning with
corresponding simulations, which allows to verify the system's functionality in
fine-tuning the magnetic field configuration. This is of major importance for a
successful neutrino mass measurement at KATRIN.Comment: 32 pages, 16 figure
A pulsed, mono-energetic and angular-selective UV photo-electron source for the commissioning of the KATRIN experiment
The KATRIN experiment aims to determine the neutrino mass scale with a
sensitivity of 200 meV/c^2 (90% C.L.) by a precision measurement of the shape
of the tritium -spectrum in the endpoint region. The energy analysis of
the decay electrons is achieved by a MAC-E filter spectrometer. To determine
the transmission properties of the KATRIN main spectrometer, a mono-energetic
and angular-selective electron source has been developed. In preparation for
the second commissioning phase of the main spectrometer, a measurement phase
was carried out at the KATRIN monitor spectrometer where the device was
operated in a MAC-E filter setup for testing. The results of these measurements
are compared with simulations using the particle-tracking software
"Kassiopeia", which was developed in the KATRIN collaboration over recent
years.Comment: 19 pages, 16 figures, submitted to European Physical Journal
Observations of heterogeneous reactions between Asian pollution and mineral dust over the Eastern North Pacific during INTEX-B
In-situ airborne measurements of trace gases, aerosol size distributions, chemistry and optical properties were conducted over Mexico and the Eastern North Pacific during MILAGRO and INTEX-B. Heterogeneous reactions between secondary aerosol precursor gases and mineral dust lead to sequestration of sulfur, nitrogen and chlorine in the supermicrometer particulate size range.
Simultaneous measurements of aerosol size distributions and weak-acid soluble calcium result in an estimate of 11 wt% of CaCO_3 for Asian dust. During transport across the North Pacific, ~5ā30% of the CaCO_3 is converted to CaSO_4 or Ca(NO_3)_2 with an additional ~4% consumed through reactions with HCl. The 1996 to 2008 record from the Mauna Loa Observatory confirm these findings, indicating that, on average, 19% of the CaCO_3 has reacted to form CaSO_4 and 7% has reacted to form Ca(NO_3)_2 and ~2% has reacted with HCl. In the nitrogen-oxide rich boundary layer near Mexico City up to 30% of the CaCO_3 has reacted to form Ca(NO_3)_2 while an additional 8% has reacted with HCl.
These heterogeneous reactions can result in a ~3% increase in dust solubility which has an insignificant effect on their optical properties compared to their variability in-situ. However, competition between supermicrometer dust and submicrometer primary aerosol for condensing secondary aerosol species led to a 25% smaller number median diameter for the accumulation mode aerosol. A 10ā25% reduction of accumulation mode number median diameter results in a 30ā70% reduction in submicrometer light scattering at relative humidities in the 80ā95% range. At 80% RH submicrometer light scattering is only reduced ~3% due to a higher mass fraction of hydrophobic refractory components in the dust-affected accumulation mode aerosol. Thus reducing the geometric mean diameter of the submicrometer aerosol has a much larger effect on aerosol optical properties than changes to the hygroscopic:hydrophobic mass fractions of the accumulation mode aerosol.
In the presence of dust, nitric acid concentrations are reduced to 85% to 60ā80% in the presence of dust. These observations support previous model studies which predict irreversible sequestration of reactive nitrogen species through heterogeneous reactions with mineral dust during long-range transport
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