230 research outputs found
On the fracture toughness of fine-grained Mo-3Si-1B (wt.%) alloys at ambient to elevated (1300â°C) temperatures
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Characterization of Silicon Crystals Grown from Melt in a Granulate Crucible
The growth of silicon crystals from a melt contained in a granulate crucible significantly differs from the classical growth techniques because of the granulate feedstock and the continuous growth process. We performed a systematic study of impurities and structural defects in several such crystals with diameters up to 60 mm. The possible origin of various defects is discussed and attributed to feedstock (concentration of transition metals), growth setup (carbon concentration), or growth process (dislocation density), showing the potential for further optimization. A distinct correlation between crystal defects and bulk carrier lifetime is observed. A bulk carrier lifetime with values up to 600 ÎŒs on passivated surfaces of dislocation-free parts of the crystal is currently achieved
Density Fluctuations in an Electrolyte from Generalized Debye-Hueckel Theory
Near-critical thermodynamics in the hard-sphere (1,1) electrolyte is well
described, at a classical level, by Debye-Hueckel (DH) theory with (+,-) ion
pairing and dipolar-pair-ionic-fluid coupling. But DH-based theories do not
address density fluctuations. Here density correlations are obtained by
functional differentiation of DH theory generalized to {\it non}-uniform
densities of various species. The correlation length diverges universally
at low density as (correcting GMSA theory). When
one has as
where the amplitudes compare informatively with experimental data.Comment: 5 pages, REVTeX, 1 ps figure included with epsf. Minor changes,
references added. Accepted for publication in Phys. Rev. Let
Classical-to-critical crossovers from field theory
We extent the previous determinations of nonasymptotic critical behavior of
Phys. Rev B32, 7209 (1985) and B35, 3585 (1987) to accurate expressions of the
complete classical-to-critical crossover (in the 3-d field theory) in terms of
the temperature-like scaling field (i.e., along the critical isochore) for : 1)
the correlation length, the susceptibility and the specific heat in the
homogeneous phase for the n-vector model (n=1 to 3) and 2) for the spontaneous
magnetization (coexistence curve), the susceptibility and the specific heat in
the inhomogeneous phase for the Ising model (n=1). The present calculations
include the seventh loop order of Murray and Nickel (1991) and closely account
for the up-to-date estimates of universal asymptotic critical quantities
(exponents and amplitude combinations) provided by Guida and Zinn-Justin [J.
Phys. A31, 8103 (1998)].Comment: 4 figs, 4 program documents in appendix, some corrections adde
Universality class of criticality in the restricted primitive model electrolyte
The 1:1 equisized hard-sphere electrolyte or restricted primitive model has
been simulated via grand-canonical fine-discretization Monte Carlo. Newly
devised unbiased finite-size extrapolation methods using temperature-density,
(T, rho), loci of inflections, Q = ^2/ maxima, canonical and C_V
criticality, yield estimates of (T_c, rho_c) to +- (0.04, 3)%. Extrapolated
exponents and Q-ratio are (gamma, nu, Q_c) = [1.24(3), 0.63(3); 0.624(2)] which
support Ising (n = 1) behavior with (1.23_9, 0.630_3; 0.623_6), but exclude
classical, XY (n = 2), SAW (n = 0), and n = 1 criticality with potentials
phi(r)>Phi/r^{4.9} when r \to \infty
Dipolar origin of the gas-liquid coexistence of the hard-core 1:1 electrolyte model
We present a systematic study of the effect of the ion pairing on the
gas-liquid phase transition of hard-core 1:1 electrolyte models. We study a
class of dipolar dimer models that depend on a parameter R_c, the maximum
separation between the ions that compose the dimer. This parameter can vary
from sigma_{+/-} that corresponds to the tightly tethered dipolar dimer model,
to R_c --> infinity, that corresponds to the Stillinger-Lovett description of
the free ion system. The coexistence curve and critical point parameters are
obtained as a function of R_c by grand canonical Monte Carlo techniques. Our
results show that this dependence is smooth but non-monotonic and converges
asymptotically towards the free ion case for relatively small values of R_c.
This fact allows us to describe the gas-liquid transition in the free ion model
as a transition between two dimerized fluid phases. The role of the unpaired
ions can be considered as a perturbation of this picture.Comment: 16 pages, 13 figures, submitted to Physical Review
Deep saltwater in Chalk of North-West Europe: origin, interface characteristics and development over geological time
Towards accurate and precise T1 and extracellular volume mapping in the myocardium: a guide to current pitfalls and their solutions
Mapping of the longitudinal relaxation time (T1) and extracellular volume (ECV) offers a means of identifying pathological changes in myocardial tissue, including diffuse changes that may be invisible to existing T1-weighted methods. This technique has recently shown strong clinical utility for pathologies such as Anderson- Fabry disease and amyloidosis and has generated clinical interest as a possible means of detecting small changes in diffuse fibrosis; however, scatter in T1 and ECV estimates offers challenges for detecting these changes, and bias limits comparisons between sites and vendors. There are several technical and physiological pitfalls that influence the accuracy (bias) and precision (repeatability) of T1 and ECV mapping methods. The goal of this review is to describe the most significant of these, and detail current solutions, in order to aid scientists and clinicians to maximise the utility of T1 mapping in their clinical or research setting. A detailed summary of technical and physiological factors, issues relating to contrast agents, and specific disease-related issues is provided, along with some considerations on the future directions of the field. Towards accurate and precise T1 and extracellular volume mapping in the myocardium: a guide to current pitfalls and their solutions. Available from: https://www.researchgate.net/publication/317548806_Towards_accurate_and_precise_T1_and_extracellular_volume_mapping_in_the_myocardium_a_guide_to_current_pitfalls_and_their_solutions [accessed Jun 13, 2017]
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