888 research outputs found
Experimental and computational investigations of biomass mixing and combustion processes
Biomass is considered to be a promising source of sustainable energy and consequently it is attracting more research
attention. The focus of this ongoing study is on the performance of biomass combustion processes. Computational
fluid dynamics (CFD) techniques are planned to simulate the combustion process in various models. This is done in
parallel with experimental work to understand the mixing and combustion behaviour biomass. For this purpose CFD
models based on both Euler-Lagrange and Euler-Euler have been used. A new combustion chamber has been
designed and fabricated to validate the theoretical models. As a first step research investigations on static
combustion are currently underway. The mixing and concentration of a small fixed quantity of carbon powder has
been investigated and some preliminary results are presented
A new method in applying the universal wave equation to measure the speed of sound in water as a function of temperature with low frequency ultrasound
A new methodology was used to determine the speed of sound in water by using low frequency ultrasound over the temperature range 20 to 95° C. The initial procedure was developed based on finding the resonant locations over variable pathlengths in an acoustic tube and calculating their separation distances through the water, yielding the wavelength (λ) measurement. An in-house gain detector was employed to detect the resonant points, through detection of the amplitude voltage peaks in response to the displacement of the moving transmitter. The λ was calculated as 53 mm for water at 20° C with the fixed frequency of 28 kHz. As a result, using the universal wave equation, the speed of sound was estimated to be 1484 m/s with an accuracy of 99.89% compared to the references. The methodology was then followed through the second procedure to measure the sound speeds at temperatures higher than 20 °C, using coincidence frequency determination over different temperatures. In a fixed acoustic pathlength equal to the calculated λ at 20° C, the initial frequency, 28 kHz, was linearly swept to track the coincidence frequency corresponding to certain temperatures. The gain detector was used to obtain the coincidence frequencies, wherein the amplitude voltage peaks were recorded during the frequency adjustment. The simultaneous monitoring with an oscilloscope consolidated data when the phase differences between radiated and received waves were eliminated at the coincidence frequencies. The measured coincidence frequencies were then directly used to determine the speed of sound in water as function of temperature. The third order curve fitted to the results yielded an R2 equal to 0.9856, representing excellent agreement with the reference data
Quality Assurance in Emergency Medicine - A Caribbean Perspective
Purpose
– Emergency medicine is a new specialty in the Caribbean. With the development of specialist training over the past 20 years, the issues of quality assurance and governance have become more prominent. The purpose of this paper is to explore the successes and challenges of implementing systems of quality assurance in this unique environment, highlighting issues peculiar to the Caribbean setting.
Design/methodology/approach
– This paper is a review of current practice in the emergency departments (ED) of the four major teaching hospitals of the University of the West Indies. Information was gathered through interviews with key stakeholders (including the respective ED residency directors, senior residents and senior nursing and administrative staff), review of departmental protocols and guidelines and reviews of current published and unpublished literature.
Findings
– Examples of good practice were identified in all six components of the clinical governance framework (clinical audit, clinical effectiveness, research and development, openness, risk management and education and training). Challenges to implementation of quality management included an underdeveloped quality culture, inadequate data collection, poor incentives for improvement and high external pressures, including staff shortages, departmental crowding and lack of public empowerment.
Originality/value
– This is the first published work on clinical governance and quality assurance in emergency medicine in the Caribbean. This paper gives an insight into the unique opportunities and challenges in the area of quality management and clinical governance in the developing world, and suggests ways forward with regard to more effective implementation of quality initiatives in under-resourced jurisdictions
Pinch Technique and the Batalin-Vilkovisky formalism
In this paper we take the first step towards a non-diagrammatic formulation
of the Pinch Technique. In particular we proceed into a systematic
identification of the parts of the one-loop and two-loop Feynman diagrams that
are exchanged during the pinching process in terms of unphysical ghost Green's
functions; the latter appear in the standard Slavnov-Taylor identity satisfied
by the tree-level and one-loop three-gluon vertex. This identification allows
for the consistent generalization of the intrinsic pinch technique to two
loops, through the collective treatment of entire sets of diagrams, instead of
the laborious algebraic manipulation of individual graphs, and sets up the
stage for the generalization of the method to all orders. We show that the task
of comparing the effective Green's functions obtained by the Pinch Technique
with those computed in the background field method Feynman gauge is
significantly facilitated when employing the powerful quantization framework of
Batalin and Vilkovisky. This formalism allows for the derivation of a set of
useful non-linear identities, which express the Background Field Method Green's
functions in terms of the conventional (quantum) ones and auxiliary Green's
functions involving the background source and the gluonic anti-field; these
latter Green's functions are subsequently related by means of a Schwinger-Dyson
type of equation to the ghost Green's functions appearing in the aforementioned
Slavnov-Taylor identity.Comment: 45 pages, uses axodraw; typos corrected, one figure changed, final
version to appear in Phys.Rev.
Screened Coulomb interactions in metallic alloys: I. Universal screening in the atomic sphere approximation
We have used the locally self-consistent Green's function (LSGF) method in
supercell calculations to establish the distribution of the net charges
assigned to the atomic spheres of the alloy components in metallic alloys with
different compositions and degrees of order. This allows us to determine the
Madelung potential energy of a random alloy in the single-site mean field
approximation which makes the conventional single-site density-functional-
theory coherent potential approximation (SS-DFT-CPA) method practically
identical to the supercell LSGF method with a single-site local interaction
zone that yields an exact solution of the DFT problem. We demonstrate that the
basic mechanism which governs the charge distribution is the screening of the
net charges of the alloy components that makes the direct Coulomb interactions
short-ranged. In the atomic sphere approximation, this screening appears to be
almost independent of the alloy composition, lattice spacing, and crystal
structure. A formalism which allows a consistent treatment of the screened
Coulomb interactions within the single-site mean-filed approximation is
outlined. We also derive the contribution of the screened Coulomb interactions
to the S2 formalism and the generalized perturbation method.Comment: 28 pages, 8 figure
Unscreened Hartree-Fock calculations for metallic Fe, Co, Ni, and Cu from ab-initio Hamiltonians
Unscreened Hartree-Fock approximation (HFA) calculations for metallic Fe, Co,
Ni, and Cu are presented, by using a quantum-chemical approach. We believe that
these are the first HFA results to have been done for crystalline 3d transition
metals. Our approach uses a linearized muffin-tin orbital calculation to
determine Bloch functions for the Hartree one-particle Hamiltonian, and from
these obtains maximally localized Wannier functions, using a method proposed by
Marzari and Vanderbilt. Within this Wannier basis all relevant one-particle and
two-particle Coulomb matrix elements are calculated. The resulting
second-quantized multi-band Hamiltonian with ab-initio parameters is studied
within the simplest many-body approximation, namely the unscreened,
self-consistent HFA, which takes into account exact exchange and is free of
self-interactions. Although the d-bands sit considerably lower within HFA than
within the local (spin) density approximation L(S)DA, the exchange splitting
and magnetic moments for ferromagnetic Fe, Co, and Ni are only slightly larger
in HFA than what is obtained either experimentally or within LSDA. The HFA
total energies are lower than the corresponding LSDA calculations. We believe
that this same approach can be easily extended to include more sophisticated
ab-initio many-body treatments of the electronic structure of solids.Comment: 11 papes, 7 figures, 5 table
Transverse spin dynamics in a spin-polarized Fermi liquid
The linear equations for transverse spin dynamics in weakly polarised
degenerate Fermi liquid with arbitrary relationship between temperature and
polarization are derived from Landau-Silin phenomenological kinetic equation
with general form of two-particle collision integral. The temperature and
polarization dependence of the spin current relaxation time is established. It
is found in particular that at finite polarization transverse spin wave damping
has a finite value at T=0. The analogy between temperature dependences of spin
waves attenuation and ultrasound absorption in degenerate Fermi liquid at
arbitrary temperature is presented. We also discuss spin-polarized Fermi liquid
in the general context of the Fermi-liquid theory and compare it with "Fermi
liquid" with spontaneous magnetization.Comment: 10 page
Onset of magnetism in B2 transition metals aluminides
Ab initio calculation results for the electronic structure of disordered bcc
Fe(x)Al(1-x) (0.4<x<0.75), Co(x)Al(1-x) and Ni(x)Al(1-x) (x=0.4; 0.5; 0.6)
alloys near the 1:1 stoichiometry, as well as of the ordered B2 (FeAl, CoAl,
NiAl) phases with point defects are presented. The calculations were performed
using the coherent potential approximation within the Korringa-Kohn-Rostoker
method (KKR-CPA) for the disordered case and the tight-binding linear
muffin-tin orbital (TB-LMTO) method for the intermetallic compounds. We studied
in particular the onset of magnetism in Fe-Al and Co-Al systems as a function
of the defect structure. We found the appearance of large local magnetic
moments associated with the transition metal (TM) antisite defect in FeAl and
CoAl compounds, in agreement with the experimental findings. Moreover, we found
that any vacancies on both sublattices enhance the magnetic moments via
reducing the charge transfer to a TM atom. Disordered Fe-Al alloys are
ferromagnetically ordered for the whole range of composition studied, whereas
Co-Al becomes magnetic only for Co concentration >0.5.Comment: 11 pages with 9 embedded postscript figures, to be published in
Phys.Rev.
Serum outperforms plasma in small extracellular vesicle microRNA biomarker studies of adenocarcinoma of the esophagus
Background: To compare computed tomography coronary angiography (CTCA) with intravascular ultrasound (IVUS) in quantitative and qualitative plaque assessment. Methods: Patients who underwent IVUS and CTCA within 3 months for suspected coronary artery disease were retrospectively studied. Plaque volumes on CTCA were quantified manually and with automated-software and were compared to IVUS. High-risk plaque features were compared between CTCA and IVUS. Results: There were 769 slices in 32 vessels (27 patients). Manual plaque quantification on CTCA was comparable to IVUS per slice (mean difference of 0.06 ± 0.07, p = 0.44; Bland-Altman 95% limits of agreement -2.19–2.08 mm3, bias of -0.06 mm3) and per vessel (3.1 mm3 ± -2.85 mm3, p = 0.92). In contrast, there was significant difference between automated-software and IVUS per slice (2.3 ± 0.09mm3, p < 0.001; 95% LoA -6.78 to 2.25 mm3, bias of -2.2 mm3) and per vessel (33.04 ± 10.3 mm3, p < 0.01). The sensitivity, specificity, positive and negative predictive value of CTCA to detect plaques that had features of echo-attenuation on IVUS was 93.3%, 99.6%, 93.3% and 99.6% respectively. The association of ≥2 high-risk plaque features on CTCA with echo attenuation (EA) plaque features on IVUS was excellent (86.7%, 99.6%, 92.9% and 99.2%). In comparison, the association of high-risk plaque features on CTCA and plaques with echo-lucency on IVUS was only modest. Conclusion: Plaque volume quantification by manual CTCA method is accurate when compared to IVUS. The presence of at least two high-risk plaque features on CTCA is associated with plaque features of echo attenuation on IVUS.Ravi Kiran Munnur, Jordan Andrews ... Dorothy Keefe ... Lorelle Smith ... Joanne Bowen ... Sarah Thompson ... et al
Magnetoelectric ordering of BiFeO3 from the perspective of crystal chemistry
In this paper we examine the role of crystal chemistry factors in creating
conditions for formation of magnetoelectric ordering in BiFeO3. It is generally
accepted that the main reason of the ferroelectric distortion in BiFeO3 is
concerned with a stereochemical activity of the Bi lone pair. However, the lone
pair is stereochemically active in the paraelectric orthorhombic beta-phase as
well. We demonstrate that a crucial role in emerging of phase transitions of
the metal-insulator, paraelectric-ferroelectric and magnetic disorder-order
types belongs to the change of the degree of the lone pair stereochemical
activity - its consecutive increase with the temperature decrease. Using the
structural data, we calculated the sign and strength of magnetic couplings in
BiFeO3 in the range from 945 C down to 25 C and found the couplings, which
undergo the antiferromagnetic-ferromagnetic transition with the temperature
decrease and give rise to the antiferromagnetic ordering and its delay in
regard to temperature, as compared to the ferroelectric ordering. We discuss
the reasons of emerging of the spatially modulated spin structure and its
suppression by doping with La3+.Comment: 18 pages, 5 figures, 3 table
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