Predicting bioavailability of PAHs in field-contaminated soils by passive sampling with triolein embedded cellulose acetate membranes

Triolein embedded cellulose acetate membrane (TECAM) was used for passive sampling of the fraction of naphthalene, phenanthrene, pyrene and benzo[a]pyrene in 18 field -contaminated soils. The sampling process of PAHs by TECAM fitted well with a first-order kinetics model and PAHs reached 95% of equilibrium in TECAM within 20 h. Concentrations of PAHs in TECAM (C-TECAM) correlated well with the concentrations in soils (r(2) = 0.693-0.962, p < 0.001). Furthermore. concentrations of PAHs determined in the soil solution were very close to the values estimated by C-TECAM and the partition coefficient between TECAM and water (KTECAM-W). After lipid normalization nearly 1:1 relationships were observed between PAH concentrations in TECAMs and earthworms exposed to the soils (r(2) = 0.591-0.824, n = 18, p < 0.01). These results suggest that TECAM can be a useful tool to predict bioavailability of PAHs in field-contaminated soils. (C) 2008 Elsevier Ltd. All rights reserved

An anatomical study in a Chinese population of the position of the rib head for placing anterior vertebral body screws

The instrumentation of anterior vertebral body screws has become an important approach for the treatment of unstable fractures or curvature of the spine, but little attention has been paid to the starting point of placing the screws and the variability of the rib head position. We analysed the variability of rib head position in a Chinese population in terms of the spinal canal and vertebral body using computed tomography (CT). Images from transverse CT scans of the T4&#8211;T12 vertebral bodies of 30 normal individuals were 3-D reconstructed and analysed for measurement of parameters which included: 1) distance between the left (or right) anterior border of the rib head and the posterior (or anterior) margin of the vertebral body [L(R)ARHP(A)VB]; 2) left (or right) transverse dimension [L(R)TD]; 3) left (or right) posterior (or anterior) safe angle [L(R)P(A)SA]; and 4) distance between the inferior border of the left (or right) rib head and the superior (or inferior) end-plate in the sagittal plane [I L(R)RHS(I)EP]. The ARHPVB, PSA, and IRHIEP gradually decrease, but ARHAVB, TD, ASA, and IRHSEP gradually increase, from T4 to T12, indicating that the position of the rib head changes from a more anterior position to a more posterior position and from a more superior position to a more inferior position, as the number of the vertebra increases. Our study has provided a comprehensive reference guide for accurate and safe instrumentation of vertebral body screws in treating related spine diseases. (Folia Morphol 2010; 69, 4: 232-240

A Real-Time Game Theoretic Planner for Autonomous Two-Player Drone Racing

In this article, we propose an online 3-D planning algorithm for a drone to race competitively against a single adversary drone. The algorithm computes an approximation of the Nash equilibrium in the joint space of trajectories of the two drones at each time step, and proceeds in a receding horizon fashion. The algorithm uses a novel sensitivity term, within an iterative best response computational scheme, to approximate the amount by which the adversary will yield to the ego drone to avoid a collision. This leads to racing trajectories that are more competitive than without the sensitivity term. We prove that the fixed point of this sensitivity enhanced iterative best response satisfies the first-order optimality conditions of a Nash equilibrium. We present results of a simulation study of races with 2-D and 3-D race courses, showing that our game theoretic planner significantly outperforms amodel predictive control (MPC) racing algorithm. We also present results of multiple drone racing experiments on a 3-D track in which drones sense each others'' relative position with onboard vision. The proposed game theoretic planner again outperforms the MPC opponent in these experiments where drones reach speeds up to 1.25m/s

Mixing state of atmospheric particles over the North China Plain

In this unique processing study, the mixing state of ambient submicron aerosol particles in terms of hygroscopicity and volatility was investigated with a Hygroscopicity Tandem Differential Mobility Analyzer and a Volatility Tandem Differential Mobility Analyzer. The measurements were conducted at a regional atmospheric observational site in the North China Plain (NCP) from 8 July to 9 August, 2013. Multimodal patterns were observed in the probability density functions of the hygroscopicity parameter κ and the shrink factor, indicating that ambient particles are mostly an external mixture of particles with different hygroscopicity and volatility. Linear relationships were found between the number fraction of hydrophobic and non-volatile populations, reflecting the dominance of soot in hydrophobic and non-volatile particles. The number fraction of non-volatile particles is lower than that of hydrophobic particles in most cases, indicating that a certain fraction of hydrophobic particles is volatile. Distinct diurnal patterns were found for the number fraction of the hydrophobic and non-volatile particles, with a higher level at nighttime and a lower level during the daytime. The result of air mass classification shows that aerosol particles in air masses coming from north with high moving speed have a high number fraction of hydrophobic/non-volatile population, and are more externally mixed. Only minor differences can be found between the measured aerosol properties for the rest of the air masses. With abundant precursor in the NCP, no matter where the air mass originates, as far as it stays in the NCP for a certain time, aerosol particles may get aged and mixed with newly emitted particles in a short time

Investigation on viscosity and non-isothermal crystallization behavior of P-bearing steelmaking slags with varying TiO2 content

The viscous flow and crystallization behavior of CaO-SiO2-MgO-Al2O3-FetO-P2O5-TiO2 steelmaking slags have been investigated over a wide range of temperatures under Ar (High purity, >99.999 pct) atmosphere, and the relationship between viscosity and structure was determined. The results indicated that the viscosity of the slags slightly decreased with increasing TiO2 content. The constructed nonisothermal continuous cooling transformation (CCT) diagrams revealed that the addition of TiO2 lowered the crystallization temperature. This can mainly be ascribed to that addition of TiO2 promotes the formation of [TiO6]-octahedra units and, consequently, the formation of MgFe2O4-Mg2TiO4 solid solution. Moreover, the decreasing viscosity has a significant effect on enhancing the diffusion of ion units, such as Ca2+ and [TiO4]-tetrahedra, from bulk melts to the crystal–melt interface. The crystallization of CaTiO3 and CaSiTiO5 was consequently accelerated, which can improve the phosphorus content in P-enriched phase (n2CaO·SiO2-3CaO·P2O5). Finally, the nonisothermal crystallization kinetics was characterized and the activation energy for the primary crystal growth was derived such that the activation energy increases from −265.93 to −185.41 KJ·mol−1 with the addition of TiO2 content, suggesting that TiO2 lowered the tendency for the slags to crystallize

BES3 time of flight monitoring system

A Time of Flight monitoring system has been developed for BES3. The light source is a 442-443 nm laser diode, which is stable and provides a pulse width as narrow as 50 ps and a peak power as large as 2.6 W. Two optical-fiber bundles with a total of 512 optical fibers, including spares, are used to distribute the light pulses to the Time of Flight counters. The design, operation, and performance of the system are described.Comment: 8 pages 16 figures, submitted to NI

Long-term measurements of particle number size distributions and the relationships with air mass history and source apportionment in the summer of Beijing

A series of long-term and temporary measurements were conducted to study the improvement of air quality in Beijing during the Olympic Games period (8–24 August 2008). To evaluate actions taken to improve the air quality, comparisons of particle number and volume size distributions of August 2008 and 2004–2007 were performed. The total particle number and volume concentrations were 14 000 cm−3 and 37 μm−3 cm−3 in August of 2008, respectively. These were reductions of 41% and 35% compared with mean values of August 2004–2007. A cluster analysis on air mass history and source apportionment were performed, exploring reasons for the reduction of particle concentrations. Back trajectories were classified into five major clusters. Air masses from the south direction are always associated with pollution events during the summertime in Beijing. In August 2008, the frequency of air mass arriving from the south was 1.3 times higher compared to the average of the previous years, which however did not result in elevated particle volume concentrations in Beijing. Therefore, the reduced particle number and volume concentrations during the 2008 Beijing Olympic Games cannot be only explained by meteorological conditions. Four factors were found influencing particle concentrations using a positive matrix factorization (PMF) model. They were identified as local and remote traffic emissions, combustion sources as well as secondary transformation. The reductions of the four sources were calculated to 47%, 44%, 43% and 30%, respectively. The significant reductions of particle number and volume concentrations may attribute to actions taken, focusing on primary emissions, especially related to the traffic and combustion sources

Acoustic phonon transport through a double-bend quantum waveguide

In this work, using the scattering matrix method, we have investigated the transmission coefficients and the thermal conductivity in a double-bend waveguide structure. The transmission coefficients show strong resonances due to the scattering in the midsection of a double-bend structure; the positions and the widths of the resonance peaks are determined by the dimensions of the midsection of the structure. And the scattering in the double-bend structure makes the thermal conductivity decreases with the increasing of the temperature first, then increases after reaches a minimum. Furthermore, the investigations of the multiple double-bend structures indicate that the first additional double-bend structure suppresses the transmission coefficient and the frequency gap formed; and the additional double-bend structures determine the numbers of the resonance peaks at the frequency just above the gap region. These results could be useful for the design of phonon devices.Comment: 13 pages, 6 figures, elsart.cls is use