76 research outputs found
How a colloidal paste flows – scaling behaviors in dispersions of aggregated particles under mechanical stress –
We have developed a novel computational scheme that allows direct numerical simulation of the mechanical
behavior of sticky granular matter under stress. We present here the general method, with particular emphasis on the
particle features at the nanometric scale. It is demonstrated that, although sticky granular material is quite complex and is a good example of a challenging computational problem (it is a dynamical problem, with irreversibility, self-organization
and dissipation), its main features may be reproduced on the basis of rather simple numerical model, and a small number of physical parameters. This allows precise analysis of the possible deformation processes in soft materials submitted to mechanical stress. This results in direct relationship between the macroscopic rheology of these pastes and local interactions
between the particles
Oxometalate-glass composites and thin films
New glass-composites with ion exchange properties have been developed.
Ammonium 12-molybdophosphate (AMP) (ΝΗ4)3ΡΜοΐ2θ4ο, and ammonium 12-tungstophosphate (AWP) (Nh4)3PW12O40, known for their ion exchange
capabilities, are included either in preformed aerogels with defined pore size, or are
added to sol-gel mixtures during the process of gel formation. Characterization is
carried out by FTIR, Raman and EXAFS spectroscopy. Ion exchange capacities for the
oxometalate precursors are determined for silver and rubidium and are compared to
those of the glass composites. Glass composites show high ion exchange capacity, but
some portion of the metalate complexes leaches from the glass during the procedure.
This is in contrast to thin composite films, which have almost no porosity and do not
show loss of metalate. EXAFS spectroscopy demostrates that the oxometalate
microstructure is maintained in glass composites and that rubidium ions after ion
exchange in glasses occupy similar cation positions as in the precursor compounds
Vortex Lattice Symmetry and Electronic Structure in YBa₂Cu₃O₇
We report a small angle neutron scattering study of the vortex lattice in YBa2Cu3O7 in magnetic fields of 0.5≤H≤5 T applied along and close to the c axis. Over the entire field range, the vortices form an oblique lattice with two nearly equal lattice constants and an angle of 73°between primitive vectors. Numerical calculations suggest that variations of the superconducting order parameter near the vortex core are important in stabilizing this structure. An analysis that accounts for the fourfold symmetry of the vortex core qualitatively explains both the symmetry and the orientation of the observed vortex lattice. A quantitative explanation of our data will require calculations based on a realistic gap equation
Quantum Monte Carlo study of a magnetic-field-driven 2D superconductor-insulator transition
We numerically study the superconductor-insulator phase transition in a model
disordered 2D superconductor as a function of applied magnetic field. The
calculation involves quantum Monte Carlo calculations of the (2+1)D XY model in
the presence of both disorder and magnetic field. The XY coupling is assumed to
have the form -J\cos(\theta_i-\theta_j-A_{ij}), where A_{ij} has a mean of zero
and a standard deviation \Delta A_{ij}. In a real system, such a model would be
approximately realized by a 2D array of small Josephson-coupled grains with
slight spatial disorder and a uniform applied magnetic field. The different
values \Delta A_{ij} then corresponds to an applied field such that the average
number of flux quanta per plaquette has various integer values N: larger N
corresponds to larger \Delta A_{ij}. For any value of \Delta A_{ij}, there
appears to be a critical coupling constant K_c(\Delta
A_{ij})=\sqrt{[J/(2U)]_c}, where U is the charging energy, above which the
system is a Mott insulator; there is also a corresponding critical conductivity
\sigma^*(\Delta A_{ij}) at the transition. For \Delta A_{ij}=\infty, the order
parameter of the transition is a renormalized coupling constant g. Using a
numerical technique appropriate for disordered systems, we show that the
transition at this value of \Delta A_{ij} takes place from an insulating (I)
phase to a Bose glass (BG) phase, and that the dynamical critical exponent
characterizing this transition is z \sim 1.3. By contrast, z=1 for this model
at \Delta A_{ij}=0. We suggest that the superconductor to insulator transition
is actually of this I to BG class at all nonzero \Delta A_{ij}'s, and we
support this interpretation by both numerical evidence and an analytical
argument based on the Harris criterion.Comment: 17 pages, 23 figures, accepted for publication in Phys. Rev.
A Rapid Method to Regenerate Piezoelectric Microcantilever Sensors (PEMS)
Piezoelectric microcantilever sensors (PEMS) can be sensitive tools for the detection of proteins and cells in biological fluids. However, currently available PEMS can only be used a single time or must be completely stripped and refunctionalized prior to subsequent uses. Here we report the successful use of an alternative regeneration protocol employing high salt concentrations to remove the target, leaving the functional probe immobilized on the microcantilever surface. Our model system employed the extracellular domain (ECD) of recombinant human Epidermal Growth Factor Receptor (EGFR) as the probe and anti-human EGFR polyclonal antibodies as the target. We report that high concentrations of MgCl2 dissociated polyclonal antibodies specifically bound to EGFR ECD immobilized on the sensor surface without affecting its bioactivity. This simple regeneration protocol both minimized the time required to re-conjugate the probe and preserved the density of probe immobilized on PEMS surface, yielding identical biosensor sensitivity over a series of assays
Microwatt energy harvesting by exploiting flow-induced vibration
The green technology approaches by harvesting energy from aerodynamic flowinduced vibrations using a flexible square cylinder is experimentally investigated. The practicability of flow-induced vibration system to supply a sufficient base excitation vibration in microwatt scale is evaluated through a series of wind tunnel tests with different velocities. Test are performed for high Reynolds number 3.9 × 103≤ Re 1.4 × 104 and damping ratio ζ = 0.0052. The experiment setup is able to replicate the pattern of vibration amplitude for isolated square cylinder with previous available study. Then, the experimental setup is used to study the effect of vibration cylinder in harvesting the fluid energy. A prototype of electromagnetic energy harvesting is invented and fabricated to test its performance in the wind tunnel test. Test results reveal that the harnessed power is corresponding to vibration amplitude flow pattern, but the power obtained is much lower than the vibration amplitude due to the power dissipation at the resistor. The best condition for harnessing power is identified at UR = 7.7 where the Karman Vortex-Induced Vibration (KVIV) is the largest
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