How a colloidal paste flows – scaling behaviors in dispersions of aggregated particles under mechanical stress –

We have developed a novel computational scheme that allows direct numerical simulation of the mechanical behavior of sticky granular matter under stress. We present here the general method, with particular emphasis on the particle features at the nanometric scale. It is demonstrated that, although sticky granular material is quite complex and is a good example of a challenging computational problem (it is a dynamical problem, with irreversibility, self-organization and dissipation), its main features may be reproduced on the basis of rather simple numerical model, and a small number of physical parameters. This allows precise analysis of the possible deformation processes in soft materials submitted to mechanical stress. This results in direct relationship between the macroscopic rheology of these pastes and local interactions between the particles

Oxometalate-glass composites and thin films

New glass-composites with ion exchange properties have been developed. Ammonium 12-molybdophosphate (AMP) (ΝΗ4)3ΡΜοΐ2θ4ο, and ammonium 12-tungstophosphate (AWP) (Nh4)3PW12O40, known for their ion exchange capabilities, are included either in preformed aerogels with defined pore size, or are added to sol-gel mixtures during the process of gel formation. Characterization is carried out by FTIR, Raman and EXAFS spectroscopy. Ion exchange capacities for the oxometalate precursors are determined for silver and rubidium and are compared to those of the glass composites. Glass composites show high ion exchange capacity, but some portion of the metalate complexes leaches from the glass during the procedure. This is in contrast to thin composite films, which have almost no porosity and do not show loss of metalate. EXAFS spectroscopy demostrates that the oxometalate microstructure is maintained in glass composites and that rubidium ions after ion exchange in glasses occupy similar cation positions as in the precursor compounds

Vortex Lattice Symmetry and Electronic Structure in YBa₂Cu₃O₇

We report a small angle neutron scattering study of the vortex lattice in YBa2Cu3O7 in magnetic fields of 0.5≤H≤5 T applied along and close to the c axis. Over the entire field range, the vortices form an oblique lattice with two nearly equal lattice constants and an angle of 73°between primitive vectors. Numerical calculations suggest that variations of the superconducting order parameter near the vortex core are important in stabilizing this structure. An analysis that accounts for the fourfold symmetry of the vortex core qualitatively explains both the symmetry and the orientation of the observed vortex lattice. A quantitative explanation of our data will require calculations based on a realistic gap equation

Quantum Monte Carlo study of a magnetic-field-driven 2D superconductor-insulator transition

We numerically study the superconductor-insulator phase transition in a model disordered 2D superconductor as a function of applied magnetic field. The calculation involves quantum Monte Carlo calculations of the (2+1)D XY model in the presence of both disorder and magnetic field. The XY coupling is assumed to have the form -J\cos(\theta_i-\theta_j-A_{ij}), where A_{ij} has a mean of zero and a standard deviation \Delta A_{ij}. In a real system, such a model would be approximately realized by a 2D array of small Josephson-coupled grains with slight spatial disorder and a uniform applied magnetic field. The different values \Delta A_{ij} then corresponds to an applied field such that the average number of flux quanta per plaquette has various integer values N: larger N corresponds to larger \Delta A_{ij}. For any value of \Delta A_{ij}, there appears to be a critical coupling constant K_c(\Delta A_{ij})=\sqrt{[J/(2U)]_c}, where U is the charging energy, above which the system is a Mott insulator; there is also a corresponding critical conductivity \sigma^*(\Delta A_{ij}) at the transition. For \Delta A_{ij}=\infty, the order parameter of the transition is a renormalized coupling constant g. Using a numerical technique appropriate for disordered systems, we show that the transition at this value of \Delta A_{ij} takes place from an insulating (I) phase to a Bose glass (BG) phase, and that the dynamical critical exponent characterizing this transition is z \sim 1.3. By contrast, z=1 for this model at \Delta A_{ij}=0. We suggest that the superconductor to insulator transition is actually of this I to BG class at all nonzero \Delta A_{ij}'s, and we support this interpretation by both numerical evidence and an analytical argument based on the Harris criterion.Comment: 17 pages, 23 figures, accepted for publication in Phys. Rev.

A Rapid Method to Regenerate Piezoelectric Microcantilever Sensors (PEMS)

Piezoelectric microcantilever sensors (PEMS) can be sensitive tools for the detection of proteins and cells in biological fluids. However, currently available PEMS can only be used a single time or must be completely stripped and refunctionalized prior to subsequent uses. Here we report the successful use of an alternative regeneration protocol employing high salt concentrations to remove the target, leaving the functional probe immobilized on the microcantilever surface. Our model system employed the extracellular domain (ECD) of recombinant human Epidermal Growth Factor Receptor (EGFR) as the probe and anti-human EGFR polyclonal antibodies as the target. We report that high concentrations of MgCl2 dissociated polyclonal antibodies specifically bound to EGFR ECD immobilized on the sensor surface without affecting its bioactivity. This simple regeneration protocol both minimized the time required to re-conjugate the probe and preserved the density of probe immobilized on PEMS surface, yielding identical biosensor sensitivity over a series of assays

Microwatt energy harvesting by exploiting flow-induced vibration

The green technology approaches by harvesting energy from aerodynamic flowinduced vibrations using a flexible square cylinder is experimentally investigated. The practicability of flow-induced vibration system to supply a sufficient base excitation vibration in microwatt scale is evaluated through a series of wind tunnel tests with different velocities. Test are performed for high Reynolds number 3.9 × 103≤ Re 1.4 × 104 and damping ratio ζ = 0.0052. The experiment setup is able to replicate the pattern of vibration amplitude for isolated square cylinder with previous available study. Then, the experimental setup is used to study the effect of vibration cylinder in harvesting the fluid energy. A prototype of electromagnetic energy harvesting is invented and fabricated to test its performance in the wind tunnel test. Test results reveal that the harnessed power is corresponding to vibration amplitude flow pattern, but the power obtained is much lower than the vibration amplitude due to the power dissipation at the resistor. The best condition for harnessing power is identified at UR = 7.7 where the Karman Vortex-Induced Vibration (KVIV) is the largest