Photoelectron spectroscopy of NpPd3 and PuPd3

We present the results of x-ray and ultraviolet photoelectron spectroscopy of NpPd3 and PuPd3. The spectra indicate that for both compounds, the 5f electrons are well localized on the actinide sites. Comparison with bulk measurements indicates that for NpPd3 the electrons have a valence of Np3+ and thus a ground state 5f4 with a Hund's rules 5I4 configuration. Similarly for PuPd3, we find a Pu3+ valence, 5f5 ground state and a Hund's rules 6H5/2 configuration

MIPAS IMK/IAA CFC-11 (CCl3F) and CFC-12 (CCl2F2) measurements: accuracy, precision and long-term stability

Eckert, E. et. al.Profiles of CFC-11 (CCl3F) and CFC-12 (CCl2F2) of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) aboard the European satellite Envisat have been retrieved from versions MIPAS/4.61 to MIPAS/ 4.62 and MIPAS/5.02 to MIPAS/5.06 level-1b data using the scientific level-2 processor run by Karlsruhe Institute of Technology (KIT), Institute of Meteorology and Climate Research (IMK) and Consejo Superior de Investigaciones Científicas (CSIC), Instituto de Astrofísica de Andalucía (IAA). These profiles have been compared to measurements taken by the balloon-borne cryosampler, Mark IV (MkIV) and MIPAS-Balloon (MIPAS-B), the airborne MIPAS-STRatospheric aircraft (MIPAS-STR), the satellite-borne Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) and the High Resolution Dynamic Limb Sounder (HIRDLS), as well as the groundbased Halocarbon and other Atmospheric Trace Species (HATS) network for the reduced spectral resolution period (RR: January 2005-April 2012) of MIPAS. ACE-FTS, MkIV and HATS also provide measurements during the high spectral resolution period (full resolution, FR: July 2002-March 2004) and were used to validate MIPAS CFC-11 and CFC-12 products during that time, as well as profiles from the Improved Limb Atmospheric Spectrometer, ILAS-II. In general, we find that MIPAS shows slightly higher values for CFC-11 at the lower end of the profiles (below ∼15 km) and in a comparison of HATS ground-based data and MIPAS measurements at 3 km below the tropopause. Differences range from approximately 10 to 50 pptv (∼5-20 %) during the RR period. In general, differences are slightly smaller for the FR period. An indication of a slight high bias at the lower end of the profile exists for CFC-12 as well, but this bias is far less pronounced than for CFC-11 and is not as obvious in the relative differences between MIPAS and any of the comparison instruments. Differences at the lower end of the profile (below ∼15 km) and in the comparison of HATS and MIPAS measurements taken at 3 km below the tropopause mainly stay within 10-50 pptv (corresponding to ∼2-10%for CFCPublished 12) for the RR and the FR period. Between ∼15 and 30 km, most comparisons agree within 10-20 pptv (10-20 %), apart from ILAS-II, which shows large differences above ∼17 km. Overall, relative differences are usually smaller for CFC-12 than for CFC-11. For both species - CFC-11 and CFC-12 - we find that differences at the lower end of the profile tend to be larger at higher latitudes than in tropical and subtropical regions. In addition, MIPAS profiles have a maximum in their mixing ratio around the tropopause, which is most obvious in tropical mean profiles. Comparisons of the standard deviation in a quiescent atmosphere (polar summer) show that only the CFC-12 FR error budget can fully explain the observed variability, while for the other products (CFC-11 FR and RR and CFC-12 RR) only two-thirds to three-quarters can be explained. Investigations regarding the temporal stability show very small negative drifts in MIPAS CFC-11 measurements. These instrument drifts vary between ∼1 and 3% decade-1. For CFC-12, the drifts are also negative and close to zero up to ∼30 km. Above that altitude, larger drifts of up to ∼50% decade-1 appear which are negative up to ∼35 km and positive, but of a similar magnitude, above. © Author(s) 2016.IMK data analysis was supported by DLR under contract number 50EE0901. MIPAS level 1B data were provided by ESA. We acknowledge support by Deutsche Forschungsgemeinschaft and Open Access Publishing Fund of Karlsruhe Institute of Technology. The Atmospheric Chemistry Experiment (ACE), also known as SCISAT, is a Canadian-led mission mainly supported by the Canadian Space Agency and the Natural Sciences and Engineering Research Council of Canada. Work at the Jet Propulsion Laboratory, California Institute of Technology, was carried out under contract with the National Aeronautics and Space Administration. Data collection and analysis of MIPAS-STR data used here were supported by the EU-project RECONCILE (grant no. 15 226365-FP7-ENV-2008-1) and the BMBF-project ENVIVAL-Life (DLR grant no. 50EE0841).Peer reviewe

Magnetic-interference patterns in Josephson junctions with d+is symmetry

The magnetic interference pattern and the spontaneous flux in unconventional Josephson junctions of superconductors with d+is symmetry are calculated for different reduced junction lengths and the relative factor of the d and s wave components. This is a time reversal broken symmetry state. We study the stability of the fractional vortex and antivortex which are spontaneously formed and examine their evolution as we change the length and the relative factor of d and s wave components. The asymmetry in the field modulated diffraction pattern exists for lengths as long as L=10\lambda_J.Comment: 8 pages, 6 eps files, submitted to PR

Protecting the Baryon Asymmetry with Thermal Masses

We consider the evolution of baryon number $B$ in the early universe under the influence of rapid sphaleron interactions and show that $B$ will remain nonzero at all times even in the case of $B-L = 0$. This result arises due to thermal Yukawa interactions that cause nonidentical dispersion relations (thermal masses) for different lepton families. We point out the relevance of our result to the Affleck-Dine type baryogenesis.Comment: 11pp., plain tex, UMN-TH-1248/94, CfPA-TH-94-1

Precision Primordial 4^4He Measurement with CMB Experiments

Big bang nucleosynthesis (BBN) and the cosmic microwave background (CMB) are two major pillars of cosmology. Standard BBN accurately predicts the primordial light element abundances ($^4$He, D, $^3$He and $^7$Li), depending on one parameter, the baryon density. Light element observations are used as a baryometers. The CMB anisotropies also contain information about the content of the universe which allows an important consistency check on the Big Bang model. In addition CMB observations now have sufficient accuracy to not only determine the total baryon density, but also resolve its principal constituents, H and $^4$He. We present a global analysis of all recent CMB data, with special emphasis on the concordance with BBN theory and light element observations. We find $\Omega_{B}h^{2}=0.025+0.0019-0.0026$ and $Y_{p}=0.250+0.010-0.014$ (fraction of baryon mass as $^4$He) using CMB data alone, in agreement with $^4$He abundance observations. With this concordance established we show that the inclusion of BBN theory priors significantly reduces the volume of parameter space. In this case, we find $\Omega_{B}h^2=0.0244+0.00137-0.00284$ and $Y_p = 0.2493+0.0006-0.001$. We also find that the inclusion of deuterium abundance observations reduces the $Y_p$ and $\Omega_{B}h^2$ ranges by a factor of $\sim$2. Further light element observations and CMB anisotropy experiments will refine this concordance and sharpen BBN and the CMB as tools for precision cosmology.Comment: 7 pages, 3 color figures made minor changes to bring inline with journal versio

Improvement of Odin/SMR water vapour and temperature measurements and validation of the obtained data sets

Its long photochemical lifetime makes H2O a good tracer for mesospheric dynamics. Temperature observations are also critical to study middle atmospheric dynamics. In this study, we present the reprocessing of 18 years of mesospheric H2O and temperature measurements from the Sub-Millimetre Radiometer (SMR) aboard the Odin satellite, resulting in a part of the SMR version 3.0 level 2 data set. The previous version of the data set showed poor accordance with measurements from other instruments, which suggested that the retrieved concentrations and temperature were subject to instrumental artefacts. Different hypotheses have been explored, and the idea of an underestimation of the singlesideband leakage turned out to be the most reasonable one. The value of the lowest transmission achievable has therefore been raised to account for greater sideband leakage, and new retrievals have been performed with the new settings. The retrieved profiles extend between 40-100 km altitude and cover the whole globe to reach 85\ub0 latitudes. A validation study has been carried out, revealing an overall better accordance with the compared instruments. In particular, relative differences in H2O mixing ratio are always in the \ub120% range between 40 and 70 km and diverge at higher altitudes, while temperature absolute differences are within \ub15K between 40-80 km and also diverge at higher altitudes

Stable propagation of an ordered array of cracks during directional drying

We study the appearance and evolution of an array of parallel cracks in a thin slab of material that is directionally dried, and show that the cracks penetrate the material uniformly if the drying front is sufficiently sharp. We also show that cracks have a tendency to become evenly spaced during the penetration. The typical distance between cracks is mainly governed by the typical distance of the pattern at the surface, and it is not modified during the penetration. Our results agree with recent experimental work, and can be extended to three dimensions to describe the properties of columnar polygonal patterns observed in some geological formations.Comment: 8 pages, 4 figures, to appear in PR

Statistics of Coulomb blockade peak spacings for a partially open dot

We show that randomness of the electron wave functions in a quantum dot contributes to the fluctuations of the positions of the conductance peaks. This contribution grows with the conductance of the junctions connecting the dot to the leads. It becomes comparable with the fluctuations coming from the randomness of the single particle spectrum in the dot while the Coulomb blockade peaks are still well-defined. In addition, the fluctuations of the peak spacings are correlated with the fluctuations of the conductance peak heights.Comment: 13 pages, 1 figur

Local Mapping of Polar Ionospheric Electrodynamics

An accurate description of the state of the ionosphere is crucial for understanding the physics of Earth's coupling to space, including many potentially hazardous space weather phenomena. To support this effort, ground networks of magnetometer stations, optical instruments, and radars have been deployed. However, the spatial coverage of such networks is naturally restricted by the distribution of land mass and access to necessary infrastructure. We present a new technique for local mapping of polar ionospheric electrodynamics, for use in regions with high data density, such as Fennoscandia and North America. The technique is based on spherical elementary current systems (SECS), which were originally developed to map ionospheric currents. We expand their use by linking magnetic field perturbations in space and on ground, convection measurements from space and ground, and conductance measurements, via the ionospheric Ohm's law. The result is a technique that is similar to the Assimilative Mapping of Ionospheric Electrodynamics (AMIE) technique, but tailored for regional analyses of arbitrary spatial extent and resolution. We demonstrate our technique on synthetic data, and with real data from three different regions. We also discuss limitations of the technique and potential areas for improvement.publishedVersio

Detailed study of BBN implications of neutrino oscillation generated neutrino asymmetries in some four neutrino models

We re-examine the evolution of neutrino asymmetries in several four neutrino models. The first case involves the direct creation of $L_{\nu_e}$ by $\nu_e \leftrightarrow \nu_s$ oscillations. In the second case, we consider the mass hierarchy $m_{\nu_\tau} \gg m_{\nu_\mu}, m_{\nu_e}, m_{\nu_s}$ where $\nu_\tau \leftrightarrow \nu_s$ oscillations generate a large $L_{\nu_\tau}$ and some of this asymmetry is converted into $L_{\nu_e}$ by $\nu_{\tau} \leftrightarrow \nu_{e}$ oscillations. We estimate the implications for BBN for a range of cosmologically interesting $\delta m^2$ values. The present paper improves on previous published work by taking into account the finite repopulation rate and the time dependence of the distortions to the neutrino momentum distributions. The treatment of chemical decoupling is also improved.Comment: Expanded discussion on the sign of the neutrino asymmetr