Ionic profiles close to dielectric discontinuities: Specific ion-surface interactions

We study, by incorporating short-range ion-surface interactions, ionic profiles of electrolyte solutions close to a non-charged interface between two dielectric media. In order to account for important correlation effects close to the interface, the ionic profiles are calculated beyond mean-field theory, using the loop expansion of the free energy. We show how it is possible to overcome the well-known deficiency of the regular loop expansion close to the dielectric jump, and treat the non-linear boundary conditions within the framework of field theory. The ionic profiles are obtained analytically to one-loop order in the free energy, and their dependence on different ion-surface interactions is investigated. The Gibbs adsorption isotherm, as well as the ionic profiles are used to calculate the surface tension, in agreement with the reverse Hofmeister series. Consequently, from the experimentally-measured surface tension, one can extract a single adhesivity parameter, which can be used within our model to quantitatively predict hard to measure ionic profiles.Comment: 14 pages, 6 figure

Not a Tiger but a Dagger: The Larva of Comachara Cadburyi and Reassignment of the Genus to Acronictinae (Lepidoptera: Noctuidae)

Comachara cadburyi Franclemont has benn classified as a sarrothripine (Noctuidae), lithosiine (Arctiidae), and afridine (Nolidae). Larval morphology and behavior indicate a close phylogenetic relationship with Polygrammate hebraeicum Hübner, an acronictine noctuid. The egg and larva of Comachara are described and illustrated with line drawings and scanning electron micrographs. Photographs of last instars of both Comachara and Polygrammate are provided. Larval feeding and pupation habits of C. cadburyi are briefly described and compared with those of Polygrammate. Larvae of both Polygrammate and Comachara exhibit a dramatic coloration change in the last instar, transitioning from a green phase to a mottled, steely gray form. As the color change progresses, the larva ceases feeding and enters a wandering phase, during which it seeks out wood in which to pupate. Interpretation of L group setal homologies on the ninth abdominal segment is briefly addressed. Comachara provides a poignant example of the importance of immatures in elucidating phylogeny - adult features of Comachara misled a number of the twentieth century century\u27s finest lepidopterists

Predicting Foot Positions for Manual Materials Handling Tasks

Copyright © 2005 SAE International For many industrial tasks (push, pull, lift, carry, etc.), restrictions on grip locations and visibility constrain the hand and head positions and help to define feasible postures. In contrast, often the foot locations are minimally constrained and an ergonomics analyst can choose several different stances in selecting a posture to analyze. Also, because stance can be a critical determinant of a biomechanical assessment of the work posture, the lack of a valid method for placing the feet of a manikin with respect to the task compromises the accuracy of the analysis. To address this issue, foot locations and orientations were captured in a laboratory study of sagittal plane and asymmetric manual load transfers. A pilot study with four volunteers of varying anthropometry approached a load located on one of three shelves and transferred the load to one of six shelves. The data illustrate foot placements and behaviors that depend on pickup heights, the use of one or two hands to grasp the object, and the participantsʼ body dimensions. Two distinct pickup and delivery strategies were observed. Split stance, with one foot in front of the other, was markedly more frequent than parallel stance with the feet side by side. A statistical model was developed to predict foot placements at load pickup. This study confirms the importance of this topic and provides the basis for the much more comprehensive study that is now underway

Electrochemical and optical aspects of cobalt meso-carbazole substituted porphyrin complexes

A series of cobalt (II) porphyrin complexes modified with carbazole rings at one or more meso positions of the macrocycle were synthesized and characterized as to their spectroscopic and basic electrochemical properties in non-aqueous media. The effect of the number and position (syn and anti) of carbazole groups on the complexes properties were investigated. The comparison was made to cobalt (II) porphyrin containing mesityl groups at the meso-positions. The relation between the site of redox processes in cobalt meso-carbazole substituted porphyrins were analysed. It was shown that the conjugated π-ring system of the porphyrin macrocycle, the cobalt central metal ion and the carbazole peripheral substituents are redox-active

Mixing of Supersonic Streams

The Strutjet approach to Rocket Based Combined Cycle (RBCC) propulsion depends upon fuel-rich flows from the rocket nozzles and turbine exhaust products mixing with the ingested air for successful operation in the ramjet and scramjet modes. A model of the Strutjet device has been built and is undergoing test to investigate the mixing of the streams as a function of distance from the Strutjet exit plane. Initial cold flow testing of the model is underway to determine both, the behavior of the ingested air in the duct and to validate the mixing diagnostics. During the tests, each of the two rocket nozzles ejected up to two pounds mass per second into the 13.6 square inch duct. The tests showed that the mass flow of the rockets was great enough to cause the entrained air to go sonic at the strut, which is the location of the rocket nozzles. More tests are necessary to determine whether the entrained air chokes due to the reduction in the area of the duct at the strut (a physical choke), or because of the addition of mass inside the duct at the nozzle exit (a Fabri choke). The initial tests of the mixing diagnostics are showing promise

Intravenous digoxin as a bioavailability standard

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/116960/1/cpt1975171117.pd