Low temperature plasma-catalytic NOx synthesis in a packed DBD reactor: effect of support materials and supported active metal oxides

The direct synthesis of NOx from N2 and O2 by non-thermal plasma at an atmospheric pressure and low temperature is presented, which is considered to be an attractive option for replacement of the Haber-Bosch process. In this study, the direct synthesis of NOx was studied by packing different catalyst support materials in a dielectric barrier discharge (DBD) reactor. The support materials and their particle sizes both had a significant effect on the concentration of NOx. This is attributed to different surface areas, relative dielectric constants and particles shapes. The nitrogen could be fixed at substantially lowered temperatures by employing non-thermal plasma-catalytic DBD reactor, which can be used as an alternative technology for low temperature synthesis. The γ-Al2O3 with smallest particles size of 250–160 μm, gave the highest concentration of NOx and the lowest specific energy consumption of all the tested materials and particle sizes. The NOx concentration of 5700 ppm was reached at the highest residence time of 0.4 s and an N2/O2 feed ratio of 1 was found to be the most optimum for NOx production. In order to intensify the NOx production in plasma, a series of metal oxide catalysts supported on γ-Al2O3 were tested in a packed DBD reactor. A 5% WO3/γ-Al2O3 catalyst increased the NOx concentration further by about 10% compared to γ-Al2O3, while oxidation catalysts such as Co3O4 and PbO provided a minor (∼5%) improvement. These data suggest that oxygen activation plays a minor role in plasma catalytic nitrogen fixation under the studied conditions with the main role ascribed to the generation of microdischarges on sharp edges of large-surface area plasma catalysts. However, when the loading of active metal oxides was increased to 10%, NO selectivity decreased, suggesting possibility of thermal oxidation of NO to NO2 through reaction with surface oxygen species

Type IIA Orientifold Limit of M-Theory on Compact Joyce 8-Manifold of Spin(7)-Holonomy

We show that M-theory compactified on a compact Joyce 8-manifold of $Spin(7)$-holonomy, which yields an effective theory in $D = 3$ with $\N$ = 1 supersymmetry, admits at some special points in it moduli space a description in terms of type IIA theory on an orientifold of compact Joyce 7-manifold of $G_2$-holonomy. We find the evidence in favour of this duality by computing the massless spectra on both M-thory side and type IIA side. For the latter, we compute the massless spectra by going to the orbifold limit of the Joyce 7-manifold.Comment: 26 pages, 2 eps figures, Latex file, two references and one footnote added, corrected some typo

Pileup Behavior in Sharp Nanoindentation of AISI 1045 Steel

AbstractExperimental measurements have been used to investigate the pileup behavior during nanoindentation with a sharp indenter. The AISI 1045 steels treated by quenching and annealing were examined. The results show that during sharp nanoindentation process, the amount of pileup is related to the residual stress state, the indentation depth and the work hardening. The quenched steel with compressive residual stress will tend to pile up, and the stress-free annealed steel can decrease the pileup height. It is found that the pileup height gradually increases for the two steels as the indentation depth becomes larger. It is also shown that the low work hardening of the two steels can also result in the pileup deformation

Design and application of a multi-modal process tomography system

This paper presents a design and application study of an integrated multi-modal system designed to support a range of common modalities: electrical resistance, electrical capacitance and ultrasonic tomography. Such a system is designed for use with complex processes that exhibit behaviour changes over time and space, and thus demand equally diverse sensing modalities. A multi-modal process tomography system able to exploit multiple sensor modes must permit the integration of their data, probably centred upon a composite process model. The paper presents an overview of this approach followed by an overview of the systems engineering and integrated design constraints. These include a range of hardware oriented challenges: the complexity and specificity of the front end electronics for each modality; the need for front end data pre-processing and packing; the need to integrate the data to facilitate data fusion; and finally the features to enable successful fusion and interpretation. A range of software aspects are also reviewed: the need to support differing front-end sensors for each modality in a generic fashion; the need to communicate with front end data pre-processing and packing systems; the need to integrate the data to allow data fusion; and finally to enable successful interpretation. The review of the system concepts is illustrated with an application to the study of a complex multi-component process

Higher Dimensional Analogues of Donaldson-Witten Theory

We present a Donaldson-Witten type field theory in eight dimensions on manifolds with $Spin(7)$ holonomy. We prove that the stress tensor is BRST exact for metric variations preserving the holonomy and we give the invariants for this class of variations. In six and seven dimensions we propose similar theories on Calabi-Yau threefolds and manifolds of $G_2$ holonomy respectively. We point out that these theories arise by considering supersymmetric Yang-Mills theory defined on such manifolds. The theories are invariant under metric variations preserving the holonomy structure without the need for twisting. This statement is a higher dimensional analogue of the fact that Donaldson-Witten field theory on hyper-K\"ahler 4-manifolds is topological without twisting. Higher dimensional analogues of Floer cohomology are briefly outlined. All of these theories arise naturally within the context of string theory.Comment: 23 Pages, Latex. Our statement that these theories are independent of the metric is corrected to the statement that the theories are invariant under deformations that preserve the holonomy structure of the manifold. We also include more details of the construction of a higher dimensional analogue of Floer theory. Three references are adde

Two-step deterministic remote preparation of an arbitrary quantum state in the whole Hilbert space

We present a two-step exact remote state preparation protocol of an arbitrary qubit with the aid of a three-particle Greenberger-Horne-Zeilinger state. Generalization of this protocol for higher-dimensional Hilbert space systems among three parties is also given. We show that only single-particle von Neumann measurement, local operation and classical communication are necessary. Moreover, since the overall information of the quantum state can be divided into two different parts, which may be at different locations, this protocol may be useful in the quantum information field.Comment: 5 page

STM characterization of the Si-P heterodimer

We use scanning tunneling microscopy (STM) and Auger electron spectroscopy to study the behavior of adsorbed phosphine (PH$_{3}$) on Si(001), as a function of annealing temperature, paying particular attention to the formation of the Si-P heterodimer. Dosing the Si(001) surface with ${\sim}$0.002 Langmuirs of PH$_{3}$ results in the adsorption of PH$_{x}$ (x=2,3) onto the surface and some etching of Si to form individual Si ad-dimers. Annealing to 350$^{\circ}$C results in the incorporation of P into the surface layer to form Si-P heterodimers and the formation of short 1-dimensional Si dimer chains and monohydrides. In filled state STM images, isolated Si-P heterodimers appear as zig-zag features on the surface due to the static dimer buckling induced by the heterodimer. In the presence of a moderate coverage of monohydrides this static buckling is lifted, rending the Si-P heterodimers invisible in filled state images. However, we find that we can image the heterodimer at all H coverages using empty state imaging. The ability to identify single P atoms incorporated into Si(001) will be invaluable in the development of nanoscale electronic devices based on controlled atomic-scale doping of Si.Comment: 6 pages, 4 figures (only 72dpi

Manipulation of magnetization reversal of Ni81Fe19 nanoellipse arrays by tuning the shape anisotropy and the magnetostatic interactions

Two series of highly ordered two-dimensional arrays of Ni81Fe19 nanoellipses were nanofabaricated with different aspect ratios, R, and element separations, S, to investigate the influence of the self-demagnetization and the magnetostatic interaction upon the magnetization reversal. For nanostructures with low shape anisotropy, an additional magnetic easy axis was induced orthogonal to the shape-induced easy axis by reducing the separations along both axes. For the structures with larger shape anisotropy, the switching field distribution/coercivity (SFD/Hc ) was reduced, and for the array with the smallest separations (20 nm and 35 nm along the long and short axes, respectively), coherent rotation of the whole array occurred. The magnitude of both the shape anisotropy and a configurational anisotropy induced by the magnetostatic interactions have been estimated. These results provide some useful information for the design of potential magnetic nanodot logic and for high-density magnetic random access memory