A model for buoyant tephra plumes coupled to lava fountains with an application to the 29th of August 2011 paroxysmal eruption at Mount Etna, Italy

Explosive basaltic eruptions pose significant threats to local communities, regional infrastructures and international airspace. They produce tephra plumes that are often associated with a lava fountain, complicating their dynamics. Consequently, source parameters cannot be easily constrained using traditional formulations. Particularly, mass flow rates (MFRs) derived from height observations frequently differ from field deposit‐derived MFRs. Here, we investigate this discrepancy using a novel integral plume model that explicitly accounts for a lava fountain, which is represented as a hot, coarse‐grained inner plume co‐flowing with a finer‐grained outer plume. The new model shows that a plume associated with a lava fountain shows higher variability in rise height than a standard plume for the same initial MFR depending on initial conditions. The initial grain‐size distribution and the relative size of the lava fountain compared to the surrounding plume are primary controls on the final plume height as they determine the strength of coupling between the two plumes. We apply the new model to the 29th of August 2011 paroxysmal eruption of Mount Etna, Italy. The modelled MFR profile indicates that the field‐derived MFR does not correspond to that at the vent, but rather the MFR just above the lava fountain top. High fallout from the lava fountain results in much of the erupted solid material not reaching the top of the plume. This material deposits to form the proximal cone rather than dispersing in the atmosphere. With our novel model, discrepancies between the two types of observation‐derived MFR can be investigated and understood

Serine-Selective Bioconjugation.

This Communication reports the first general method for rapid, chemoselective, and modular functionalization of serine residues in native polypeptides, which uses a reagent platform based on the P(V) oxidation state. This redox-economical approach can be used to append nearly any kind of cargo onto serine, generating a stable, benign, and hydrophilic phosphorothioate linkage. The method tolerates all other known nucleophilic functional groups of naturally occurring proteinogenic amino acids. A variety of applications can be envisaged by this expansion of the toolbox of site-selective bioconjugation methods

Chemodivergent Manganese-Catalyzed C–H Activation: Modular Synthesis of Fluorogenic Probes

Bioorthogonal diversification of peptides is generally dependent on impractical prefunctionalization methods. Here, the authors develop a manganese(I)-catalyzed C–H fluorescent labeling with BODIPY probes, which enables the development of activatable fluorophores to image cell function

Controls on explosive-effusive volcanic eruption styles

One of the biggest challenges in volcanic hazard assessment is to understand how and why eruptive style changes within the same eruptive period or even from one eruption to the next at a given volcano. This review evaluates the competing processes that lead to explosive and effusive eruptions of silicic magmas. Eruptive style depends on a set of feedbacks involving interrelated magmatic properties and processes. Foremost of these are magma viscosity, gas loss, and external properties such as conduit geometry. Ultimately, these parameters control the speed at which magmas ascend, decompress and outgas en route to the surface, and thus determine eruptive style and evolution

Transitions between explosive and effusive phases during the cataclysmic 2010 eruption of Merapi volcano, Java, Indonesia

Transitions between explosive and effusive activity are commonly observed during dome-forming eruptions and may be linked to factors such as magma influx, ascent rate and degassing. However, the interplay between these factors is complex and the resulting eruptive behaviour often unpredictable. This paper focuses on the driving forces behind the explosive and effusive activity during the well-documented 2010 eruption of Merapi, the volcano’s largest eruption since 1872. Time-controlled samples were collected from the 2010 deposits, linked to eruption stage and style of activity. These include scoria and pumice from the initial explosions, dense and scoriaceous dome samples formed via effusive activity, as well as scoria and pumice samples deposited during subplinian column collapse. Quantitative textural analysis of groundmass feldspar microlites, including measurements of areal number density, mean microlite size, crystal aspect ratio, groundmass crystallinity and crystal size distribution analysis, reveal that shallow pre- and syn-eruptive magmatic processes acted to govern the changing behaviour during the eruption. High-An (up to ∼80 mol% An) microlites from early erupted samples reveal that the eruption was likely preceded by an influx of hotter or more mafic magma. Transitions between explosive and effusive activity in 2010 were driven primarily by the dynamics of magma ascent in the conduit, with degassing and crystallisation acting via feedback mechanisms, resulting in cycles of effusive and explosive activity. Explosivity during the 2010 eruption was enhanced by the presence of a ‘plug’ of cooled magma within the shallow magma plumbing system, which acted to hinder degassing, leading to overpressure prior to initial explosive activity

A model for eruption frequency of upper crustal silicic magma chambers

Whether a magma body is able to produce eruptions and at what frequency remains a challenging problem in volcanology as it involves the nonlinear interplay of different processes acting over different time scales. Due to their complexity these are often considered independently in spite of their coupled nature. Here we consider an idealized model that focuses on the evolution of the thermodynamic state of the chamber (pressure, temperature, gas and crystal content) as new magma is injected into the chamber. The magma chamber cools in contact with the crust, which responds viscoelastically to the pressure accumulated during recharge and volatile exsolution. The magma is considered eruptible if the crystal volume fraction is smaller than 0.5. If a critical overpressure is reached, mass is released from the magma chamber until the lithostatic pressure is recovered. The setup of the model allows for rapid calculations that provide the opportunity to test the influence of competing processes on the evolution of the magma reservoir. We show how the frequency of eruptions depends on the timescale of injection, cooling, and viscous relaxation and develop a scaling law that relates these timescales to the eruption frequency. Based on these timescales we place different eruption triggering mechanisms (second boiling, mass injection, and buoyancy) in a coherent framework and evaluate the conditions needed to grow large magma reservoirs