Improved magnesia for thermal control coatings

Formation of radiation-generated color centers using single crystals of magnesium oxide is discussed. Crystal structure of magnesium oxide is described. Chemical processes used to produce magnesium oxide with desired color center kinetics are presented. Proton irradiation of magnesium oxide crystals was conducted to determine lattice defects

Gamow Shell-Model Description of Weakly Bound and Unbound Nuclear States

Recently, the shell model in the complex k-plane (the so-called Gamow Shell Model) has been formulated using a complex Berggren ensemble representing bound single-particle states, single-particle resonances, and non-resonant continuum states. In this framework, we shall discuss binding energies and energy spectra of neutron-rich helium and lithium isotopes. The single-particle basis used is that of the Hartree-Fock potential generated self-consistently by the finite-range residual interaction.Comment: 13 pages, 2 figures, presented by N. Michel at the XXVII Symposium On Nuclear Physics, Taxco, Guerrero, Mexico, January 5-8 200

Drell-Yan Production at NNLL'+NNLO Matched to Parton Showers

We present results for Drell-Yan production from the GENEVA Monte-Carlo framework. We combine the fully-differential NNLO calculation with higher-order resummation in the 0-jettiness resolution variable. The resulting parton-level events are further combined with parton showering and hadronization provided by PYTHIA8. The 0-jettiness resummation is carried out to NNLL', which consistently incorporates all singular virtual and real NNLO corrections. It thus provides a natural perturbative connection between the NNLO calculation and the parton shower regime, including a systematic assessment of perturbative uncertainties. In this way, inclusive observables are correct to NNLO, up to small power corrections in the resolution cutoff. Furthermore, the perturbative accuracy of 0-jet-like resummation variables is significantly improved beyond the parton shower approximation. We provide comparisons with LHC measurements of Drell-Yan production at 7 TeV from ATLAS, CMS, and LHCb. As already observed in $e^+e^-$ collisions, for resummation-sensitive observables, the agreement with data is noticeably improved by using a lower value of $\alpha_s(M_Z) = 0.1135$.Comment: 26 pages, 20 figure

Electrothermal feedback in superconducting nanowire single-photon detectors

We investigate the role of electrothermal feedback in the operation of superconducting nanowire single-photon detectors (SNSPDs). It is found that the desired mode of operation for SNSPDs is only achieved if this feedback is unstable, which happens naturally through the slow electrical response associated with their relatively large kinetic inductance. If this response is sped up in an effort to increase the device count rate, the electrothermal feedback becomes stable and results in an effect known as latching, where the device is locked in a resistive state and can no longer detect photons. We present a set of experiments which elucidate this effect, and a simple model which quantitatively explains the results

Gamow Shell Model Description of Neutron-Rich Nuclei

This work presents the first continuum shell-model study of weakly bound neutron-rich nuclei involving multiconfiguration mixing. For the single-particle basis, the complex-energy Berggren ensemble representing the bound single-particle states, narrow resonances, and the non-resonant continuum background is taken. Our shell-model Hamiltonian consists of a one-body finite potential and a zero-range residual two-body interaction. The systems with two valence neutrons are considered. The Gamow shell model, which is a straightforward extension of the traditional shell model, is shown to be an excellent tool for the microscopic description of weakly bound systems. It is demonstrated that the residual interaction coupling to the particle continuum is important; in some cases, it can give rise to the binding of a nucleus.Comment: 4 pages, More realistic s.p. energies used than in the precedent versio

Sustainable membrane-coated electrodes for CO2 electroreduction to methanol in alkaline media

CO2 electroreduction has high potential to combine carbon capture utilization and energy storage from renewable sources. The key challenge is the construction of highly efficient electrodes giving optimal CO2 conversion to high-value products. In this regard, research on electrode structures remains as an important task to face. Despite the advancements in gas diffusion electrodes (GDEs) to facilitate CO2 transfer and electrode efficiency, the catalyst is still vulnerable to be swept by the gas and liquid electrolyte, reducing the stability. We report the fabrication of novel membrane-coated electrodes (MCEs), by coating an anion exchange membrane over a copper (Cu):chitosan (CS) catalyst layer onto the carbon paper. CS and poly(vinyl) alcohol (PVA) were chosen for membrane preparation and catalyst binder, where Cu was embedded in the polymer matrix as nanoparticles or ion-exchanged in a layered stannosilicate or zeolite Y, to improve their hydrophilic, conductive, mechanical, and environmentally-friendly properties considered relevant to the sustainability of the electrode fabrication and performance. The intimate connection between the CS:PVA polymer membrane over-layer and the CS/Cu catalytic layer protects the MCEs from material losses, enhancing the CO2 conversion to methanol, even in high alkaline medium. A maximum Faraday Efficiency to methanol of 68.05% was achieved for the 10CuY/CS:PVA membrane over-layer.Financial support from the Spanish Ministry of Science and Universities under project grant CTQ2016-76231-C2-1-R is gratefully acknowledged

Proton-Induced and Electron-Induced X-Ray Microanalysis of Insulin-Secreting Cells

Elemental redistribution induced by insulin secretion, was investigated by electron and proton probe X-ray microanalysis. In particular, ion fluxes following immediately upon stimulation were studied. As the sensitivity of the electron probe was insufficient, the proton microprobe was employed. In order to see whether the cell is asymmetric with respect to Ca2+ influx, the cells were stimulated in the presence of Sr2+ (as a Ca2+ analog). Insulin-secreting cells (RINm5F cells and isolated mouse β-cells) were cultured on grids and shock-frozen at 2-30 seconds after stimulation. In a large number of cells, the major elements and and large fluxes were analyzed by the electron microprobe. In the proton microprobe, selected cells were analyzed and elemental maps were compared with electron micrographs of the same cells. The proton microprobe, but not the electron microprobe, could detect an influx of Sr in response to K+-stimulation for 2 seconds, in RINm5F-cells. No polarization of Sr2+ uptake in RINm5F-cells could be detected, and the β-cells did not respond to high K+ by uptake of Sr. Momentary stimulation of β-cells also resulted in a significant increase in Na, detected by the electron probe. Spreading of the β-cells on the substrate appears to influence the subcellular elemental distribution. Thus, the proton probe has potential to detect small changes in elements such as those occurring after short-time stimulation