421 research outputs found

    Gewaltstraftäter mit und ohne Antisoziale Persönlichkeitsstörung: Ein Vergleich

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    Zusammenfassung: Hintergrund: Die diagnostische Wertigkeit von wiederholten Gesetzesübertretungen im Kontext der Antisozialen Persönlichkeitsstörung (ASPD) wird seit längerem kritisch diskutiert. Um festzustellen, ob sich Probanden mit einer ASPD auch abseits straffälligen Verhaltens von Straftätern unterscheiden, wurden inhaftierte Straftäter mit und ohne diese Diagnose untersucht. Material und Methoden: Sechsunddreißig inhaftierte Gewalttäter mit der Diagnose einer ASPD sowie 29 Gewaltstraftäter ohne ASPD der Justizvollzugsanstalt Straubing nahmen an der Studie teil. Die 28 strafrechtlich unauffälligen Kontrollprobanden wurden aus der deutschen Normalbevölkerung rekrutiert. Alle Probanden wurden hinsichtlich soziodemographischer, kriminologischer und klinischer Eigenschaften mit dem SKID-I und SKID-II, dem GAF, BIS-11, K-FAF und EPI untersucht. Ergebnisse: Gewaltstraftäter mit ASPD unterscheiden sich bezüglich folgender Parameter von Delinquenten ohne diese Diagnose: erhöhte Erregbarkeit, niedriges psychosoziales Funktionsniveau, gehäufte "Broken-home-Merkmale" und antisoziales Verhalten vor dem 11.Lebensjahr ("early starters"). Schlussfolgerung: Es konnten Merkmale identifiziert werden, die zwischen Gewaltstraftätern mit und ohne ASPD unterscheiden. In der Gesamtschau scheint allerdings weniger eine kategoriale als vielmehr eine dimensionale, d.h. am Ausprägungsgrad der Auffälligkeiten ausgerichtete Unterscheidung zwischen Gewaltstraftätern mit und ohne ASPD sinnvoll zu sei

    PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift

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    Pd/ZnO/Al2O3 catalysts were studied for water-gas-shift (WGS), methanol steam reforming, and reverse-water-gas-shift (RWGS) reactions. WGS activity was found to be dependent on the Pd:Zn ratio with a maximum activity obtained at approximately 0.50, which was comparable to that of a commercial Pt-based catalyst. The catalyst stability was demonstrated for 100 hours time-on-stream at a temperature of 360ÂşC without evidence of metal sintering. WGS reaction rates were approximately 1st order with respect to CO concentration, and kinetic parameters were determined to be Ea = 58.3 kJ mol-1 and k0 = 6.1x107 min-1. During methanol steam reforming, the CO selectivities were observed to be lower than the calculated equilibrium values over a range of temperatures and steam/carbon ratios studied while the reaction rate constants were approximately of the same magnitude for both WGS and methanol steam reforming. These results indicate that although Pd/ZnO/Al2O3 are active WGS catalysts, WGS is not involved in methanol steam reforming. RWGS rate constants are on the order of about 20 times lower than that of methanol steam reforming, suggesting that RWGS reaction could be one of the sources for small amount of CO formation in methanol steam reforming

    Managers’ resources for authentic leadership – A multi-study exploration of positive psychological capacities and ethical organizational climates

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    While authentic leadership is highly valued in today’s business world, managers do not necessarily have the resources to attain it. Building on conservation of resources theory, we propose a conceptual model to address how personal and contextual resources predict authentic leadership. Study 1 analyzes the day-to-day variability in managers’ positive psychological capacities as personal resources in relation to changes in authentic leadership. In addition, it tests ethical organizational climates as stable, contextual resources for authentic leadership. In Study 2, we replicate our results on the between-person level and extend the research model by exploring promotion focus as a link in the relationship between personal resources and authentic leadership. Evidence from an experience sampling study with 89 managers surveyed daily on 10 consecutive work days (Study 1) and a field survey of 130 managers at two points in time (Study 2) supports the hypothesized role of personal resources and promotion focus for authentic leadership. In both studies, only principled but not benevolent ethical organizational climates emerged as a contextual resource for authentic leadership. We discuss the implications for current management research and practice

    Social presence and dishonesty in retail

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    Self-service checkouts (SCOs) in retail can benefit consumers and retailers, providing control and autonomy to shoppers independent from staff, together with reduced queuing times. Recent research indicates that the absence of staff may provide the opportunity for consumers to behave dishonestly, consistent with a perceived lack of social presence. This study examined whether a social presence in the form of various instantiations of embodied, visual, humanlike SCO interface agents had an effect on opportunistic behaviour. Using a simulated SCO scenario, participants experienced various dilemmas in which they could financially benefit themselves undeservedly. We hypothesised that a humanlike social presence integrated within the checkout screen would receive more attention and result in fewer instances of dishonesty compared to a less humanlike agent. This was partially supported by the results. The findings contribute to the theoretical framework in social presence research. We concluded that companies adopting self-service technology may consider the implementation of social presence in technology applications to support ethical consumer behaviour, but that more research is required to explore the mixed findings in the current study.<br/

    Experimental and theoretical investigation of ligand effects on the synthesis of ZnO nanoparticles

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    ZnO nanoparticles with highly controllable particle sizes(less than 10 nm) were synthesized using organic capping ligands in Zn(Ac)2 ethanolic solution. The molecular structure of the ligands was found to have significant influence on the particle size. The multi-functional molecule tris(hydroxymethyl)-aminomethane (THMA) favoured smaller particle distributions compared with ligands possessing long hydrocarbon chains that are more frequently employed. The adsorption of capping ligands on ZnnOn crystal nuclei (where n = 4 or 18 molecular clusters of(0001) ZnO surfaces) was modelled by ab initio methods at the density functional theory (DFT) level. For the molecules examined, chemisorption proceeded via the formation of Zn...O, Zn...N, or Zn...S chemical bonds between the ligands and active Zn2+ sites on ZnO surfaces. The DFT results indicated that THMA binds more strongly to the ZnO surface than other ligands, suggesting that this molecule is very effective at stabilizing ZnO nanoparticle surfaces. This study, therefore, provides new insight into the correlation between the molecular structure of capping ligands and the morphology of metal oxide nanostructures formed in their presence

    Is satisficing really satisfying? Satisficers exhibit greater threat than maximizers during choice overload.

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    When selecting from too many options (i.e., choice overload), maximizers (people who search exhaustively to make decisions that are optimal) report more negative post-decisional evaluations of their choices than do satisficers (people who search minimally to make decisions that are sufficient). Although ample evidence exists for differences in responses after-the-fact, little is known about possible divergences in maximizers' and satisficers' experiences during choice overload. Thus, using the biopsychosocial model of challenge/threat, we examined 128 participants' cardiovascular responses as they actively made a selection from many options. Specifically, we focused on cardiovascular responses assessing the degree to which individuals (a) viewed their decisions as valuable/important and (b) viewed themselves as capable (vs. incapable) of making a good choice. Although we found no differences in terms of the value individuals placed on their decisions (i.e., cardiovascular responses of task engagement), satisficers-compared to maximizers-exhibited cardiovascular responses consistent with feeling less capable of making their choice (i.e., greater relative threat). The current work provides a novel investigation of the nature of differences in maximizers'/satisficers' momentary choice overload experiences, suggesting insight into why they engage in such distinct search behaviors
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