Half-Life of 14^{14}O

We have measured the half-life of $^{14}$O, a superallowed $(0^{+} \to 0^{+})$ $\beta$ decay isotope. The $^{14}$O was produced by the $^{12}$C($^{3}$He,n)$^{14}$O reaction using a carbon aerogel target. A low-energy ion beam of $^{14}$O was mass separated and implanted in a thin beryllium foil. The beta particles were counted with plastic scintillator detectors. We find $t_{1/2} = 70.696\pm 0.052$ s. This result is $1.5\sigma$ higher than an average value from six earlier experiments, but agrees more closely with the most recent previous measurement.Comment: 10 pages, 5 figure

Water exchange at a hydrated platinum electrode is rare and collective

We use molecular dynamics simulations to study the exchange kinetics of water molecules at a model metal electrode surface -- exchange between water molecules in the bulk liquid and water molecules bound to the metal. This process is a rare event, with a mean residence time of a bound water of about 40 ns for the model we consider. With analysis borrowed from the techniques of rare-event sampling, we show how this exchange or desorption is controlled by (1) reorganization of the hydrogen bond network within the adlayer of bound water molecules, and by (2) interfacial density fluctuations of the bulk liquid adjacent to the adlayer. We define collective coordinates that describe the desorption mechanism. Spatial and temporal correlations associated with a single event extend over nanometers and tens of picoseconds.Comment: 10 pages, 9 figure

Nonlinear Dynamics of Capacitive Charging and Desalination by Porous Electrodes

The rapid and efficient exchange of ions between porous electrodes and aqueous solutions is important in many applications, such as electrical energy storage by super-capacitors, water desalination and purification by capacitive deionization (or desalination), and capacitive extraction of renewable energy from a salinity difference. Here, we present a unified mean-field theory for capacitive charging and desalination by ideally polarizable porous electrodes (without Faradaic reactions or specific adsorption of ions) in the limit of thin double layers (compared to typical pore dimensions). We illustrate the theory in the case of a dilute, symmetric, binary electrolyte using the Gouy-Chapman-Stern (GCS) model of the double layer, for which simple formulae are available for salt adsorption and capacitive charging of the diffuse part of the double layer. We solve the full GCS mean-field theory numerically for realistic parameters in capacitive deionization, and we derive reduced models for two limiting regimes with different time scales: (i) In the "super-capacitor regime" of small voltages and/or early times where the porous electrode acts like a transmission line, governed by a linear diffusion equation for the electrostatic potential, scaled to the RC time of a single pore. (ii) In the "desalination regime" of large voltages and long times, the porous electrode slowly adsorbs neutral salt, governed by coupled, nonlinear diffusion equations for the pore-averaged potential and salt concentration

eMIL: advanced emission Mössbauer spectrometer for measurements in versatile conditions

The current work presents a contemporary design of an advanced emission Mössbauer Spectrometer: eMIL equipped with a parallel-plate avalanche detector, which has been devised and built for the Mössbauer collaboration at ISOLDE/CERN. The setup is based on emission geometry, combined with on-line/off-line isotope implantation and provides numerous advantages over conversion electron, common emission (where isotope is deposited chemically on a sample) or transmission Mössbauer spectroscopy. eMIL is designed to measure hyperfine interactions in solids under various exposures. The implemented design overcomes limitations and improves performance and handling. In the current revision, the chamber is supplied with an UV extension — allowing to perform studies of photo-catalytic materials under external light exposure. A specifically designed motorized lid-samples-holder is fully automatized, and makes it possible to study up to 4 samples loaded in a magazine within a temperature range from RT up to 1100 K and to perform angular dependent measurements in high vacuum. This work additionally briefly describes data acquisition with additional electronic blocks, vacuum and data-acquisition system construction

Lengthscale effects on exchange coupling in Co-Pt L10 + L12 nanochessboards

The Co-Pt nanochessboard is a quasi-periodic, nanocomposite tiling of L10 and L12 magnetic phases that offers a novel structure for the investigation of exchange coupling, relevant to permanent magnet applications. Periodicity of the tiling is controlled by the rate of cooling through the eutectoid isotherm, resulting in control over the L10-L12 exchange coupling. First order reversal curve analysis reveals a transition from partial coupling to nearly complete exchange-coupling in a Co40.2Pt59.8 nanochessboard structured alloy as the periodicity is reduced below the critical correlation length. Micromagnetic simulations give insights into how exchange coupling manifests in the tiling, and its impact on microscopic magnetization reversal mechanisms

Coherent amplification of classical pion fields during the cooling of droplets of quark plasma

In the framework of the linear sigma model, we study the time evolution of a system of classical $\sigma$ and pion fields coupled to quarks. For this purpose we solve numerically the classical transport equation for relativistic quarks coupled to the nonlinear Klein-Gordon equations for the meson fields. We examine evolution starting from variety of initial conditions corresponding to spherical droplets of hot quark matter, which might mimic the behaviour of a quark plasma produced in high-energy nucleus-nucleus collisions. For large droplets we find a strong amplification of the pion field that oscillates in time. This leads to a coherent production of pions with a particular isospin and so would have similar observable effects to a disoriented chiral condensate which various authors have suggested might be a signal of the chiral phase transition. The mechanism for amplification of the pion field found here does not rely on this phase transition and is better thought of as a "pion laser" which is driven by large oscillations of the $\sigma$ field.Comment: 12 TeX pages + 20 postscript figures, psfig styl

Vlasov Description Of Dense Quark Matter

We discuss properties of quark matter at finite baryon densities and zero temperature in a Vlasov approach. We use a screened interquark Richardson's potential consistent with the indications of Lattice QCD calculations. We analyze the choices of the quark masses and the parameters entering the potential which reproduce the binding energy (B.E.) of infinite nuclear matter. There is a transition from nuclear to quark matter at densities 5 times above normal nuclear matter density. The transition could be revealed from the determination of the position of the shifted meson masses in dense baryonic matter. A scaling form of the meson masses in dense matter is given.Comment: 15 pages 4 figure

Precision Study of Positronium: Testing Bound State QED Theory

As an unstable light pure leptonic system, positronium is a very specific probe atom to test bound state QED. In contrast to ordinary QED for free leptons, the bound state QED theory is not so well understood and bound state approaches deserve highly accurate tests. We present a brief overview of precision studies of positronium paying special attention to uncertainties of theory as well as comparison of theory and experiment. We also consider in detail advantages and disadvantages of positronium tests compared to other QED experiments.Comment: A talk presented at Workshop on Positronium Physics (ETH Zurich, May 30-31, 2003

Coded Aperture and Compton Imaging for the Development of 225^{225}Ac-based Radiopharmaceuticals

Targeted alpha-particle therapy (TAT) has great promise as a cancer treatment. Arguably the most promising TAT radionuclide that has been proposed is $^{225}$Ac. The development of $^{225}$Ac-based radiopharmaceuticals has been hampered due to the lack of effective means to study the daughter redistribution of these agents in small animals at the preclinical stage. The ability to directly image the daughters, namely $^{221}$Fr and $^{213}$Bi, via their gamma-ray emissions would be a boon for preclinical studies. That said, conventional medical imaging modalities, including single photon emission computed tomography (SPECT) based on pinhole collimation, cannot be employed due to sensitivity limitations. As an alternative, we propose the use of both coded aperture and Compton imaging with the former modality suited to the 218-keV gamma-ray emission of $^{221}$Fr and the latter suited to the 440-keV gamma-ray emission of $^{213}$Bi. This work includes coded aperture images of $^{221}$Fr and Compton images of $^{213}$Bi in tumor-bearing mice injected with $^{225}$Ac-based radiopharmaceuticals. These results are the first demonstration of visualizing and quantifying the $^{225}$Ac daughters in small animals via coded aperture and Compton imaging and serve as a stepping stone for future radiopharmaceutical studies