Sulphur and nitrogen fluxes and budgets in the Bohemian Forest and Tatra Mountains during the Industrial Revolution (1850-2000)

International audienceMajor fluxes of sulphur and dissolved inorganic nitrogen were estimated in Central European mountain ecosystems of the Bohemian Forest (forest lakes) and Tatra Mountains (alpine lakes) over the industrial period. Sulphur outputs from these ecosystems were comparable to inputs during a period of relatively stable atmospheric deposition (10-35 mmol m-2 yr-1) around the 1930s. Atmospheric inputs of sulphur increased by three- to four-fold between the 1950s and 1980s to ~140 and ~60 mmol mm-2 yr-1 in the Bohemian Forest and Tatra Mountains, respectively. Sulphur outputs were lower than inputs due to accumulation in soils, which was higher in forest soils than in the sparser alpine soils and represented 0.8-1.6 and 0.2-0.3 mol m-2, respectively, for the whole 1930-2000 period. In the 1990s, atmospheric inputs of sulphur decreased 80% and 50% in the Bohemian Forest and Tatra Mountains, respectively, and sulphur outputs exceeded inputs. Catchment soils became pronounced sources of sulphur with output fluxes averaging between 15 and 31 mmol m-2 yr-1. Higher sulphur accumulation in the forest soils has delayed (by several decades) recovery of forest lakes from acidification compared to alpine lakes. Estimated deposition of dissolved inorganic nitrogen was 53-75 mmol m-2 yr-1 in the Bohemian Forest and 35-45 mmol m-2 yr-1 in the Tatra Mountains in the 1880- 1950 period, i.e. below the empirically derived threshold of ~70 mmol m-2 yr-1, above which nitrogen leaching often occurs. Dissolved inorganic nitrogen was efficiently retained in the ecosystems and nitrate export was negligible (0-7 mmol m-2 yr-1). By the 1980s, nitrogen deposition increased to ~160 and ~80 mmol m-2 yr-1 in the Bohemian Forest and Tatra Mountains, respectively, and nitrogen output increased to 120 and 60 mmol m-2 yr-1. Moreover, assimilation of nitrogen in soils declined from ~40 to 10-20 mmol m-2 yr-1 in the alpine soils and even more in the Bohemian Forest, where one of the catchments has even become a net source of nitrogen. In the 1990s, nitrogen deposition decreased by ~30% and DIN output decreased to -2 yr-1 in the Bohemian Forest and Tatra Mountains, respectively. New steady-state conditions, with negligible nitrogen export, could be reached in future but at lower nitrogen depositions than in the 1930s. Keywords: emission, deposition, acidification, nitrogen-saturation, recovery, sulphate, nitrate, ammonium, mountain lake

Giant Monopole Resonances and nuclear incompressibilities studied for the zero-range and separable pairing interactions

Background: Following the 2007 precise measurements of monopole strengths in tin isotopes, there has been a continuous theoretical effort to obtain a precise description of the experimental results. Up to now, there is no satisfactory explanation of why the tin nuclei appear to be significantly softer than 208Pb. Purpose: We determine the influence of finite-range and separable pairing interactions on monopole strength functions in semi-magic nuclei. Methods: We employ self-consistently the Quasiparticle Random Phase Approximation on top of spherical Hartree-Fock-Bogolyubov solutions. We use the Arnoldi method to solve the linear-response problem with pairing. Results: We found that the difference between centroids of Giant Monopole Resonances measured in lead and tin (about 1 MeV) always turns out to be overestimated by about 100%. We also found that the volume incompressibility, obtained by adjusting the liquid-drop expression to microscopic results, is significantly larger than the infinite-matter incompressibility. Conclusions: The zero-range and separable pairing forces cannot induce modifications of monopole strength functions in tin to match experimental data.Comment: 11 RevTeX pages, 16 figures, 1 table, extended versio

Modelling reversibility of Central European mountain lakes from acidification: Part I - the Bohemian forest

International audienceA dynamic, process-based acidification model, MAGIC7, has been applied to three small, strongly acidified lakes in the Bohemian Forest, the Czech Republic. The model was calibrated for a set of experimental records on lake water composition over the 1984?2000 period, and produced hindcast concentrations that compared well, even with older (40-year) irregular determinations of nitrate, chloride and pH. Water and soil chemistry forecasts up to 2050 were based on reductions in S and N emissions presupposed by the Gothenburg Protocol. Modelled sulphate and chloride concentrations were predicted to decrease to the levels at the beginning of the 20th century by 2050. The lake water carbonate buffering system is predicted to be re-established in only two lakes (Cerné and Ple?né), with current soil base saturations of 12-15%. Concentrations of ionic aluminium species decreased sharply, from 110 ?eq l-1 in the mid-1980s to the current ~40 ?eq l-1, and were predicted to decrease below 10 ?eq l-1 in the 2020s. Diatom-inferred pH in pre-industrial times was substantially lower than modelled pH. It is suggested that the diatom pH, based almost entirely on non-planktonic species, is biased by inwash of diatoms from more acidic tributaries into the sediment of these small lakes. Generally significant results can be summarised as follows: (1) Simulated sulphate levels agree well with observations during acidification progress and retreat only for values of soil SO42- adsorption capacity three to six times (20 to 40 ?eq kg-1) higher than those found experimentally. This implies a further mechanism of S retention and release in addition to physical sulphate adsorption to Fe and Al oxides of soils. (2) The catchments' ability to retain deposited N appeared to decline after ~1950 but this was not connected with a sufficient change in the C:N ratio of the soils. Agreement between modelled and observed concentrations of nitrate was therefore achieved by empirical restriction of N retention in the soils. Based on their current ability to retain N, the catchments will remain N-saturated and could, temporarily, produce more inorganic N than they receive due to additional nitrate production from soil N-organic pools. This situation has occurred already in the Cerné Lake catchment. (3) Differences in responses of individual lakes can be attributed to different land usages over the past several centuries as well as to differences in geology and primary production. Keywords: MAGIC, atmospheric deposition, N retention, diatom-inferred pH, sulphate, nitrate, base cations, aluminium, Czech Republi

Chaos in a modified Henon-Heiles system describing geodesics in gravitational waves

A Hamiltonian system with a modified Henon-Heiles potential is investigated. This describes the motion of free test particles in vacuum gravitational pp-wave spacetimes with both quadratic ("homogeneous") and cubic ("non-homogeneous") terms in the structural function. It is shown that, for energies above a certain value, the motion is chaotic in the sense that the boundaries separating the basins of possible escapes become fractal. Similarities and differences with the standard Henon-Heiles and the monkey saddle systems are discussed. The box-counting dimension of the basin boundaries is also calculated.Comment: 11 pages, 7 figures, LaTeX. To appear in Phys. Lett.

Continuous coordinates for all impulsive pp - waves

We present a coordinate system for a general impulsive gravitational pp - wave in vacuum in which the metric is explicitly continuous, synchronous and "transverse". Also, it is more appropriate for investigation of particle motions.Comment: 4 pages, LaTeX, no figures, to be published in Phys. Lett.

Increasing silicon concentrations in Bohemian Forest lakes

International audienceLong-term trends of dissolved silicon (Si) concentrations in five glacial lakes in the Bohemian Forest, Czech Republic, recovering from acidification show higher mobility of Si from the soil to surface waters despite lower atmospheric deposition of acids. Si increased by 0.95 to 1.95 µmol yr-1 (36 to 51%) from 1986-2004 and with increasing pH. A change in soil solution conditions because of a sharp decrease in acidic deposition has led to marked decline in Al mobility and to considerable decreases in dissolved Al, especially Al3+. The increase in Si may be related to: (1) unblocking of the inhibitory effect of dissolved Al on weathering of aluminosilicates, (2) biogenic opal (phytoliths) dissolving faster, and/or (3) lower Si precipitation as secondary aluminosilicates in soil. The change in Al speciation on the dissolution rate of biogenic silica is critical. A lack of change in Si at sites outside central Europe may be explained by small or no decline in mobility of dissolved Al. The effect of a long-term increase in temperature was probably minor

The influence of the shape of a saw-cut notch in quasi-brittle 3PB specimens on the critical applied force

Values of fracture parameters of quasi-brittle building materials are usually determined from results of tests performed on notched testing specimens. The contribution deals with the influence of various shapes of tips of notches prepared by a diamond saw in three point bending (3PB) specimens. The influence of the notch tip shape on the applied force corresponding to a failure initiation at the notch tip and also on the critical applied force appropriate to the maximal load-bearing capacity of the specimen is studied. Calculations are performed in two finite element method (FEM) systems (ATENA, ANSYS) based on two different approaches to fracture description (Cohesive crack models and LEFM, respectively). The numerical results obtained by both FEM systems are compared. The influence of notch shapes and width is quantified

Linear response strength functions with iterative Arnoldi diagonalization

We report on an implementation of a new method to calculate RPA strength functions with iterative non-hermitian Arnoldi diagonalization method, which does not explicitly calculate and store the RPA matrix. We discuss the treatment of spurious modes, numerical stability, and how the method scales as the used model space is enlarged. We perform the particle-hole RPA benchmark calculations for double magic nucleus 132Sn and compare the resulting electromagnetic strength functions against those obtained within the standard RPA.Comment: 9 RevTeX pages, 11 figures, submitted to Physical Review

Hydrogen or Soot?: Partial Oxidation of High-boiling Hydrocarbon Wastes

This paper is focused on researching the influence of process parameters of partial oxidation, such as quality of hydrocarbon raw materials that differ in their stock properties (especially boiling point and viscosity) on the composition of output gas (selectivity of the process), and also on the formation extent of soot which could be used as an excellent and valued sorbent CHEZACARB® and/or filler in the rubber industry, e.g. for automotive tires. The effects of steam flow rate and the oxygen to raw material feed rate ratio is discussed as well. In addition, sensitivity of POX product composition depending on properties of different raw materials and reaction conditions were analysed in this study