156 research outputs found

    Petrogenesis of the early Cretaceous intra-plate basalts from the western North China Craton: Implications for the origin of the metasomatized cratonic lithospheric mantle

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    We present new bulk-rock 40Ar/39Ar age, major and trace elements and Sr-Nd-Hf isotopic data on the early Cretaceous intra-plate alkali basalts from the Western North China Craton (WNCC) to study the origin of the metasomatized cratonic lithosphere mantle. The age of these basalts is ~116 Ma. These basalts have elevated incompatible element abundance with high [La/Sm]N (2.80–4.56) and enriched Sr-Nd-Hf isotopic compositions (87Sr/86Sri = 0.7062–0.7075, εNd(t) = −6.0 to −13.0 and εHf(t) = −8.3 to −17.4), being similar to the contemporary analogues from the Western North China Craton and Paleozoic kimberlites and mantle xenoliths. The WNCC basalts also show good correlations between ɛNd(t) and ɛHf(t), and high [La/Sm]N. All these geochemical observations are consistent with the interpretation that these basalts originated from partial melting of the lithospheric mantle that experienced melt metasomatism. Two types metasomatism melts are required to explain the geochemical characteristics of these rocks. The obvious negative Nbsingle bondTa (compared with K)-Ti and positive Basingle bondPb anomalies observed in these basalts further constrain that one of the metasomatic melts was derived from the subducted terrigenous sediment. Furthermore, the overall higher P/Nd, Nb/La and Nb/Th and lower Lu/Hf of basalts in the WNCC suggest that there is also contribution of low-F melts from asthenosphere mantle. Collectively, we suggest that the formation of the metasomatized lithosphere mantle beneath the WNCC is the process of metasomatic reaction between mantle peridotite and the melts of different origin to generate metasomatic veins containing amphibole/phlogopite. Partial melting of the metasomatic lithospheric mantle at 106–120 Ma in the WNCC was considered to be induced by thermal perturbation that was ultimately related to the breakoff of the subducted oceanic slab following the closure of the Mongolia-Okhotsk ocean

    Manejo do dossel vegetativo e seu efeito nos componentes de produção da videira Merlot.

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    A poda verde é uma prática cultural utilizada para melhorar as condições do dossel vegetativo dos vinhedos, visando a favorecer a qualidade da uva e do vinho. Nesse sentido, realizou-se este experimento entre as safras de 1993/1994 e 1996/1997, com diferentes modalidades de poda verde, num vinhedo do cv. Merlot conduzido em latada. Houve 12 tratamentos e três repetições, sendo o delineamento experimental em blocos casualizados. Os tratamentos constituíram-se da testemunha e de 11 diferentes modalidades de poda verde, ou seja, desbrota, desponta e desfolha, algumas delas em diferentes épocas do ciclo vegetativo da videira. O componente principal 1, da análise de componentes principais (ACP) feita em cada ano, separadamente, mostra que o tratamento 10 (desbrota + desponta + desfolha realizada no início da floração, eliminando-se as folhas abaixo dos cachos) discriminou-se nos quatro anos, e os tratamentos 7 (desfolha realizada 21 dias antes da colheita, eliminando-se metade das folhas abaixo dos cachos) e 6 (desfolha realizada 21 dias antes da colheita, eliminando-se as folhas abaixo dos cachos), em três deles; a ACP da média dos quatro anos também evidencia essa discriminação entre eles. Constata-se que o tratamento 10 foi um dos que tiveram intensidade de poda verde mais intensa, caracterizando-se por variáveis indicativas de plantas com vigor e produtividade mais baixos que os demais

    Analysis of norfloxacin ecotoxicity and the relation with its degradation by means of electrochemical oxidation using different anodes

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    [EN] In this work, ecotoxicological bioassays based on Lactuca sativa seeds and bioluminescent bacterium (Vibrio fischeri) have been carried out in order to quantify the toxicity of Norfloxacin (NOR) and sodium sulfate solutions, before and after treating them using electrochemical advanced oxidation. The effect of some process variables (anode material, reactor configuration and applied current) on the toxicity evolution of the treated solution has been studied. A NOR solution shows an EC50 (5 days) of 336 mg L-1 towards Lactuca sativa. This threshold NOR concentration decreases with sodium sulfate concentration, in solutions that contain simultaneously Norfloxacin and sodium sulfate. In every case considered in this work, the electrochemical advanced oxidation process increased the toxicity (towards both Lactuca sativa and Vibrio fischeri) of the solution. This toxicity increase is mainly due to the persulfate formation during the electrochemical treatment. From a final solution toxicity point of view, the best results were obtained using a BDD anode in a divided reactor applying the lowest current intensity.The authors are very grateful to the Ministerio de Economia y Competitividad (Projects CTQ2015-65202-C2-1-R and RTI2018-101341-B-C21) for their economic support.Montañés, M.; García Gabaldón, M.; Roca-Pérez, L.; Giner-Sanz, JJ.; Mora-Gómez, J.; Pérez-Herranz, V. (2020). Analysis of norfloxacin ecotoxicity and the relation with its degradation by means of electrochemical oxidation using different anodes. Ecotoxicology and Environmental Safety. 188:1-10. https://doi.org/10.1016/j.ecoenv.2019.109923S110188Banks, M. K., & Schultz, K. E. (2005). Comparison of Plants for Germination Toxicity Tests in Petroleum-Contaminated Soils. Water, Air, and Soil Pollution, 167(1-4), 211-219. doi:10.1007/s11270-005-8553-4Barreto, J. P. d. P., Araujo, K. C. d. F., de Araujo, D. M., & Martinez-Huitle, C. A. (2015). Effect of sp3/sp2 Ratio on Boron Doped Diamond Films for Producing Persulfate. ECS Electrochemistry Letters, 4(12), E9-E11. doi:10.1149/2.0061512eelBueno, F., Borba, F. H., Pellenz, L., Schmitz, M., Godoi, B., Espinoza-Quiñones, F. R., … Módenes, A. N. (2018). Degradation of ciprofloxacin by the Electrochemical Peroxidation process using stainless steel electrodes. Journal of Environmental Chemical Engineering, 6(2), 2855-2864. doi:10.1016/j.jece.2018.04.033Carlesi Jara, C., Fino, D., Specchia, V., Saracco, G., & Spinelli, P. (2007). Electrochemical removal of antibiotics from wastewaters. Applied Catalysis B: Environmental, 70(1-4), 479-487. doi:10.1016/j.apcatb.2005.11.035Charles, J., Crini, G., Degiorgi, F., Sancey, B., Morin-Crini, N., & Badot, P.-M. (2013). Unexpected toxic interactions in the freshwater amphipod Gammarus pulex (L.) exposed to binary copper and nickel mixtures. Environmental Science and Pollution Research, 21(2), 1099-1111. doi:10.1007/s11356-013-1978-1Chen, M., & Chu, W. (2012). Degradation of antibiotic norfloxacin in aqueous solution by visible-light-mediated C-TiO2 photocatalysis. Journal of Hazardous Materials, 219-220, 183-189. doi:10.1016/j.jhazmat.2012.03.074Coledam, D. A. C., Aquino, J. M., Silva, B. F., Silva, A. J., & Rocha-Filho, R. C. (2016). Electrochemical mineralization of norfloxacin using distinct boron-doped diamond anodes in a filter-press reactor, with investigations of toxicity and oxidation by-products. Electrochimica Acta, 213, 856-864. doi:10.1016/j.electacta.2016.08.003Da Silva, S. W., Navarro, E. M. O., Rodrigues, M. A. S., Bernardes, A. M., & Pérez-Herranz, V. (2019). Using p-Si/BDD anode for the electrochemical oxidation of norfloxacin. Journal of Electroanalytical Chemistry, 832, 112-120. doi:10.1016/j.jelechem.2018.10.049Davis, J., Baygents, J. C., & Farrell, J. (2014). Understanding Persulfate Production at Boron Doped Diamond Film Anodes. Electrochimica Acta, 150, 68-74. doi:10.1016/j.electacta.2014.10.104Oliveira, G. A. R. de, Leme, D. M., de Lapuente, J., Brito, L. B., Porredón, C., Rodrigues, L. de B., … Oliveira, D. P. de. (2018). A test battery for assessing the ecotoxic effects of textile dyes. Chemico-Biological Interactions, 291, 171-179. doi:10.1016/j.cbi.2018.06.026Drèze, V., Monod, G., Cravedi, J.-P., Biagianti-Risbourg, S., & Le Gac, F. (2000). Ecotoxicology, 9(1/2), 93-103. doi:10.1023/a:1008976431227Flaherty, C. M., & Dodson, S. I. (2005). Effects of pharmaceuticals on Daphnia survival, growth, and reproduction. Chemosphere, 61(2), 200-207. doi:10.1016/j.chemosphere.2005.02.016González-Pleiter, M., Gonzalo, S., Rodea-Palomares, I., Leganés, F., Rosal, R., Boltes, K., … Fernández-Piñas, F. (2013). Toxicity of five antibiotics and their mixtures towards photosynthetic aquatic organisms: Implications for environmental risk assessment. Water Research, 47(6), 2050-2064. doi:10.1016/j.watres.2013.01.020Gustavson, K. E., Sonsthagen, S. A., Crunkilton, R. A., & Harkin, J. M. (2000). Groundwater toxicity assessment using bioassay, chemical, and toxicity identification evaluation analyses. Environmental Toxicology, 15(5), 421-430. doi:10.1002/1522-7278(2000)15:53.0.co;2-zHeberle, A. N. A., Alves, M. E. P., da Silva, S. W., Klauck, C. R., Rodrigues, M. A. S., & Bernardes, A. M. (2019). Phytotoxicity and genotoxicity evaluation of 2,4,6-tribromophenol solution treated by UV-based oxidation processes. Environmental Pollution, 249, 354-361. doi:10.1016/j.envpol.2019.03.057Iniesta, J. (2001). Electrochemical oxidation of phenol at boron-doped diamond electrode. Electrochimica Acta, 46(23), 3573-3578. doi:10.1016/s0013-4686(01)00630-2Larsson, D. G. J., de Pedro, C., & Paxeus, N. (2007). Effluent from drug manufactures contains extremely high levels of pharmaceuticals. Journal of Hazardous Materials, 148(3), 751-755. doi:10.1016/j.jhazmat.2007.07.008Leme, D. M., & Marin-Morales, M. A. (2009). Allium cepa test in environmental monitoring: A review on its application. Mutation Research/Reviews in Mutation Research, 682(1), 71-81. doi:10.1016/j.mrrev.2009.06.002Li, Y., Niu, J., & Wang, W. (2011). Photolysis of Enrofloxacin in aqueous systems under simulated sunlight irradiation: Kinetics, mechanism and toxicity of photolysis products. Chemosphere, 85(5), 892-897. doi:10.1016/j.chemosphere.2011.07.008Liu, P., Zhang, H., Feng, Y., Yang, F., & Zhang, J. (2014). Removal of trace antibiotics from wastewater: A systematic study of nanofiltration combined with ozone-based advanced oxidation processes. Chemical Engineering Journal, 240, 211-220. doi:10.1016/j.cej.2013.11.057Mao, F., He, Y., & Gin, K. (2018). Evaluating the Joint Toxicity of Two Benzophenone-Type UV Filters on the Green Alga Chlamydomonas reinhardtii with Response Surface Methodology. 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Treated wastewater phytotoxicity assessment using Lactuca sativa : Focus on germination and root elongation test parameters. Comptes Rendus Biologies, 340(3), 188-194. doi:10.1016/j.crvi.2017.01.002Radix, P., Léonard, M., Papantoniou, C., Roman, G., Saouter, E., Gallotti-Schmitt, S., … Vasseur, P. (2000). Comparison of Four Chronic Toxicity Tests Using Algae, Bacteria, and Invertebrates Assessed with Sixteen Chemicals. Ecotoxicology and Environmental Safety, 47(2), 186-194. doi:10.1006/eesa.2000.1966Rizzo, L. (2011). Bioassays as a tool for evaluating advanced oxidation processes in water and wastewater treatment. Water Research, 45(15), 4311-4340. doi:10.1016/j.watres.2011.05.035Seco, J. I., Fernández-Pereira, C., & Vale, J. (2003). A study of the leachate toxicity of metal-containing solid wastes using Daphnia magna. Ecotoxicology and Environmental Safety, 56(3), 339-350. doi:10.1016/s0147-6513(03)00102-7Uzu, G., Sobanska, S., Sarret, G., Muñoz, M., & Dumat, C. (2010). 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    The INCREASE project: Intelligent Collections of food‐legume genetic resources for European agrofood systems

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    Food legumes are crucial for all agriculture-related societal challenges, including climate change mitigation, agrobiodiversity conservation, sustainable agriculture, food security and human health. The transition to plant-based diets, largely based on food legumes, could present major opportunities for adaptation and mitigation, generating significant co-benefits for human health. The characterization, maintenance and exploitation of food-legume genetic resources, to date largely unexploited, form the core development of both sustainable agriculture and a healthy food system. INCREASE will implement, on chickpea (Cicer arietinum), common bean (Phaseolus vulgaris), lentil (Lens culinaris) and lupin (Lupinus albus and L. mutabilis), a new approach to conserve, manage and characterize genetic resources. Intelligent Collections, consisting of nested core collections composed of single-seed descent-purified accessions (i.e., inbred lines), will be developed, exploiting germplasm available both from genebanks and on-farm and subjected to different levels of genotypic and phenotypic characterization. Phenotyping and gene discovery activities will meet, via a participatory approach, the needs of various actors, including breeders, scientists, farmers and agri-food and non-food industries, exploiting also the power of massive metabolomics and transcriptomics and of artificial intelligence and smart tools. Moreover, INCREASE will test, with a citizen science experiment, an innovative system of conservation and use of genetic resources based on a decentralized approach for data management and dynamic conservation. By promoting the use of food legumes, improving their quality, adaptation and yield and boosting the competitiveness of the agriculture and food sector, the INCREASE strategy will have a major impact on economy and society and represents a case study of integrative and participatory approaches towards conservation and exploitation of crop genetic resources

    The Fate of an Amazonian Savanna: Government Land-Use Planning Endangers Sustainable Development in Amapá, the Most Protected Brazilian State

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    Although Amapa´ is the most protected Brazilian state, the same level of protection does not extend to its savannas. These are currently suffering increased pressure from threats including large-scale agriculture, particularly the expansion of soybean plantations. In September 2016, the Government of Amapa´ presented a zoning proposal (Zoneamento Socioambiental do Cerrado [ZSC]) that reserves most of the savannas for agricultural activities. Here, we outline how the methodology employed is flawed because it does not include fauna surveys, evaluations of ecosystem services or an assessment of the social importance of the savannas. The ZSC authors admit that, contrary to Brazilian legislation, the zoning was carried out with the single intention of increasing agriculture production. Current knowledge indicates that Amapa´’s savannas are rich in biodiversity, including endemic and threatened species, and are also home to a rich culture of traditional populations. These savannas are important providers of ecosystem services that, if intact, could represent around US$ 1.52 billion annually. We hold that the ZSC should be reformulated, with fair participation of stakeholders, in accordance with Brazil’s legal requirements. At least 30% of the savannas should be protected, local family farming should be supported, and the rights of traditional peoples must now be assured through recognition of their land rights

    The Fate of an Amazonian Savanna: Government Land-Use Planning Endangers Sustainable Development in Amapá, the Most Protected Brazilian State

    Get PDF
    Although Amapa´ is the most protected Brazilian state, the same level of protection does not extend to its savannas. These are currently suffering increased pressure from threats including large-scale agriculture, particularly the expansion of soybean plantations. In September 2016, the Government of Amapa´ presented a zoning proposal (Zoneamento Socioambiental do Cerrado [ZSC]) that reserves most of the savannas for agricultural activities. Here, we outline how the methodology employed is flawed because it does not include fauna surveys, evaluations of ecosystem services or an assessment of the social importance of the savannas. The ZSC authors admit that, contrary to Brazilian legislation, the zoning was carried out with the single intention of increasing agriculture production. Current knowledge indicates that Amapa´’s savannas are rich in biodiversity, including endemic and threatened species, and are also home to a rich culture of traditional populations. These savannas are important providers of ecosystem services that, if intact, could represent around US$ 1.52 billion annually. We hold that the ZSC should be reformulated, with fair participation of stakeholders, in accordance with Brazil’s legal requirements. At least 30% of the savannas should be protected, local family farming should be supported, and the rights of traditional peoples must now be assured through recognition of their land rights
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