Proposal for an Experiment to Test a Theory of High Temperature Superconductors

A theory for the phenomena observed in Copper-Oxide based high temperature superconducting materials derives an elusive time-reversal and rotational symmetry breaking order parameter for the observed pseudogap phase ending at a quantum-critical point near the composition for the highest $T_c$. An experiment is proposed to observe such a symmetry breaking. It is shown that Angle-resolved Photoemission yields a current density which is different for left and right circularly polarized photons. The magnitude of the effect and its momentum dependence is estimated. Barring the presence of domains of the predicted phase an asymmetry of about 0.1 is predicted at low temperatures in moderately underdoped samples.Comment: latex, 2 figure

Topological Excitations near the Local Critical Point in the Dissipative 2D XY model

The dissipative XY model in two spatial dimensions belongs to a new universality class of quantum critical phenomena with the remarkable property of the decoupling of the critical fluctuations in space and time. We have shown earlier that the quantum critical point is driven by proliferation in time of topological configurations that we termed warps. We show here that a warp may be regarded as a configuration of a monopoles surrounded symmetrically by anti-monopoles so that the total charge of the configuration is zero. Therefore the interaction with other warps is local in space. They however interact with other warps at the same spatial point logarithmically in time. As a function of dissipation warps unbind leading to a quantum phase transition. The critical fluctuations are momentum independent but have power law correlations in time

A Theory of the Pseudogap State of the Cuprates

The phase diagram for a general model for Cuprates is derived in a mean-field approximation. A phase violating time-reversal without breaking translational symmetry is possible when both the ionic interactions and the local repulsions are large compared to the energy difference between the Cu and O single-particle levels. It ends at a quantum critical point as the hole or electron doping is increased. Such a phase is necessarily accompanied by singular forward scattering such that, in the stable phase, the density of states at the chemical potential, projected to a particular point group symmetry of the lattice is zero producing thereby an anisotropic gap in the single-particle spectrum. It is suggested that this phase occupies the "pseudogap" region of the phase diagram of the cuprates. The temperature dependence of the single-particle spectra, the density of states, the specific heat and the magnetic susceptibility are calculated with rather remarkable correspondence with the experimental results. The importance of further direct experimental verification of such a phase in resolving the principal issues in the theory of the Cuprate phenomena is pointed out. To this end, some predictions are provided.Comment: 41 pages, 8 figure

Performance of Electropun Polyacrylonitrile Nanofibrous Phases, Shown for the Separation of Water-Soluble Food Dyes via UTLC-Vis-ESI-MS

Research in the miniaturization of planar chromatography led to various approaches in manufacturing ultrathin-layer chromatography (UTLC) layers of reduced thickness (<50 µm) along with smaller instrumentation, as targeted in Office Chromatography. This novel concept merges 3D print & media technologies with miniaturized planar chromatography to realize an all-in-one instrument, in which all steps of UTLC are automated and integrated in the same tiny device. In this context, the development of electrospun polyacrylonitrile (PAN) nanofiber phases was investigated as well as its performance. A nanofibrous stationary phase with fiber diameters of 150–225 nm and a thickness of ca. 25 µm was manufactured. Mixtures of water-soluble food dyes were printed on it using a modified office printer, and successfully separated to illustrate the capabilities of such UTLC media. The separation took 8 min for 30 mm and was faster (up to a factor of 2) than on particulate layers. The mean hRF values ranging from 25 to 90 for the five food dyes were well spread over the migration distance, with an overall reproducibility of 7% (mean %RSD over 5 different plates for 5 dyes). The individual mean plate numbers over 5 plates ranged between 8286 and 22,885 (mean of 11,722 over all 5 dyes). The single mean resolutions RS were between 1.7 and 6.5 (for the 5 food dyes over 5 plates), with highly satisfying reproducibilities (0.3 as mean deviation of RS). Using videodensitometry, different amounts separated in parallel led to reliable linear calibrations for each dye (sdv of 3.1–9.1% for peak heights and 2.4–9.3% for peak areas). Coupling to mass spectrometry via an elution head-based interface was successfully demonstrated for such ultrathin layers, showing several advantages such as a reduced cleaning process and a minimum zone distance. All these results underline the potential of electrospun nanofibrous phases to succeed as affordable stationary phase for quantitative UTLC

Pre-Service Elementary Teachers' Field Experiences in Classrooms Led by Science Specialists

DOI 10.1007/s10972-008-9110-y http://www.springerlink.com/content/yq5p4925661g1757/fulltext.pdfThe purpose of this study was to examine the experiences of preservice elementary teachers in a content-specific field-based experience with elementary science specialists. Data collected from electronic discussions, interviews, and observations in the field revealed preservice teachers experienced a wide range of instructional and assessment strategies in specialists' classrooms, but failed to generalize aspects of the specialist model of science instruction to traditional models for delivery of science instruction at the elementary level. Implications for supporting preservice teachers' learning to teach science through participation in a field experience with specialists are discussed

Dispersion of the high-energy phonon modes in Nd1.85_{1.85}Ce0.15_{0.15}CuO4_4

The dispersion of the high-energy phonon modes in the electron doped high-temperature superconductor Nd$_{1.85}$Ce$_{0.15}$CuO$_4$ has been studied by inelastic neutron scattering. The frequencies of phonon modes with Cu-O bond-stretching character drop abruptly when going from the Brillouin zone center along the [100]-direction; this dispersion is qualitatively similar to observations in the hole-doped cuprates. We also find a softening of the bond-stretching modes along the [110]-direction but which is weaker and exhibits a sinusoidal dispersion. The phonon anomalies are discussed in comparison to hole-doped cuprate superconductors and other metallic perovskites

High-density speckle contrast optical tomography (SCOT) for three dimensional tomographic imaging of the small animal brain

High-density speckle contrast optical tomography (SCOT) utilizing tens of thousands of source-detector pairs, was developed for in vivo imaging of blood flow in small animals. The reduction in cerebral blood flow (CBF) due to local ischemic stroke in a mouse brain was transcanially imaged and reconstructed in three dimensions. The reconstructed volume was then compared with corresponding magnetic resonance images demonstrating that the volume of reduced CBF agrees with the infarct zone at twenty-four hours.Peer ReviewedPostprint (author's final draft

Growth Stress Induced Tunability of Dielectric Constant in Thin Films

It is demonstrated here that growth stress has a substantial effect on the dielectric constant of zirconia thin films. The correct combination of parameters - phase, texture and stress - is shown to yield films with high dielectric constant and best reported equivalent oxide thickness of 0.8 nm. The stress effect on dielectric constant is twofold, firstly, by the effect on phase transitions and secondly by the effect on interatomic distances. We discuss and explain the physical mechanisms involved in the interplay between the stress, phase changes and the dielectric constant in detail.Comment: 11 pages, 5 figure