Sorption of apolar pesticides by units of benzoic acid propyl ester in cyclic phosphazene

Indexación: Scopus.The effects of temperature, pH and agitation time (equilibrium) on the adsorption process of different pesticides on N3P3(OC6H4COOCH2CH2CH3)6 was studied. With optimal conditions experimental, the adsorption isotherms have been realized with through Langmuir and Freundlich models. Pesticides are compounds used mainly in agriculture to control various species (plants, insects, worms, fungi). Due to their physicochemical properties, they can remain for a long time in the application sites, bioaccumulating and moving between environmental compartments which generate various environmental problems. The results obtained showed a physisorption mechanism for the fve pesticides studied, with higher sorption for: azinphos methyl (93,5 mg kg-1), carbaryl (290.5 mg kg-1) and carbofuran (580.5 mg kg-1) at 20 ° C, according to the models used. © 2018 Sociedad Chilena de Quimica. All rights reserved.https://scielo.conicyt.cl/pdf/jcchems/v62n4/0717-9324-jcchems-62-04-3783.pd

Conductivity anisotropy in the antiferromagnetic state of iron pnictides

Recent experiments on iron pnictides have uncovered a large in-plane resistivity anisotropy with a surprising result: the system conducts better in the antiferromagnetic x direction than in the ferromagnetic y direction. We address this problem by calculating the ratio of the Drude weight along the x and y directions, Dx/Dy, for the mean-field Q=(\pi,0) magnetic phase diagram of a five-band model for the undoped pnictides. We find that Dx/Dy ranges between 0.3 < D_x/D_y < 1.4 for different interaction parameters. Large values of orbital ordering favor an anisotropy opposite to the one found experimentally. On the other hand D_x/D_y is strongly dependent on the topology and morfology of the reconstructed Fermi surface. Our results points against orbital ordering as the origin of the observed conductivity anisotropy, which may be ascribed to the anisotropy of the Fermi velocity.Comment: 4 pages, 3 pdf figures. Fig 1(b) changed, one equation corrected, minor changes in the text, references update

Tight binding model for iron pnictides

We propose a five-band tight-binding model for the Fe-As layers of iron pnictides with the hopping amplitudes calculated within the Slater-Koster framework. The band structure found in DFT, including the orbital content of the bands, is well reproduced using only four fitting parameters to determine all the hopping amplitudes. The model allows to study the changes in the electronic structure caused by a modification of the angle $\alpha$ formed by the Fe-As bonds and the Fe-plane and recovers the phenomenology previously discussed in the literature. We also find that changes in $\alpha$ modify the shape and orbital content of the Fermi surface sheets.Comment: 12 pages, 6 eps figures. Figs 1 and 2 modified, minor changes in the text. A few references adde

Metal-to-glass ratio and the Magneto-Impedance of glass-covered CoFeBSi microwires at high frequencies

High frequency [1-500 MHz] measurements of the Magneto-Impedance (MI) of glass-covered Co$_{69.4}$Fe$_{3.7}$B$_{15.9}$Si$_{11}$ microwires are carried out with various metal-to-wire diameter ratios. A twin-peak, anhysteretic behaviour is observed as a function of magnetic field. A maximum in $\Delta Z/Z$ appears at different values of the frequency $f$, 125, 140 and 85 MHz with the corresponding diameter ratio $p$ = 0.80, 0.55 and 0.32. We describe the measurement technique and interpret our results with a thermodynamic model that leads to a clearer view of the effects of $p$ on the maximum value of MI and the anisotropy field.Comment: 5 pages and 6 figure

Clumpy Disc and Bulge Formation

We present a set of hydrodynamical/Nbody controlled simulations of isolated gas rich galaxies that self-consistently include SN feedback and a detailed chemical evolution model, both tested in cosmological simulations. The initial conditions are motivated by the observed star forming galaxies at z ~ 2-3. We find that the presence of a multiphase interstellar media in our models promotes the growth of disc instability favouring the formation of clumps which in general, are not easily disrupted on timescales compared to the migration time. We show that stellar clumps migrate towards the central region and contribute to form a classical-like bulge with a Sersic index, n > 2. Our physically-motivated Supernova feedback has a mild influence on clump survival and evolution, partially limiting the mass growth of clumps as the energy released per Supernova event is increased, with the consequent flattening of the bulge profile. This regulation does not prevent the building of a classical-like bulge even for the most energetic feedback tested. Our Supernova feedback model is able to establish a self-regulated star formation, producing mass-loaded outflows and stellar age spreads comparable to observations. We find that the bulge formation by clumps may coexit with other channels of bulge assembly such as bar and mergers. Our results suggest that galactic bulges could be interpreted as composite systems with structural components and stellar populations storing archaeological information of the dynamical history of their galaxy.Comment: Accepted for publication in MNRAS - Aug. 20, 201

The Relative Importance of Global Agricultural Subsidies and Market Access

The claim by global trade modelers that the potential contribution to global economic welfare of removing agricultural subsidies is less than one-tenth of that from removing agricultural tariffs puzzles many observers. To help explain that result, this paper first compares the OECD and model-based estimates of the extent of the producer distortions (leaving aside consumer distortions), and shows that 75 percent of total support is provided by market access barriers when account is taken of all forms of support to farmers and to agricultural processors globally, and only 19 percent to domestic farm subsidies. We then provide a back-of-the-envelope (BOTE) calculation of the welfare cost of those distortions. Assuming unitary supply and demand elasticities, that BOTE analysis suggests 86 percent of the welfare cost is due to tariffs and only 6 percent to domestic farm subsidies. When the higher costs associated with the greater variability of trade measures relative to domestic support are accounted for, the BOTE estimate of the latter's share falls to 4 percent. This is close to the 5 percent generated by the most commonly used global model (GTAP) and reported in the paper's final section.International Relations/Trade,

Optical conductivity and Raman scattering of iron superconductors

We discuss how to analyze the optical conductivity and Raman spectra of multi-orbital systems using the velocity and the Raman vertices in a similar way Raman vertices were used to disentangle nodal and antinodal regions in cuprates. We apply this method to iron superconductors in the magnetic and non-magnetic states, studied at the mean field level. We find that the anisotropy in the optical conductivity at low frequencies reflects the difference between the magnetic gaps at the X and Y electron pockets. Both gaps are sampled by Raman spectroscopy. We also show that the Drude weight anisotropy in the magnetic state is sensitive to small changes in the lattice structure.Comment: 14 pages, 10 figures, as accepted in Phys. Rev. B, explanations/discussion added in Secs. II, III and V

INCORPORATING COMMODITY STOCKHOLDING BEHAVIOR INTO A SHORT-RUN GENERAL EQUILIBRIUM MODEL OF THE GLOBAL ECONOMY

This paper incorporates commodity stockholding into a short run, stochastic global general equilibrium model. A mix of econometric and calibration techniques are used to reconcile model outcomes with historical stockholding and price behavior. The resulting framework is useful for analyzing policies in the short run or presence of production variability.Agribusiness,