Search for rare processes with ZnWO4 crystal scintillators

Radiopure ZnWO4 crystal scintillators with mass (0.1–0.7 kg) have been developed and put in measurement in the Gran Sasso National Laboratories of the INFN to search for rare processes. The radioactive contamination of the crystals have been estimated and the double beta decay of zinc and tungsten isotopes was searched for, reaching a sensitivity at the level of 1018 − 1021 yr; in addition a new half-life limit on alpha transition of 183W to the metastable excited level of 179Hf has also been obtained. The achieved radiopurity of the ZnWO4 crystals make them very promising detectors for ββ decay investigations while their anisotropic features make them very interesting detectors to investigate dark matter particles directionality

Development of 100^{100}Mo-containing scintillating bolometers for a high-sensitivity neutrinoless double-beta decay search

We report recent achievements in the development of scintillating bolometers to search for neutrinoless double-beta decay of $^{100}$Mo. The presented results have been obtained in the framework of the LUMINEU, LUCIFER and EDELWEISS collaborations, and are now part of the R\&D activities towards CUPID (CUORE Update with Particle IDentification), a proposed next-generation double-beta decay experiment based on the CUORE experience. We have developed a technology for the production of large mass ($\sim$1 kg), high optical quality, radiopure zinc and lithium molybdate crystal scintillators (ZnMoO$_4$ and Li$_2$MoO$_4$, respectively) from deeply purified natural and $^{100}$Mo-enriched molybdenum. The procedure is applied for a routine production of enriched crystals. Furthermore, the technology of a single detector module consisting of a large-volume ($\sim 100$~cm$^3$) Zn$^{100}$MoO$_4$ and Li$_2$$^{100}$MoO$_4$ scintillating bolometer has been established, demonstrating performance and radiopurity that are close to satisfy the demands of CUPID. In particular, the FWHM energy resolution of the detectors at 2615 keV --- near the $Q$-value of the double-beta transition of $^{100}$Mo (3034~keV) --- is $\approx$ 4--10~keV. The achieved rejection of $\alpha$-induced dominant background above 2.6~MeV is at the level of more than 99.9\%. The bulk activity of $^{232}$Th ($^{228}$Th) and $^{226}$Ra in the crystals is below 10 $\mu$Bq/kg. Both crystallization and detector technologies favor Li$_2$MoO$_4$, which was selected as a main element for the realization of a CUPID demonstrator (CUPID-0/Mo) with $\sim$7 kg of $^{100}$Mo

Optimization of light collection from oxide CaWO4 scintillators

The purpose of this work is to study the possibility to improve light collection in conditions similar to than in cryogenic scintillating bolometers. Energy resolution and relative pulse amplitude of scintillation detectors were measured using CaWO4 crystals with different shapes (cylindrical, hexagonal and cube prism), reflector materials and shapes, optical contact and surface conditions (polished and diffused). Light collection was simulated using ZEMAX codes

Optimization of light collection from crystal scintillators for cryogenic experiments

Cryogenic scintillation bolometers are a promising technique to search for dark matter and neutrinoless double β decay. Improvement of light collection and energy resolution are important requirements in such experiments. Energy resolutions and relative pulse amplitudes of scintillation detectors using ZnWO4 scintillation crystals of different shapes (cylinder Ø 20 × 20 mm and hexagonal prism with diagonal 20 mm and height 20 mm), reflector materials and shapes, optical contact and surface properties (polished and diffused) were measured. The crystal scintillator of hexagonal shape shows the better energy resolution and pulse amplitude. The best energy resolution (FWHM = 9.3 % for 662 keV γ quanta of 137Cs) was obtained with a hexagonal scintillator with all surfaces diffuse, in optical contact with a PMT and surrounded by a reflector (3M) of size Ø 26 × 25 mm. In the geometry "without optical contact" representing the conditions of light collection for a cryogenic scintillating bolometer the best energy resolution and relative pulse amplitude was obtained for a hexagonal shape scintillator with diffuse side and polished face surfaces, surrounded by a reflector with a gap between the scintillator and the reflector

ZnWO4 scintillators for cryogenic dark matter experiments

The scintillation properties of a zinc tungstate crystal, shaped as a hexagonal prism (height 40 mm, diagonal 40 mm) were determined. An energy resolution of 10.7% for the 662 keV γ-line of 137Cs was measured with the scintillator placed in a light collection setup similar to that used by the CRESST dark matter search. The light output and decay kinetics of ZnWO4 were examined over the temperature range 7-300 K and confirmed to be competitive with those of CaWO4. The radioactive contaminations of the ZnWO4 scintillator measured in the Solotvina Underground Laboratory do not exceed 0.1-10 mBq/kg (depending on radionuclide). Our study highlights the excellent feasibility of this ZnWO4 scintillator for a cryogenic dark matter experiment. © 2008 Elsevier B.V. All rights reserved

New half-life limits on the 2beta+ decay processes of Cd-106

The study of the 2beta+ decay of the 106Cd was performed at Gran Sasso National Laboratory. Two low-background NaI(Tl) crystals and enriched (68%) 106Cd samples (about 154 g) were used. New T_1/2 limits for the 2beta+, beta+EC, 2EC decay of 106Cd have been set in the range (0.3-4)x10^20 yr at 90% C.L. higher by a factor 6 to 60 than those already published

Effect of recrystallisation on the radioactive contamination of CaWO4 crystal scintillators

Minimising intrinsic radioactivity of crystal scintillators is of particular importance for experiments searching for rare events. We studied the impact of the crystal production process (recrystallisation) on the level of radioactive contamination of CaWO4 crystal scintillators. Several samples of single crystal scintillators were produced using the recrystallisation procedure. It is shown that this has a significant effect on the radioactive contamination of the crystals. Depending on the stage of recrystallisation the activity due to 210Po (product of 210Pb decay) varies in the range 0.031.32 Bq kg-1 while the activity of 238U varies from 0.04 to 0.33 Bq kg-1. We found that uranium is rejected by the crystal with a segregation coefficient ≈0.3. The improvement in radiopurity of CaWO4 by one order of magnitude due to recrystallisation has been demonstrated. The additional benefit of this process is the improvement in the energy resolution. A programme to develop radiopure CaWO4 crystal scintillators is discussed briefly. © 2010 Elsevier B.V. All rights reserved

New limit on two neutrino electron capture with positron emission in 106Cd

An experiment to search for double beta processes in 106Cd is in progress with the help of 106CdWO4 crystal scintillator (enriched in 106Cd to 66%) in coincidence with two large volume CdWO4 crystal scintillators in close geometry at the Gran Sasso Underground Laboratory. The time resolution of the set-up was analyzed, and the methods of pulse-shape discrimination of α and γ(β) events was applied to estimate the radioactive contamination of the crystal and to reduce the background counting rate. The possible double beta decay processes and the background components have been simulated by a Monte Carlo method with GEANT4. The experimental sensitivity is approaching the theoretical predictions for the two-neutrino electron capture with positron emission in 106Cd: lim T1/2≥4×10^21 yr at 90% C.L. (the best previous limit was established in the previous stage of the experiment as T1/2≥1.1× 10^21 yr, while the theoretical predictions are in the region of T1/2∼10^21−10^22 yr)