The dynamics of methylammonium ions in hybrid organic-inorganic perovskite solar cells

Methylammonium lead iodide perovskite can make high-efficiency solar cells, which also show an unexplained photocurrent hysteresis dependent on the device-poling history. Here we report quasielastic neutron scattering measurements showing that dipolar CH3NH3+ ions reorientate between the faces, corners or edges of the pseudo-cubic lattice cages in CH3NH3PbI3 crystals with a room temperature residence time of ~14 ps. Free rotation, π-flips and ionic diffusion are ruled out within a 1–200-ps time window. Monte Carlo simulations of interacting CH3NH3+ dipoles realigning within a 3D lattice suggest that the scattering measurements may be explained by the stabilization of CH3NH3+ in either antiferroelectric or ferroelectric domains. Collective realignment of CH3NH3+ to screen a device’s built-in potential could reduce photovoltaic performance. However, we estimate the timescale for a domain wall to traverse a typical device to be ~0.1–1 ms, faster than most observed hysteresis

Sand fly synthetic sex-aggregation pheromone co-located with insecticide reduces the incidence of infection in the canine reservoir of visceral leishmaniasis: a stratified cluster randomised trial

The predominant sand fly vector of the intracellular parasite Leishmania infantum, that causes human and canine visceral leishmaniasis in the Americas, is Lutzomyia longipalpis. Dogs are the proven reservoir. Vector control tools to reduce transmission suited to this predominantly exophilic vector are lacking. Insecticide-impregnated dog collars protect dogs against infectious bites from sand fly vectors, and result in reductions of new infections in both dogs and humans. However, collars are costly for endemic communities, and alternative approaches are needed. Recently the bulk synthesised sex-aggregation pheromone of male Lu. longipalpis was shown to attract large numbers of conspecific females to lethal pyrethroid insecticides, indicating the potential for use in a vector control application. This study, conducted in Brazil, evaluated the efficacy of this novel lure-and-kill approach to reduce seroconversion and infection incidence with L. infantum in the canine reservoir, in addition to measuring its impact on household abundance of Lu. longipalpis. Deployed in 14 stratified clusters, the outcomes were compared to those attributed to insecticide impregnated collars fitted to dogs in another 14 clusters; each intervention was compared to 14 clusters that received placebo treatments. The beneficial effects of the lure-and-kill method were most noticeable on confirmed infection incidence and clinical parasite loads, and in reducing sand fly abundance. The overall effect of the two interventions were not statistically dissimilar, though the confidence intervals were broad. We conclude that the novel low-cost lure-and-kill approach should be added to the vector control toolbox against visceral leishmaniasis in the Americas

A variação da acuidade visual durante esforços físicos em atletas com baixa visão, participantes de seleção brasileira de atletismo The visual acuity variability during physical efforts in low vision athletes from the athletics Brazilian team

INTRODUÇÃO E OBJETIVO: Esta pesquisa teve como objetivo avaliar o comportamento da acuidade visual em atletas com baixa visão, durante um protocolo de esforço contínuo. Pesquisas apontam que a acuidade visual apresenta variações de rendimento quando submetida a esforços físicos em sujeitos sem deficiência visual. MÉTODO: A população estudada foi composta por seis pessoas, praticantes de atletismo e integrantes da seleção brasileira em provas de pista. No primeiro dia aplicou-se o teste de esforço físico progressivo, realizado em esteira. No segundo dia realizou-se o teste de esforço contínuo, o qual foi dividido em três níveis, cada um com 15 minutos de duração e 30 minutos de intervalo entre eles. Como delimitador das intensidades aplicadas utilizaram-se os resultados obtidos no teste de físico progressivo (60% do VE pico, limiar de VE e 90% do VE pico). A aferição da acuidade visual aconteceu antes, durante e após cada nível de intensidade no protocolo de esforço contínuo. O teste t de Student foi utilizado para a análise estatística (p < 0,05). RESULTADOS: A acuidade visual apresentou, nos três níveis de esforço, queda de seu desempenho. A variação entre os resultados da aferição da acuidade visual estática inicial e a mensuração da mesma variável ao final da fase de corrida foi de 44,5% no primeiro nível, 52,5% no segundo e 60% no terceiro nível. Os resultados apresentaram maior degradação do componente visual durante as aferições dinâmicas. As fases de recuperação que sucediam os níveis de esforço mais intensos tiveram os melhores resultados da acuidade visual, após o déficit encontrado durante o exercício. CONCLUSÃO: Pode-se inferir que nessa população específica ocorre queda da acuidade visual durante o esforço. Tal fato implica a necessidade de a classificação esportiva ser direcionada para avaliar a funcionalidade visual de cada atleta com baixa visão durante o esforço físico, já que tais variações podem ocorrer durante o mesmo.<br>INTRODUCTION AND OBJECTIVE: This study had as an objective to evaluate the visual acuity behavior in athletes with low vision, during a continuous effort protocol. Researches point out that visual acuity presents performance varieties when submitted to physical efforts in subjects without visual impairment. METHOD: The studied population was composed by six peoples, who practiced athletics and were part of the Brazilian team in track events. The progressive physical effort test was applied on the first day in a treadmill. On the second day the continuous effort test was applied, which was divided in three levels, each one had a 15 and 30 minutes break between them. To determine the intensities, the results obtained in the progressive physical effort test (60% of VE peak, limiar VE and 90% VE peak) were used. The visual acuity was measured before, during and after each level of intensity in the continuous effort protocol. The t Student test was used for statistics analysis (p < 0.05). RESULTS: The visual acuity presented a decrease in the three levels of effort in its performance. The variety between the initial static visual acuity measure results and the measurement of the same variable in the end of the running phase was 44.5% in the first level, 52.5% in the second and 60% in the third level. The results presented higher degradation of the visual component during the dynamic measurements. The recuperation phases, which succeeded the most intense levels of effort, had the results of the visual acuity, after the deficit found during the exercise. CONCLUSION: It can be inferred that in this specific population there is a decrease in the visual acuity during the effort. This fact implies on the necessity of the visual sportive classification being directed to evaluate the visual functionality of each athlete with low vision during the physical effort, since these varieties can occur during it