Oxygen reduction in acid media: influence of the heat treatment on the FeNPc(1–20 isomer mixture impregnated on carbon blacks and active charcoals

Oxygen reduction with the aid of a number of FeNPc(1–2) impregnated carbon supports in sulphuric acid solutions has been investigated.\ud \ud Loading of the carbon samples amounted to about 10 wt.%. After a 10 day stay in the aerated solutions the samples were investigated with rotating disk electrode and X-ray photoelectron spectroscopy techniques. The most active and stable samples correspond to mono- or submonolayers of FeNPc deposited on high dibutylphthalate adsorption carbon blacks. Comparison with data obtained previously on Norit BrX impregnations emphasizes the rôle of the electron density on the inner nitrogen atoms rather than that on the iron centres

Oxygen reduction in acid media on supported iron naphthalocyanine: Effect of isomer configuration and pyrolysis

O2 reduction in H2SO4 medium has been investigated on FeNPc impregnations on Norit BrX by the rotating disk electrode technique. Important differences in activity and stability were found between the 1,2- and 2,3-FeNPc isomers (pyrolysed or not). XPS analyses show, for the most inactive sample, strong demetallation and nitrogen losses. This phenomenon can be attributed to the differences in flexibility between the FeNPc isomers, which influences their stabilization on the substrate

Oxygen reduction in an acid medium : electrocatalysis by CoNPc(1,2) impregnated on a carbon black support; effect of loading and heat treatment

O2 reduction in an acid medium has been investigated on a transition metal macrocycle, CoNPc(1,2), impregnated on a carbon black support with a high dibutylphthalate adsorption value, using a rotating disk electrode and voltammetry techniques described previously, combined with X-ray photoelectron spectroscopy measurements. Optimal activity was found for a bilayer coverage (n = 2) at 17%-18% w/w loading. Heat treatment seems to be beneficial for n 3: it increases the overall number N of exchanged electrons and improves the electrode wetting. For the most active samples, mixed Co(II)/Co(III) valencies were displayed

Optical Absorption Spectra of Bipolarons

The absorption of large bipolarons is investigated using the path-integral method. The response of a bipolaron to an external electromagnetic field is derived in the framework of the memory-function approach. The bipolaron optical absorption spectrum consists of a series of relatively narrow peaks. The peculiarities of the bipolaron optical absorption as a function of the frequency of the electromagnetic field may be attributed to the transitions involving relaxed excited states and scattering states of a bipolaron.Comment: 14 pages, 3 figures, E-mail addresses: [email protected], [email protected]; to be published in Phys. Rev.

Bipolaron Binding in Quantum Wires

A theory of bipolaron states in quantum wires with a parabolic potential well is developed applying the Feynman variational principle. The basic parameters of the bipolaron ground state (the binding energy, the number of phonons in the bipolaron cloud, the effective mass, and the bipolaron radius) are studied as a function of sizes of the potential well. Two cases are considered in detail: a cylindrical quantum wire and a planar quantum wire. Analytical expressions for the bipolaron parameters are obtained at large and small sizes of the quantum well. It is shown that at $R\gg 1$ [where $R$ means the radius (halfwidth) of a cylindrical (planar) quantum wire, expressed in Feynman units], the influence of confinement on the bipolaron binding energy is described by the function $\sim 1/R^{2}$ for both cases, while at small sizes this influence is different in each case. In quantum wires, the bipolaron binding energy $W(R)$ increases logarithmically with decreasing radius. The shapes and the sizes of a nanostructure, which are favorable for observation of stable bipolaron states, are determined.Comment: 17 pages, 6 figures, E-mail addresses: [email protected]; [email protected]

Does Free Cell Area Influence the Outcome in Carotid Artery Stenting?

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Spin singlet small bipolarons in Nb-doped BaTiO3

The magnetic susceptibility and electrical resistivity of n-type BaTi{1-x}Nb{x}O3 have been measured over a wide temperature range. It is found that, for 0 < x < 0.2, dopant electrons form immobile spin singlet small bipolarons with binding energy around 110 meV. For x = 0.2, a maximum in the electrical resistivity around 15 K indicates a crossover from band to hopping transport of the charge carriers, a phenomenon expected but rarely observed in real polaronic systems.Comment: 5 pages, 4 figure

Strong energy-momentum dispersion of phonon-dressed carriers in the lightly doped band insulator SrTiO3_3

Much progress has been made recently in the study of the effects of electron-phonon (el-ph) coupling in doped insulators using angle resolved photoemission (ARPES), yielding evidence for the dominant role of el-ph interactions in underdoped cuprates. As these studies have been limited to doped Mott insulators, the important question arises how this compares with doped band insulators where similar el-ph couplings should be at work. The archetypical case is the perovskite SrTiO$_3$ (STO), well known for its giant dielectric constant of 10000 at low temperature, exceeding that of La$_2$CuO$_4$ by a factor of 500. Based on this fact, it has been suggested that doped STO should be the archetypical bipolaron superconductor. Here we report an ARPES study from high-quality surfaces of lightly doped SrTiO$_3$. Comparing to lightly doped Mott insulators, we find the signatures of only moderate electron-phonon coupling: a dispersion anomaly associated with the low frequency optical phonon with a $\lambda'\sim0.3$ and an overall bandwidth renormalization suggesting an overall $\lambda'\sim0.7$ coming from the higher frequency phonons. Further, we find no clear signatures of the large pseudogap or small polaron phenomena. These findings demonstrate that a large dielectric constant itself is not a good indicator of el-ph coupling and highlight the unusually strong effects of the el-ph coupling in doped Mott insulators

Structure of 2,5-dimethyl-1,3,4,6-tetraazacycl[3.3.3]azine, C10H9N5

Orientador: Prof. Dr. Ramón Sigifredo Cortés ParedesCoorientadora: Profª. Drª. Maria Lúcia Leite Ribeiro OkimotoTese (doutorado) - Universidade Federal do Paraná, Setor de Tecnologia, Programa de Pós-Graduação em Engenharia Mecânica. Defesa : Curitiba, 20/02/2019Inclui referências: p. 202-219Área de concentração: ManufaturaResumo: A cor é um dos elementos mais importantes da vida humana, estando conscientes disso ou não. A cor está em tudo, desde a natureza, em todos os ambientes internos e externos, nos objetos circundantes, vestuários e, até mesmo, como forma de expressão verbal, ou seja, inimaginável a vida sem cor. No entanto, milhares de pessoas no mundo não têm acesso a esta informação. O presente trabalho refere-se ao desenvolvimento de código em relevo com o objetivo de possibilitar a identificação das cores às pessoas com deficiência visual por meio do tato. Esta abordagem científica e inovadora é composta de elementos em formato tridimensional, com dimensões mínimas, inspirado no elemento principal do Sistema Braille, o ponto. A abordagem metodológica partiu de revisão bibliográfica sobre o tema, investigação e avaliação criteriosa dos códigos de cores preexistentes e o desenvolvido de um sistema inovador, fundamentado na Teoria da Cor. Os códigos foram produzidos e experimentados em duas técnicas distintas: na técnica da Manufatura Aditiva (impressão em 3D) e na impressão em papel microcapsulado que produz relevos por meio de fusora térmica. Para a realização dos experimentos participaram 18 voluntários divididos em grupos de pessoas cegas, com baixa visão e com visão normal. Sendo nove mulheres e nove homens, com idades entre 25 a 64 anos. Os resultados da pesquisa evidenciaram que este sistema de código foi facilmente assimilado e memorizado pelos participantes com o tempo médio de 18,5 minutos para o ensino-aprendizado. A análise dos valores obtidos com o tempo médio de 14,08 segundos para o reconhecimento das cores através do código, comprovou que este sistema é eficaz e eficiente no que se propôs: o reconhecimento das cores pelo sentido do tato para promover inclusão e a acessibilidade da informação às pessoas com deficiência visual. Palavras-chave: Código de cor. Tecnologia Assistiva. Acessibilidade. Comunicação. Cegueira. Deficiência visual.Abstract: Color is one of the most important elements of human life, whether you are aware of it or not. The color is at all, from nature, in all internal and external environments, in the surrounding objects, garments and, even, as a form of verbal expression, unimaginable life without color. However, thousands of people in the world do not have access to this information. The present work refers to the development of code in relief with the objective of enabling the identification of the colors to people with visual impairment through tact. This scientific and innovative approach is composed of elements in three-dimensional format, with minimal dimensions, inspired by the main element of the Braille System, the point. The methodological approach was based on a bibliographic review of the theme, investigation and judicious evaluation of the pre-existing color codes and the development of an innovative system, grounded in the Color Theory. The codes were produced and tried in two distinct techniques: in the additive manufacturing technique (3D printing) and the microcapsulated paper printing that produces reliefs by means of thermal fuser. Eighteen volunteers were divided into groups of blind people, low vision and normal vision to perform the experiments. Nine women and nine men, aged between 25 and 64 years. The results of the research evidenced that this system of code was easily assimilated and memorized by the participants with an average time of 18,5 minutes for teaching/learning. The analysis of the values obtained with the average time of 14,08 seconds for the recognition of colors through the code, proved that this system is effective and efficient with has been proposed: the recognition of colors by the sense of touch to promote inclusion and accessibility information to visually impaired persons. Keywords: Color code. Assistive Technology. Accessibility. Communication. Blindness. Visual impairment.