2,088 research outputs found

    Determination of the absolute space directions between Baker-Nunn camera stations

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    Synthetic simultaneous observations for determining fixed-earth oriented directions between Baker-Nunn camera station

    H\"uckel--Hubbard-Ohno modeling of π\boldsymbol{\pi}-bonds in ethene and ethyne with application to trans-polyacetylene

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    Quantum chemistry calculations provide the potential energy between two carbon atoms in ethane (H3_3C−-CH3_3), ethene (H2_2C==CH2_2), and ethyne (HC≡\equivCH) as a function of the atomic distance. Based on the energy function for the σ\sigma-bond in ethane, Vσ(r)V_{\sigma}(r), we use the H\"uckel model with Hubbard--Ohno interaction for the π\pi~electrons to describe the energies Vσπ(r)V_{\sigma\pi}(r) and Vσππ(r)V_{\sigma\pi\pi}(r) for the σπ\sigma\pi double bond in ethene and the σππ\sigma\pi\pi triple bond in ethyne, respectively. The fit of the force functions shows that the Peierls coupling can be estimated with some precision whereas the Hubbard-Ohno parameters are insignificant at the distances under consideration. We apply the H\"uckel-Hubbard-Ohno model to describe the bond lengths and the energies of elementary electronic excitations of trans-polyacetylene, (CH)n_n, and adjust the σ\sigma-bond potential for conjugated polymers.Comment: 10 pages, 7 figures, 3 table

    Geodetic research studies Final technical report

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    Geopotential surface measurement of ocean using altimeter dat

    TSH, The Bone Suppressing Hormone

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    AbstractThe skeleton is a dynamic organ whose structural integrity depends on constant remodeling, controlled by many local and systemic factors. In this issue of Cell, Abe et al. (2003) identify thyroid-stimulating hormone (TSH) as an important regulator of this process
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