7 research outputs found
Scandium Recovery from Red Mud by Carbonate Assist
Known methods for production of scandium compounds are based mainly on the acidic leaching of scandium-containing materials, followed by its isolation as sparingly soluble compounds. However, these schemes have many operations, consume high amounts of reagents and electric power, resulting in a high cost of the final product. The effect of carbonate ions concentration, contact time, temperature, the ratio of S:L, type and amount of sorbent on the degree of scandium separation directly from red mud slurry was studied in this work. It has been shown that the greatest capacity of macroporous adsorbents exhibit scandium acrylic copolymers iminodifosfonic group situated closer to the polymer skeleton.
Keywords: Scandium, red mud, leaching, sorption, ion exchange resin, extractio
Electronic structure, charge transfer, and intrinsic luminescence of gadolinium oxide nanoparticles: Experiment and theory
The cubic (c) and monoclinic (m) polymorphs of Gd2O3 were studied using the
combined analysis of several materials science techniques - X-ray diffraction
(XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy
(XPS), and photoluminescence (PL) spectroscopy. Density functional theory (DFT)
based calculations for the samples under study were performed as well. The
cubic phase of gadolinium oxide (c-Gd2O3) synthesized using a precipitation
method exhibits spheroidal-like nanoclusters with well-defined edges assembled
from primary nanoparticles with an average size of 50 nm, whereas the
monoclinic phase of gadolinium oxide (m-Gd2O3) deposited using explosive
pyrolysis has a denser structure compared with natural gadolinia. This phase
also has a structure composed of three-dimensional complex agglomerates without
clear-edged boundaries that are ~21 nm in size plus a cubic phase admixture of
only 2 at. % composed of primary edge-boundary nanoparticles ~15 nm in size.
These atomic features appear in the electronic structure as different defects
([Gd...O-OH] and [Gd...O-O]) and have dissimilar contributions to the
charge-transfer processes among the appropriate electronic states with
ambiguous contributions in the Gd 5p - O 2s core-like levels in the valence
band structures. The origin of [Gd...O-OH] defects found by XPS was
well-supported by PL analysis. The electronic and atomic structures of the
synthesized gadolinias calculated using DFT were compared and discussed on the
basis of the well-known joint OKT-van der Laan model, and good agreement was
established.Comment: 27 pages, 10 figures, accepted in Appl. Surf. Sc