458 research outputs found
M\"ossbauer, nuclear inelastic scattering and density functional studies on the second metastable state of Na2[Fe(CN)5NO]2H2O
The structure of the light-induced metastable state SII of
Na2[Fe(CN)5NO]2H2O 14 was investigated by transmission M\"ossbauer
spectroscopy (TMS) in the temperature range 15 between 85 and 135 K, nuclear
inelastic scattering (NIS) at 98 K using synchrotron 16 radiation and density
functional theory (DFT) calculations. The DFT and TMS results 17 strongly
support the view that the NO group in SII takes a side-on molecular orientation
18 and, further, is dynamically displaced from one eclipsed, via a staggered,
to a second 19 eclipsed orientation. The population conditions for generating
SII are optimal for 20 measurements by TMS, yet they are modest for
accumulating NIS spectra. Optimization 21 of population conditions for NIS
measurements is discussed and new NIS experiments on 22 SII are proposed
Anionic lanthanide complexes with 3-methyl-1-phenyl-4-formylpyrazole-5-one and hydroxonium as counter ion
AbstractA series of [H3O]+[LnL4]â·nH2O complexes (n=1â3, Ln=Nd, (1), Sm (2), Eu (3), Tb (4); HL=3-methyl-1-phenyl-4-formylpyrazole-5-one) were synthesized and characterized. The structures of the SmIII and EuIII complexes were investigated by X-ray diffraction. The isostructutal crystalls 2 and 3 consist the tetrakis [LnL4]â anions which are linked by H-bonding with the hydroxonium counter-ion and water molecules. The lanthanide ion is situated in the center of distorted tetragonal antiprism formed by eight oxygen atoms of 4-formyl-5-hydroxypyrazolonate anions. The TbIII and SmIII complexes show strong luminescence in solid state, whereas the EuIII and NdIII complexes show low luminescence activity
Observation of the magnetic domain structures in CuNi thin films at low temperatures
We report on the first experimental visualization of domain structure in
films of weakly ferromagnetic CuNi alloy with different
thickness at liquid helium temperatures. Improved high-resolution Bitter
decoration technique was used to map the magnetic contrast on the top of the
films well below the Curie temperature T ( 60 K). In contrast
to magnetic force microscopy, this technique allowed visualization of the
domain structure without its disturbance while the larger areas of the sample
were probed. Maze-like domain patterns, typical for perpendicular magnetic
anisotropy, were observed. The average domain width was found to be about 100
nm.Comment: 4 pages, 5 figures, will be published in JETP Let
First experiment on fission transients in highly fissile spherical nuclei produced by fragmentation of radioactive beams
We report on a novel experimental approach for studying the dissipative
spreading of collective motion in a meta-stable nuclear system, using, for the
first time, highly fissile nuclei with spherical shape. This was achieved by
fragmentation of 45 radioactive heavy-ion beams at GSI, Darmstadt. The use of
inverse kinematics and a dedicated experimental set-up allowed for the
identification in atomic number of both fission fragments. From the width of
their charge distributions, a transient time of (3.3 +/- 0.7) 10-21 s is
deduced for initially spherical nuclei.Comment: 7 pages, 4 figures, background information at
http://www-win.gsi.de/charms
Correlation between proteome changes and synchrony of cardiac electrical excitation under 3-day «dry immersion» conditions
Transition Radiation Spectroscopy with Prototypes of the ALICE TRD
We present measurements of the transition radiation (TR) spectrum produced in
an irregular radiator at different electron momenta. The data are compared to
simulations of TR from a regular radiator.Comment: 4 pages, 5 Figures, Proceedings for "TRDs for the 3rd millennium"
(Sept. 4-7, 2003, Bari, Italy
Energy loss of pions and electrons of 1 to 6 GeV/c in drift chambers operated with Xe,CO2(15%)
We present measurements of the energy loss of pions and electrons in drift
chambers operated with a Xe,CO2(15%) mixture. The measurements are carried out
for particle momenta from 1 to 6 GeV/c using prototype drift chambers for the
ALICE TRD. Microscopic calculations are performed using input parameters
calculated with GEANT3. These calculations reproduce well the measured average
and most probable values for pions, but a higher Fermi plateau is required in
order to reproduce our electron data. The widths of the measured distributions
are smaller for data compared to the calculations. The electron/pion
identification performance using the energy loss is also presented.Comment: 15 pages, 10 figures, accepted for publication in Nucl.Instrum.Meth.
Space charge in drift chambers operated with the Xe,CO2(15%) mixture
Using prototype modules of the ALICE Transition Radiation Detector we
investigate space charge effects and the dependence of the pion rejection
performance on the incident angle of the ionizing particle. The average pulse
height distributions in the drift chambers operated with the Xe,CO2(15%)
mixture provide quantitative information on the gas gain reduction due to space
charge accumulating during the drift of the primary ionization. Our results
demonstrate that the pion rejection performance of a TRD is better for tracks
which are not at normal incidence to the anode wires. We present detailed
simulations of detector signals, which reproduce the measurements and lend
strong support to our interpretation of the measurements in terms of space
charge effects.Comment: 18 pages, 10 figures, accepted for publication in Nucl.Instrum.Meth.
A. Data files available at http://www-alice.gsi.de/tr
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