3,532 research outputs found

    Mechanisms of water-salt metabolism disturbances in dogs subjected to six month hypokinesia

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    Water-salt metabolism in dogs during prolonged restricted motor activity (hypokinesia) was investigated. It was found that hydration occurred and fluid was redistributed between the extra- and intra-cellular sectors. Also, electrolyte excretion rose, and magnetism and calcium metabolism changed significantly. It is concluded that the forces caused by muscle strain proper (which was decreased under conditions of hypokinesia) influence the state of bone metabolism

    Functionalization of PET track-etched membranes by UV-induced graft (co)polymerization for detection of heavy metal ions in water

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    Nowadays, water quality monitoring is an essential task since environmental contamination and human exposure to heavy metals increased. Sensors that are able to detect ever lower concentrations of heavy metal ions with greater accuracy and speed are needed to effectively monitor water quality and prevent poisoning. This article shows studies of the modification of flexible track-etched membranes as the basis for the sensor with various polymers and their influence on the accuracy of detection of copper, cadmium, and lead ions in water. We report the UV-induced graft (co)polymerization of acrylic acid (AA) and 4-vinylpyridine (4-VPy) on poly(ethylene terephthalate) track-etched membrane (PET TeMs) and use them after platinum layer sputtering in square wave anodic stripping voltammetry (SW-ASV) for detection of Cu2+, Cd2+, and Pb2+. Optimal conditions leading to functionalization of the surface and retention of the pore structure were found. Modified membranes were characterized by SEM, FTIR, X-ray photoelectron spectroscopy (XPS) and colorimetric analysis. The dependence of the modification method on the sensitivity of the sensor was shown. Membrane modified with polyacrylic acid (PET TeMs-g-PAA), poly(4-vinylpyridine) (PET TeMs-g-P4VPy), and their copolymer (PET TeMs-g-P4VPy/PAA) with average grafting yield of 3% have been found to be sensitive to μg/L concentration of copper, lead, and cadmium ions. Limits of detection (LOD) for sensors based on PET TeMs-g-PAA are 2.22, 1.05, and 2.53 μg/L for Cu2+, Pb2+, and Cd2+, respectively. LODs for sensors based on PET TeMs-g-P4VPy are 5.23 μg/L (Cu2+), 1.78 μg/L (Pb2+), and 3.64 μg/L (Cd2+) μg/L. PET TeMs-g-P4VPy/PAA electrodes are found to be sensitive with LODs of 0.74 μg/L(Cu2+), 1.13 μg/L (Pb2+), and 2.07 μg/L(Cd2+). Thus, it was shown that the modification of membranes by copolymers with carboxylic and amino groups leads to more accurate detection of heavy metal ions, associated with the formation of more stable complexes. © 2019 by the authors.Ministry of Education and Science of the Republic of KazakhstanMinistry of Education and Science of the Republic of KazakhstanFunding: The research was funded by the Ministry of Energy of the Republic of Kazakhstan (technological program, #74 on 02.04.2018).Acknowledgments: The research was funded by the Ministry of Energy of the Republic of Kazakhstan (technological program, #74 on 02.04.2018)

    Pilot project of measuring and computing system for mesoscale monitoring of atmospheric boundary layer

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    Conception of design of measuring and computing system for monitoring atmospheric boundary layer is proposed. The system includes: stationary measuring complex consisting of four multiple-elevation ultrasonic weather stations and mobile measuring complex consisting of transportable weather station, touch probing system of weather data profile based on unmanned aerial vehicle and also Raman scattering gas analyzer, and new modification mercury gas analyzer. © (2015) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only

    Acesso das pequenas empresas russas aos mercados de contratos públicos: análise de dados

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    The aim of this study was to assess the current extent of participation by Russian small enterprises in regional public procurement. We discussed how legislation affects the volume of contracts awarded to small enterprises. We calculated the number of contracts per 100 small enterprises, how much the number and value of such contracts account for in the total number and value of contracts concluded with all suppliers per region, as well as what is the average value of contracts per small enterprise and the average value of one such contract. In order to ensure benchmarking for enterprises located in different regions, such enterprises were assessed on the basis of relative indicators. This study used official statistics accumulated with regard to all public procurement in the regions. The data on the number of contracts and their value for the period from 2010 to 2014 were used. For the purposes of empirical data analysis, the normal distribution probability density functions set for all the indicators in question were used. The findings of this study and the tools used for assessing the extent of participation by small enterprises in public procurement can be used when researching entrepreneurship, as well as to justify the contract system development programs in Russia. Such information is important for entrepreneurs, as it enables them to assess the feasibility and consequences of participation in public procurement.El objetivo de este estudio fue evaluar el grado actual de participación de las pequeñas empresas rusas en la contratación pública regional. Discutimos cómo la legislación afecta el volumen de contratos adjudicados a pequeñas empresas. Calculamos el número de contratos por cada 100 pequeñas empresas, cuánto representan el número y el valor de dichos contratos en el número y el valor total de los contratos celebrados con todos los proveedores por región, así como también cuál es el valor promedio de los contratos por cada pequeña empresa y el valor promedio de uno de esos contratos. Con el fin de garantizar la evaluación comparativa para las empresas ubicadas en diferentes regiones, dichas empresas se evaluaron sobre la base de indicadores relativos. Este estudio utilizó estadísticas oficiales acumuladas con respecto a todas las contrataciones públicas en las regiones. Se utilizaron los datos sobre el número de contratos y su valor para el período de 2010 a 2014. A los efectos del análisis de datos empíricos, se utilizaron las funciones de densidad de probabilidad de distribución normal establecidas para todos los indicadores en cuestión. Las conclusiones de este estudio y las herramientas utilizadas para evaluar el grado de participación de las pequeñas empresas en la contratación pública se pueden utilizar al investigar el espíritu empresarial, así como para justificar los programas de desarrollo de sistemas contractuales en Rusia. Dicha información es importante para los empresarios, ya que les permite evaluar la viabilidad y las consecuencias de la participación en la contratación pública.O objetivo deste estudo foi avaliar o atual grau de participação das pequenas empresas russas nas compras públicas regionais. Discutimos como a legislação afeta o volume de contratos concedidos a pequenas empresas. Nós calculamos o número de contratos por 100 pequenas empresas, que representam o número eo valor desses contratos no número total eo valor total dos contratos com todos os fornecedores por região, bem como o que o valor médio de contratos para cada empresa de pequeno porte e o valor médio de um desses contratos. Para garantir benchmarking para empresas localizadas em diferentes regiões, essas empresas foram avaliadas com base em indicadores relativos. Este estudo utilizou estatísticas oficiais acumuladas em relação a todas as compras públicas nas regiões. Foram utilizados os dados sobre o número de contratos e seu valor para o período de 2010 a 2014. Para fins de análise empírica dos dados, foram utilizadas as funções de densidade de probabilidade de distribuição normal estabelecidas para todos os indicadores em questão. As conclusões deste estudo e os instrumentos utilizados para avaliar o grau de participação das pequenas empresas nos contratos públicos podem ser utilizados na investigação do empreendedorismo, bem como para justificar os programas de desenvolvimento de sistemas contratuais na Rússia. Esta informação é importante para os empresários, pois permite avaliar a viabilidade e as consequências da participação em contratos públicos
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