Intrinsic Anharmonicities In The Bx4 2- Orthorhombic Sublattice

We have measured the room-temperature polarized Raman spectra of the internal modes of K2SO4 and K2SeO4 under hydrostatic pressure up to 10 GPa in a backscattering configuration. It was found that phonons involving the motion of selenium atoms have distinctive pseudoanharmonicities that can be traced to isotopic natural abundances. Accordingly, a reinterpretation is given to the origin of the fourth-order anharmonicity (g4 coupling constant) within the quartic potential formalism as representing dynamical isotopic effects in the cluster picture. We found that this analysis may be extended to other molecular systems with either phonon instabilities or order-disorder commensurate- incommensurate phase transitions. © 1986 The American Physical Society.3353379338

Symmetry Plays a Key Role in the Erasing of Patterned Surface Features

We report on how the relaxation of patterns prepared on a thin film can be controlled by manipu- lating the symmetry of the initial shape. The validity of a lubrication theory for the capillary-driven relaxation of surface profiles is verified by atomic force microscopy measurements, performed on films that were patterned using focused laser spike annealing. In particular, we observe that the shape of the surface profile at late times is entirely determined by the initial symmetry of the perturba- tion, in agreement with the theory. Moreover, in this regime the perturbation amplitude relaxes as a power-law in time, with an exponent that is also related to the initial symmetry. The results have relevance in the dynamical control of topographic perturbations for nanolithography and high density memory storage

Determination of Wave Function Functionals: The Constrained-Search--Variational Method

In a recent paper [Phys. Rev. Lett. \textbf{93}, 130401 (2004)], we proposed the idea of expanding the space of variations in variational calculations of the energy by considering the approximate wave function $\psi$ to be a functional of functions $\chi: \psi = \psi[\chi]$ rather than a function. The space of variations is expanded because a search over the functions $\chi$ can in principle lead to the true wave function. As the space of such variations is large, we proposed the constrained-search-- variational method whereby a constrained search is first performed over all functions $\chi$ such that the wave function functional $\psi[\chi]$ satisfies a physical constraint such as normalization or the Fermi-Coulomb hole sum rule, or leads to the known value of an observable such as the diamagnetic susceptibility, nuclear magnetic constant or Fermi contact term. A rigorous upper bound to the energy is then obtained by application of the variational principle. A key attribute of the method is that the wave function functional is accurate throughout space, in contrast to the standard variational method for which the wave function is accurate only in those regions of space contributing principally to the energy. In this paper we generalize the equations of the method to the determination of arbitrary Hermitian single-particle operators as applied to two-electron atomic and ionic systems. The description is general and applicable to both ground and excited states. A discussion on excited states in conjunction with the theorem of Theophilou is provided.Comment: 26 pages, 4 figures, 5 table

A taxonomic revision of western Eupholidoptera bush crickets (Orthoptera: Tettigoniidae): testing the discrimination power of DNA barcode.

The genus Eupholidoptera includes 46 Mediterranean species distributed from Turkey to Greece, Italy and southern France. In the eastern part of its range, Eupholidoptera has been considered to consist of several distinct species, while in the Balkans and Italian peninsula only E. chabrieri has been recognized. However, the status of some Italian populations, confined to particular geographic areas, remains uncertain. To investigate the delimitation of the Italian taxa of Eupholidoptera, we performed both morphological and molecular analyses. Morphological analysis was carried out by considering diagnostic characters usually used to distinguish different taxa, such as the shape of titillators in males and the subgenital plate in females. Molecular analysis was performed by sequencing three mitochondrial genes: 12S rRNA, 16S rRNA, partially sequenced and the entire gene of cox1 . Molecular markers were used to infer phylogenetic relationships among the Italian Eupholidoptera species and to reconstruct the historical processes that shaped their current geographic distribution. Results from both morphological and molecular analyses were used to revise the taxonomic arrangement of species. On the whole we were able to distinguish nine lineages of Italian Eupholidoptera, of which E. tyrrhenica sp.n. from Corsica is described as a new species

Determination of a Wave Function Functional

In this paper we propose the idea of expanding the space of variations in standard variational calculations for the energy by considering the wave function $\psi$ to be a functional of a set of functions $\chi: \psi = \psi[\chi]$, rather than a function. In this manner a greater flexibility to the structure of the wave function is achieved. A constrained search in a subspace over all functions $\chi$ such that the wave function functional $\psi[\chi]$ satisfies a constraint such as normalization or the Fermi-Coulomb hole charge sum rule, or the requirement that it lead to a physical observable such as the density, diamagnetic susceptibility, etc. is then performed. A rigorous upper bound to the energy is subsequently obtained by variational minimization with respect to the parameters in the approximate wave function functional. Hence, the terminology, the constrained-search variational method. The \emph{rigorous} construction of such a constrained-search--variational wave function functional is demonstrated by example of the ground state of the Helium atom.Comment: 10 pages, 2 figures, changes made, references adde

Genetic interaction of Pax3 mutation and canonical Wnt signaling modulates neural tube defects and neural crest abnormalities

Mouse models provide opportunities to investigate genetic interactions that cause or modify the frequency of neural tube defects (NTDs). Mutation of the PAX3 transcription factor prevents neural tube closure, leading to cranial and spinal NTDs whose frequency is responsive to folate status. Canonical Wnt signalling is implicated both in regulation of Pax3 expression and as a target of PAX3. This study investigated potential interactions of Pax3 mutation and canonical Wnt signalling using conditional gain- and loss-of-function models of β-catenin. We found an additive effect of β-catenin gain of function and Pax3 loss of function on NTDs and neural crest defects. β-catenin gain of function in the Pax3 expression domain led to significantly increased frequency of cranial but not spinal NTDs in embryos that are heterozygous for Pax3 mutation, while both cranial and spinal neural tube closure were exacerbated in Pax3 homozygotes. Similarly, deficits of migrating neural crest cells were exacerbated by β-catenin gain of function, with almost complete ablation of spinal neural crest cells and derivatives in Pax3 homozygous mutants. Pax3 expression was not affected by β-catenin gain of function, while we confirmed that loss of function led to reduced Pax3 transcription. In contrast to gain of function, β-catenin knockout in the Pax3 expression domain lowered the frequency of cranial NTDs in Pax3 null embryos. However, loss of function of β-catenin and Pax3 resulted in spinal NTDs, suggesting differential regulation of cranial and spinal neural tube closure. In summary, β-catenin function modulates the frequency of PAX3-related NTDs in the mouse

[The role of endoscopy in gastroenteropancreatic neuroendocrine tumors].

[The role of endoscopy in gastroenteropancreatic neuroendocrine tumors]. [Article in Italian] Magno L, Sivero L, Napolitano V, Ruggiero S, Fontanarosa G, Massa S. Source Dipartmento di Chirurgia Generale, Geriatrica ed Endoscopia Diagnostica ed Geriatrica, Universitá degli Studi, Federico II di Napoli. Abstract Versione italiana Riassunto: Il ruolo dell'endoscopia nei tumori neuroendocrini gastroenteropancreatici. L. Magno, L. Sivero, V. Napolitano, S. Ruggiero, G. Fontanarosa, S. Massa I tumori neuroendocrini (NET) gastro-entero-pancreatici (GEP) sono neoplasie rare che originano dalle cellule neuroendocrine del tubo digerente e del pancreas. L'endoscopia digestiva e l'ecoendoscopia rivestono un ruolo importante nella diagnosi, stadiazione e sorveglianza dei pazienti con NET. Inoltre, in casi selezionati, le tecniche endoscopiche operative consentono il trattamento di queste neoplasie in fase precoce. English version Summary: The role of endoscopy in gastroenteropancreatic neuroendocrine tumors. L. Magno, L. Sivero, V. Napolitano, S. Ruggiero, G. Fontanarosa, S. Massa Gastroenteropancreatic (GEP) neuroendocrine tumors (NET) are rare neoplasia arisen from neuroendocrine cells present in the gut mucosa and pancreas. Digestive endoscopy and endoscopic ultrasonography play a relevant role in NET diagnosis, stadiation and surveillance. Moreover, in selected patients, surgical endoscopy allows the tratment of these cancers at an early stage