Doping and temperature dependence of Mn 3d states in A-site ordered manganites

We present a systematic study of the electronic structure in A-site ordered manganites as function of doping and temperature. The energy dependencies observed with soft x-ray resonant diffraction (SXRD) at the Mn L_{2,3} edges are compared with structural investigations using neutron powder diffraction as well as with cluster calculations. The crystal structures obtained with neutron powder diffraction reflect the various orbital and charge ordered phases and show an increase of the Mn-O-Mn bond angle as function of doping and temperature. Cluster calculations show that the observed spectral changes in SXRD as a function of doping are more pronounced than expected from an increase in bandwitdh due to the increase in Mn-O-Mn bond angle, and are best described by holes that are distributed at the neighbouring oxygen ions. These holes are not directly added to the Mn 3d shell, but centered at the Mn site. In contrast, the spectral changes in SXRD as function of temperature are best described by an increase of magnetic correlations. This demonstrates the strong correlations between orbitals and magnetic moments of the 3d states

Effect of extrusion on the mechanical and rheological properties of a reinforced poly(lactic acid): Reprocessing and recycling of biobased materials

The aim of this research paper is to study the behaviour of a common used biopolymer (Poly(Lactic Acid) (PLA)) after several reprocesses and how two different types of additives (a melt strength enhancer and a nanoadditive) affect its mechanical and rheological properties. Systematic extraction of extrudate samples from a twin-screw compounder was done in order to study the effect in the properties of the reprocessed material. Detailed rheological tests on a capillary rheometer as well as mechanical studies on a universal tensile machine after preparation of injected specimens were carried out. Results evidenced that PLA and reinforced PLA materials can be reprocessed and recycled without a remarkable loss in their mechanical properties. Several processing restrictions and specific phenomena were identified and are explained in the present manuscript

Fusion of 8He with 206Pb around Coulomb barrier energies

5th International Conference FUSION11The experimental study of the fusion of light neutron-rich nucleus 8He with 206Pb is reported in this work. A fusion stack of 206Pb targets has been used for this study. The most prominent evaporation residue (210Po), which has half-life of 138 days and decays by alpha emission, is populated in the reaction. Radiochemical analysis technique is used to extract the yield of this evaporation residueMinisterio Español de Ciencia e Innovación FPA2007-6307

Nanostructured giant magneto-impedance multilayers deposited onto flexible substrates for low pressure sensing

Nanostructured FeNi-based multilayers are very suitable for use as magnetic sensors using the giant magneto-impedance effect. New fields of application can be opened with these materials deposited onto flexible substrates. In this work, we compare the performance of samples prepared onto a rigid glass substrate and onto a cyclo olefin copolymer flexible one. Although a significant reduction of the field sensitivity is found due to the increased effect of the stresses generated during preparation, the results are still satisfactory for use as magnetic field sensors in special applications. Moreover, we take advantage of the flexible nature of the substrate to evaluate the pressure dependence of the giant magneto-impedance effect. Sensitivities up to 1 Ω/Pa are found for pressures in the range of 0 to 1 Pa, demostrating the suitability of these nanostructured materials deposited onto flexible substrates to build sensitive pressure sensors

Theoretical Kinetics Study of the F(2P) + NH3 Hydrogen Abstraction Reaction

The hydrogen abstraction reaction of fluorine with ammonia represents a true chemical challenge because it is very fast, is followed by secondary abstraction reactions, which are also extremely fast, and presents an experimental/theoretical controversy about rate coefficients. Using a previously developed full-dimensional analytical potential energy surface, we found that the F + NH3 → HF + NH2 system is a barrierless reaction with intermediate complexes in the entry and exit channels. In order to understand the reactivity of the title reaction, thermal rate coefficidents were calculated using two approaches: ring polymer molecular dynamics and quasi-classical trajectory calculations, and these were compared with available experimental data for the common temperature range 276–327 K. The theoretical results obtained show behavior practically independent of temperature, reproducing Walther–Wagner’s experiment, but in contrast with Persky’s more recent experiment. However, quantitatively, our results are 1 order of magnitude larger than those of Walther–Wagner and reasonably agree with the Persky at the lowest temperature, questioning so Walther−Wagner’s older data. At present, the reason for this discrepancy is not clear, although we point out some possible reasons in the light of current theoretical calculationsThis work was partially supported by Gobierno de Extremadura, Spain, and FEDER (Project No. IB10001). Y.V.S. acknowledges the support of a Combustion Energy Research Fellowship through the Combustion Energy Frontier Research Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Basic Energy Sciences under Award Number DE-SC0001198. A.F-.R. thanks Xunta de Galicia through Grant No. 2012/314 para a consolidación e a estruturación de unidades de investigación competitivas do Sistema Universitario de Galicia, 2012S

Density and reproductive characteristics of female brown bears in the Cantabrian Mountains, NW Spain

Here we present annual nearest-neighbour distances (as a proxy of density) between females with cubs-of-the-year (hereafter FCOY) and reproductive characteristics of brown bears Ursus arctos in the Cantabrian Mountains (NW Spain), from 1989 to 2017. FCOY nearest-neighbour distances and reproduction parameters of 19 focal females followed over several consecutive years (from 2004 to 2017) were obtained from bears inhabiting the western sector of the Cantabrian Mountains, where most of the bear population resides. In contrast, general reproductive characteristics were studied in the whole Cantabrian Mountains (western and eastern sectors together) on a sample of 362 litter sizes and 695 cubs. Mean nearest-neighbour distance between FCOY was 2559 ± 1222 m (range = 1305–4757 m). Mean litter size was significantly larger in the west (1.8 ± 0.2 cubs) than in the east (1.3 ± 0.6 cubs). Mean litter size for the whole of the Cantabrian Mountains was 1.6 ± 0.3 cubs. Litter sizes of one, two and three cubs represented 33.4, 56.1 and 10.5% of observed family groups, respectively. Interannual variations in litter size were not significant for both the western and the eastern areas. Mean cub mortality was 0.2 ± 0.5 cubs and did not vary among years. Cub mortality per litter size was 3.9% for one cub, 69.2% for two cubs and 26.9% for three cubs. Mean reproductive rate of the 19 focal females was 1.5 ± 0.6 cubs (n = 58 litters). Litter size of focal FCOY did not differ from the litter size obtained from systematic observations in the whole Cantabrian Mountains. During this period, cub mortality occurred in 24.1% of the 58 litters. Females usually bred every second year (average litter interval = 2.2 years). The estimated reproductive rate for the bear population was 0.7 young born/year/reproductive adult female

Beyond conventional factorization: Non-Hermitian Hamiltonians with radial oscillator spectrum

The eigenvalue problem of the spherically symmetric oscillator Hamiltonian is revisited in the context of canonical raising and lowering operators. The Hamiltonian is then factorized in terms of two not mutually adjoint factorizing operators which, in turn, give rise to a non-Hermitian radial Hamiltonian. The set of eigenvalues of this new Hamiltonian is exactly the same as the energy spectrum of the radial oscillator and the new square-integrable eigenfunctions are complex Darboux-deformations of the associated Laguerre polynomials.Comment: 13 pages, 7 figure

Factores microclimáticos que afectan a la regeneración de Pinus pinaster Ait. en Tierra de Pinares (Segovia)

El objetivo de este estudio fue evaluar los factores micrometeorológicos que afectan a la regeneración del pino resinero en la Tierra de Pinares Segoviana. Se registró durante un período vegetativo completo la temperatura del suelo y la temperatura de la capa de aire más próximo al suelo. La temperatura del suelo alcanzó máximos de 56 ºC desde el mes de julio a septiembre, en períodos de más de 4 horas seguidas durante 2-5 días consecutivos y la temperatura del aire más próximo al suelo, donde viven las plántulas recién nacidas, alcanzó valores de hasta 56 ºC desde junio a septiembre, durante períodos de más de 4,5 horas en periodos de 7 días consecutivos. En las plántulas objeto de estudio se identificaron heridas en el cuello de la raíz lo que indica que las altas temperaturas producen cambios fisiológicos y morfológicos en las plántulas comprometiendo su supervivencia y la de la regeneración de estos montes. El análisis estadístico mostró que los puntos de muestreo seleccionados no presentaron grandes diferencias respecto a las variables microclimáticas consideradas

Spike-based VITE control with Dynamic Vision Sensor applied to an Arm Robot.

Spike-based motor control is very important in the field of robotics and also for the neuromorphic engineering community to bridge the gap between sensing / processing devices and motor control without losing the spike philosophy that enhances speed response and reduces power consumption. This paper shows an accurate neuro-inspired spike-based system composed of a DVS retina, a visual processing system that detects and tracks objects, and a SVITE motor control, where everything follows the spike-based philosophy. The control system is a spike version of the neuroinspired open loop VITE control algorithm implemented in a couple of FPGA boards: the first one runs the algorithm and the second one drives the motors with spikes. The robotic platform is a low cost arm with four degrees of freedom.Ministerio de Ciencia e Innovación TEC2009-10639-C04-02/01Ministerio de Economía y Competitividad TEC2012-37868-C04-02/0

Valorization of Microalgae and Energy Resources

Microalgae biotechnology has grown very rapidly in the last few decades due to the multiple applications that these microorganisms have from pharmaceuticals and cosmetics to foods/feeds and biofuels. One of the main challenges in expanding this industry is to enlarge the single use of the biomass produced in addition to reducing the high biomass production cost of the current technologies. To overcome this bottleneck, the development of microalgae-based biorefineries has been proposed. The issue is to obtain as many bioproducts as possible from the cultivated biomass, including biofuels. Consequently, biodiesel production (from the lipid fraction), bioethanol (from carbohydrate fraction), and biogas or bio-oil (from the whole biomass) have been posited. In this book chapter, we review the current state of the art in the production of sustainable biofuels from microalgae and analyze the potential of microalgae to contribute to the biofuel sector