Sedimentology and depositional architecture of tufas deposited in stepped fluvial systems of changing slope: Lessons from the quaternary añamaza valley (Iberian Range, Spain)

The Pleistocene and Holocene tufas of the Añamaza valley (stepped build-ups, up to 70 m thick, along the valley) consist of several depositional stages separated by erosional surfaces. Eight associations of tufa and related carbonate facies, plus minor polygenic detrital facies, represent the processes that occurred in different fluvial and related environments. The bedrock lithology and structure controlled the location of the knickpoints along the valley and allowed separation of two stepped stretches with distinct conceptual facies models. The moderate-slope model includes extensive standing-water areas dammed by barrage-cascades. In the lakes, bioclastic silts, sands and limestones along with phytoclastic and marly, at places peaty, sediments formed. Abundant stem phytoherms account for extensive palustrine areas. The high-slope model consists of smaller dammed areas between close-up cascades and barrage-cascades, which were composed primarily of moss phytoherms and phytoclastic tufas. An outstanding feature is the extensive steep reach with phytoclastic and polygenic detrital sediments, and stepped cascades consisting of stromatolitic and moss phytoherms. There, the steep slope limited the preservation of stem phytoherms and favoured erosion. The geometry and thickness of the sedimentary fill (wedge-shaped units composed of cascade and barrage-cascade deposits downstream, and dammed and gentle-sloped channel deposits upstream) are therefore different for each model. Multi-storey wedges are a distinctive feature of the high-slope model. The initial knickpoint geometry and the tufa aggradation/progradation ratio on such steep surfaces (for example, related to changes in discharge) controlled the growth style of the cascades or barrage-cascades and, hence, the extent, thickness and vertical evolution of the upstream deposits. The sedimentological attributes and stable-isotope composition of the carbonate facies suggest a higher and more variable precipitation/evaporation ratio during the Pleistocene than during the Holocene, consistent with an overall decrease in the river discharge. This evolution was coupled with warm conditions, which prevailed during the stages of tufa formation. These results may help to assess architectural patterns in interpreting other basins, and underscore the significance of tufas as records of past hydrology and climate

Intrinsic and extrinsic controls of spatial and temporal variations in modern fluvial tufa sedimentation: A thirteen-year record from a semi-arid environment

Sedimentological and hydrochemical parameters of the River Piedra (north-east Spain) were monitored every six months (from 1999 to 2012) at 24 sites, at which tablets were installed all along the river. The river water is of HCO3–SO4–Ca type and is notably influenced by inputs from upstream karstic springs. Tufa deposition was first detected 8 km downstream of these springs and greatly increased from there, primarily along the steeper stretch (i.e. within the Monasterio de Piedra Natural Park); then, deposition decreased through the most downstream stretch, with smaller ground water inputs. The spatial evolution of the tufa thickness, with parallel variations of PWP (Plummer, Wigley, Parkhurst) rates, was thus determined by the river water pCO2 which was controlled by ground water inputs and by the river bed slope. Five fluvial subenvironments and seven sedimentary facies were characterized. The water flow conditions are the primary factor responsible for the distinct deposition rates of facies, mainly through CO2-outgassing. Stromatolites and moss-tufa and alga-tufa had the highest rates, whereas loose tufa formed in slow-flowing water and tufa of spray areas had thinner deposition. A six-month pattern in the deposition rate was detected through thickness measurements. That pattern was parallel to the seasonal PWP rates. The increased deposition during warm periods (spring and summer; mean: 5·08 mm) compared with cool periods (autumn and winter; mean: 2·77 mm) is linked chiefly to temperature, which controlled the seasonal changes in the physico-chemical and biological processes; this finding is supported by a principal components analysis. Seasonal variations of insolation and day duration also contributed to such a deposition pattern. Large discharge events, which provoked erosion of tufa deposits and dilution of water, caused the reversal of the seasonal deposition rate pattern. Stromatolites are likely to preserve the most complete sedimentary record. Although tufas are a potentially sensitive record of climate-related parameters, erosion is an intrinsic process that may overwhelm the effects of such parameters. This issue should be considered in palaeoclimatic studies based on the tufa record, particularly in semi-arid conditions

Tufa sedimentation in changing hydrological conditions: the River Mesa (Spain)

The processes controlling tufa deposition along the River Mesa (NE Spain) were studied from April 2003 to September 2009, based on six-monthly monitoring of physical and chemical parameters of the river water and sedimentological characteristics, including deposition rates on tablets. With a mean annual discharge around 1.5m3/s, the sedimentation rate (mean 2mm/yr) recorded important spatial, seasonal and interannual variations. The river waters are of the calcium bicarbonate type. In this study, three distinct river stretches were distinguished based on the steady groundwater inputs, some of low-thermal nature. Groundwater discharges controlled the water chemical composition, and some sedimentation features too. At each stretch, an increase in pCO2 and conductivity was measured around the spring sites. Decreasing trends in conductivity or alkalinity with high enough saturation values with respect to calcite were only clearly observed in the intermediate stretch, which had higher tufa deposition rates than the other two. Tufa deposition rates were higher in cool (autumn+winter) than in warm (spring+summer) periods. In some low-rainfall warm periods, tufa deposition was inhibited or limited due to the low flow –mainly from groundwater inputs– and to the dryness of some river sites, which indeed favoured erosion during flooding. A decrease in yearly deposition rates from April 2006 onwards paralleled an important reduction in the river discharge. Groundwater inputs, drought periods and flood events should therefore be considered to understand fluvial tufa sedimentation in semi-arid conditions

Tufa sedimentation in changing hydrological conditions: the River Mesa (Spain)

The processes controlling tufa deposition along the River Mesa (NE Spain) were studied from April 2003 to September 2009, based on six-monthly monitoring of physical and chemical parameters of the river water and sedimentological characteristics, including deposition rates on tablets. With a mean annual discharge around 1.5m3 /s, the sedimentation rate (mean 2mm/yr) recorded important spatial, seasonal and interannual variations. The river waters are of the calcium bicarbonate type. In this study, three distinct river stretches were distinguished based on the steady groundwater inputs, some of low-thermal nature. Groundwater discharges controlled the water chemical composition, and some sedimentation features too. At each stretch, an increase in pCO2 and conductivity was measured around the spring sites. Decreasing trends in conductivity or alkalinity with high enough saturation values with respect to calcite were only clearly observed in the intermediate stretch, which had higher tufa deposition rates than the other two. Tufa deposition rates were higher in cool (autumn+winter) than in warm (spring+summer) periods. In some low-rainfall warm periods, tufa deposition was inhibited or limited due to the low flow –mainly from groundwater inputs– and to the dryness of some river sites, which indeed favoured erosion during flooding. A decrease in yearly deposition rates from April 2006 onwards paralleled an important reduction in the river discharge. Groundwater inputs, drought periods and flood events should therefore be considered to understand fluvial tufa sedimentation in semi-arid conditions

Discerning the interactions between environmental parameters reflected in d13C and d18O of recent fluvial tufas: Lessons from a Mediterranean climate region

d13C and d18O of recent, continuous tufa records, obtained during a monitoring period spanning 3 to 13 years, are compared with the corresponding, known environmental conditions. Three rivers in NE Iberia (located along a 200-km N–S transect) are used for this comparison. The isotopic variations through space and time are discussed in terms of the environmental and geological parameters that operate on different scales, focusing on discerning the interactions between these parameters and providing examples of possible misinterpretation of climatic conditions, which is important to past climate studies based on isotopic data. The calculation of the actual isotopic fractionation coefficients, and the comparison with the literature-derived coefficients, demonstrates that the studied tufa formation was close to isotopic equilibrium to reflect the water temperature. The difference between mean measured water temperature (Tw) and mean calculated Tw (based on d18Ocalcite and measured d18Owater) is less than 2.7 °C. Tendencies of these calculated Tw are similar to the regional air temperature (Tair) tendencies through time, in particular in the case of the 13-year record, although certain deviations exist over shorter time spans. The best agreement between measured and calculated Tw and between d18Ocalcite-based Tw tendencies and Tair tendencies corresponds to the tufa stromatolite facies. Differences between the d18Ocalcite records of the three rivers cannot be attributed to temperature changes, but to the varying influences of groundwater inputs and isotopic rainfall composition in each river.Without considering these parameters, d18Ocalcite-based Tw calculations yield inaccurate results when comparing the study sites. d13Ccalcite values do not exhibit distinct patterns over time, and d13Ccalcite variations are likely caused by local processes that do not reflect general environmental changes. These findings underscore the significance of accounting for both groundwater behaviour and rainfall stable isotope composition when interpreting climate parameters in carbonate systems, particularly when differences between the isotopic signatures of deposits exist in the same region

Benthic diatoms on fluvial tufas of the Mesa River, Iberian Range, Spain

Background. The Mesa River (MR) in the Iberian Range (Spain) displays prominent, Pleistocene to present-day fluvial tufa deposits. Little of their associated microbiota has been studied to date despite the regional and historical relevance of these calcareous buildups. Goals. This paper is a preliminary exploration of the diatom (Bacillariophyta) genera associated with actively-growing tufa from 10 benthic environments along 24 km of the Mesa River. Methods. Bright- field microscopy, as well as consultation with specialists and specialized literature was used for taxonomic classification of diatoms. Results. We identified 25 diatom genera in three different types of sedimentary facies (porous and moss-algae rich, dense-laminated, and tufa-free gravel). Most diatoms were raphid pennate (class Bacillariophyceae), while few were centric (class Coscinodiscophyceae) or araphid pennate (class Fragilariophyceae). They appeared as integral components of the tufa structure along with cyanobacteria and other algae and mosses. Conclusions. Together with previous studies on the hydrochemistry and sedimentology of the MR, our interpretations suggest that HCO3-, pCO2, Ca2+, and TDIC negatively affect diatom richness and that their abundance is positively related to the presence of mosses and algae

El sistema de barreras tobáceas holocenas de Las Parras de Martín (Cordillera Ibérica, Teruel)

[EN] A well-developed Holocene tufa system occurs in the headwaters of Las Parras River, Iberian Range (Teruel province). The longitudinal profile of the river shows two knickpoints downstream of two gorges known as Hocino de las Palomas and Hocino del Pajazo. The largest tufa build-ups in this area (49 m and 26 m thick) were found just downstream these two gorges and associated waterfalls. Barrage and cascade structures and facies suggest a rapid down-stream and vertical development of the tufa system. Between the knickpoints and upstream, the river valley displays a low-gradient (2%) and tufa deposits occur as laterally extensive terraces, with variable thickness (up to 8.2 m in El Batán) and fluvio-lacustrine tufa sequences associated to dammed areas. The Las Parras Tufa system represents a depositional environment including stepped fluvial systems with barrage-cascade and associated dammed areas separated by low gradient fluvial stretches. According to the chronological data, the development of Las Parras Holocene tufa occurred between 9.9 ky and 3.1 ky, with the highest growth rate from 5.5 to 3.1 ky, and a significant reduction of tufa activity during the last 2000 years. This evolution reflects the water availability in the area, and is coherent with changes in summer insolation during the Holocene. © Universidad de La Rioja.[ES] En el valle del río Las Parras (Cuenca alta del río Martín, Cordillera Ibérica turolense) aparecen importantes registros tobáceos holocenos. El perfil longitudinal del río muestra dos fuertes rupturas de pendiente coincidiendo con la salida de sendos estrechamientos conocidos como los hocinos de las Palomas y del Pajazo. En estos puntos se encuentran las acumulaciones tobáceas más potentes, 49 m en el Hocino de las Palomas y 26 m en el Hocino del Pajazo, con facies que indican un crecimiento rápido en un sistema de cascadas y barreras que se desarrollan vertical y lateralmente aguas abajo. El resto del tramo estudiado presenta pendientes suaves (2%) con depósitos tobáceos fluvio-lacustres, de morfología aterrazada de gran desarrollo longitudinal y menor potencia (hasta 8 m en El Batán), asociados con represamientos. El conjunto morfosedimentario corresponde a un sistema fluvial escalonado compuesto por cascadas y áreas represadas. Los datos cronológicos indican que las tobas holocenas del río Las Parras se formaron entre 9.9 y 3.1 ka, con un periodo de mayor desarrollo entre 5.5 y 3.1 ka. En los últimos 2000 años se produce un descenso brusco en la actividad tobácea en la zona que coincide con un periodo de mínima insolación estival y probablemente con una menor disponibilidad hídrica en la zona.Este trabajo ha sido financiado por los proyectos CGL2009-10455/BTE, CGL2009- 09216/CLI, el proyecto “Clima y patrones de ocupación humana en las sierras turolenses durante el holoceno temprano” (PI089/09) financiado por el Gobierno de Aragón y por los Grupos de Investigación Paleoambientes del Cuaternario y Análisis de Cuencas Sedimentarias Continentales. Los autores agradecen a Miguel Sevilla su soporte técnico en el análisis de los datos topográficos.Peer Reviewe