9 research outputs found
Revealing early stage nuleation events of pharmaceutical crystals using liquid phase electron microscopy
Liquid phase electron microscopy has enabled the direct observation of liquid phase events that had previously been unexplored in situ at the nanoscale such as nanoparticle nucleation, electrochemical dynamics, catalysis transformations.[1, 2, 3] So far the information gathered utilising this invaluable in situ technique has gathered traction for inorganic materials as well as soft materials owing to the performance of instrumentation paired with in situ equipment e.g. TEM environmental holders and direct electron detectors
Control of Radiation Damage in MoS<sub>2</sub> by Graphene Encapsulation
Recent dramatic progress in studying various two-dimensional (2D) atomic crystals and their heterostructures calls for better and more detailed understanding of their crystallography, reconstruction, stacking order, <i>etc</i>. For this, direct imaging and identification of each and every atom is essential. Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) are ideal and perhaps the only tools for such studies. However, the electron beam can in some cases induce dramatic structure changes, and radiation damage becomes an obstacle in obtaining the desired information in imaging and chemical analysis in the (S)TEM. This is the case of 2D materials such as molybdenum disulfide MoS<sub>2</sub>, but also of many biological specimens, molecules, and proteins. Thus, minimizing damage to the specimen is essential for optimum microscopic analysis. In this article we demonstrate, on the example of MoS<sub>2</sub>, that encapsulation of such crystals between two layers of graphene allows for a dramatic improvement in stability of the studied 2D crystal and permits careful control over the defect nature and formation in it. We present STEM data collected from single-layer MoS<sub>2</sub> samples prepared for observation in the microscope through three distinct procedures. The fabricated single-layer MoS<sub>2</sub> samples were either left bare (pristine), placed atop a single-layer of graphene, or finally encapsulated between single graphene layers. Their behavior under the electron beam is carefully compared, and we show that the MoS<sub>2</sub> sample “sandwiched” between the graphene layers has the highest durability and lowest defect formation rate compared to the other two samples, for very similar experimental conditions
Control of Radiation Damage in MoS<sub>2</sub> by Graphene Encapsulation
Recent dramatic progress in studying various two-dimensional (2D) atomic crystals and their heterostructures calls for better and more detailed understanding of their crystallography, reconstruction, stacking order, <i>etc</i>. For this, direct imaging and identification of each and every atom is essential. Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) are ideal and perhaps the only tools for such studies. However, the electron beam can in some cases induce dramatic structure changes, and radiation damage becomes an obstacle in obtaining the desired information in imaging and chemical analysis in the (S)TEM. This is the case of 2D materials such as molybdenum disulfide MoS<sub>2</sub>, but also of many biological specimens, molecules, and proteins. Thus, minimizing damage to the specimen is essential for optimum microscopic analysis. In this article we demonstrate, on the example of MoS<sub>2</sub>, that encapsulation of such crystals between two layers of graphene allows for a dramatic improvement in stability of the studied 2D crystal and permits careful control over the defect nature and formation in it. We present STEM data collected from single-layer MoS<sub>2</sub> samples prepared for observation in the microscope through three distinct procedures. The fabricated single-layer MoS<sub>2</sub> samples were either left bare (pristine), placed atop a single-layer of graphene, or finally encapsulated between single graphene layers. Their behavior under the electron beam is carefully compared, and we show that the MoS<sub>2</sub> sample “sandwiched” between the graphene layers has the highest durability and lowest defect formation rate compared to the other two samples, for very similar experimental conditions
Control of Radiation Damage in MoS<sub>2</sub> by Graphene Encapsulation
Recent dramatic progress in studying various two-dimensional (2D) atomic crystals and their heterostructures calls for better and more detailed understanding of their crystallography, reconstruction, stacking order, <i>etc</i>. For this, direct imaging and identification of each and every atom is essential. Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) are ideal and perhaps the only tools for such studies. However, the electron beam can in some cases induce dramatic structure changes, and radiation damage becomes an obstacle in obtaining the desired information in imaging and chemical analysis in the (S)TEM. This is the case of 2D materials such as molybdenum disulfide MoS<sub>2</sub>, but also of many biological specimens, molecules, and proteins. Thus, minimizing damage to the specimen is essential for optimum microscopic analysis. In this article we demonstrate, on the example of MoS<sub>2</sub>, that encapsulation of such crystals between two layers of graphene allows for a dramatic improvement in stability of the studied 2D crystal and permits careful control over the defect nature and formation in it. We present STEM data collected from single-layer MoS<sub>2</sub> samples prepared for observation in the microscope through three distinct procedures. The fabricated single-layer MoS<sub>2</sub> samples were either left bare (pristine), placed atop a single-layer of graphene, or finally encapsulated between single graphene layers. Their behavior under the electron beam is carefully compared, and we show that the MoS<sub>2</sub> sample “sandwiched” between the graphene layers has the highest durability and lowest defect formation rate compared to the other two samples, for very similar experimental conditions
Probing the Bonding and Electronic Structure of Single Atom Dopants in Graphene with Electron Energy Loss Spectroscopy
A combination of scanning transmission electron microscopy,
electron
energy loss spectroscopy, and ab initio calculations reveal striking
electronic structure differences between two distinct single substitutional
Si defect geometries in graphene. Optimised acquisition conditions
allow for exceptional signal-to-noise levels in the spectroscopic
data. The near-edge fine structure can be compared with great accuracy
to simulations and reveal either an sp<sup>3</sup>-like configuration
for a trivalent Si or a more complicated hybridized structure for
a tetravalent Si impurity
Charged domain wall and polar vortex topologies in a room temperature magnetoelectric multiferroic thin
Multiferroic topologies are an emerging solution for future low-power magnetic nanoelectronics due to their
combined tuneable functionality and mobility. Here, we show that in addition to being magnetoelectric multiferroic at room
temperature, thin-film Aurivillius phase Bi6TixFeyMnzO18 is an ideal material platform for both domain wall and vortex topology based nanoelectronic devices. Utilizing atomic-resolution electron microscopy, we reveal the presence and structure of 180°-type
charged head-to-head and tail-to-tail domain walls passing throughout the thin film. Theoretical calculations confirm the subunit cell
cation site preference and charged domain wall energetics for Bi6TixFeyMnzO18. Finally, we show that polar vortex-type topologies
also form at out-of-phase boundaries of stacking faults when internal strain and electrostatic energy gradients are altered. This study
could pave the way for controlled polar vortex topology formation via strain engineering in other multiferroic thin films. Moreover,
these results confirm that the subunit cell topological features play an important role in controlling the charge and spin state of
Aurivillius phase films and other multiferroic heterostructures
Ferroelectric domain wall memristor
A domain wall-enabled memristor is created, in thin film lithium niobate capacitors, which shows up to twelve orders of magnitude variation in resistance. Such dramatic changes are caused by the injection of strongly inclined conducting ferroelectric domain walls, which provide conduits for current flow between electrodes. Varying the magnitude of the applied electric-field pulse, used to induce switching, alters the extent to which polarization reversal occurs; this systematically changes the density of the injected conducting domain walls in the ferroelectric layer and hence the resistivity of the capacitor structure as a whole. Hundreds of distinct conductance states can be produced, with current maxima achieved around the coercive voltage, where domain wall density is greatest, and minima associated with the almost fully switched ferroelectric (few domain walls). Significantly, this “domain wall memristor” demonstrates a plasticity effect:
when a succession of voltage pulses of constant magnitude is applied, the resistance changes. Resistance plasticity opens the way for the domain wall memristor to be considered for artificial synapse applications in neuromorphic circuit
Jérémie 17,1-4TM, oracle contre ou sur Juda propre au texte long, annoncé en 11,7-8.13 et en 15,12-14
A combination of scanning transmission electron microscopy, electron energy loss spectroscopy, and <i>ab initio</i> calculations is used to describe the electronic structure modifications incurred by free-standing graphene through two types of single-atom doping. The N <i>K</i> and C <i>K</i> electron energy loss transitions show the presence of π* bonding states, which are highly localized around the N dopant. In contrast, the B <i>K</i> transition of a single B dopant atom shows an unusual broad asymmetric peak which is the result of delocalized π* states away from the B dopant. The asymmetry of the B <i>K</i> toward higher energies is attributed to highly localized σ* antibonding states. These experimental observations are then interpreted as direct fingerprints of the expected p- and n-type behavior of graphene doped in this fashion, through careful comparison with density functional theory calculations
Electrostatically driven polarization flop and strain-induced curvature in free-standing ferroelectric superlattices
he combination of strain and electrostatic engineering in epitaxial heterostructures of ferroelectric oxides offers many possibilities for inducing
new phases, complex polar topologies, and enhanced electrical properties. However, the dominant effect of substrate clamping can also limit the
electromechanical response and often leaves electrostatics to play a secondary role. Releasing the mechanical constraint imposed by the substrate
can not only dramatically alter the balance between elastic and electrostatic
forces, enabling them to compete on par with each other, but also activates
new mechanical degrees of freedom, such as the macroscopic curvature of
the heterostructure. In this work, an electrostatically driven transition from
a predominantly out-of-plane polarized to an in-plane polarized state is
observed when a PbTiO3/SrTiO3 superlattice with a SrRuO3 bottom electrode
is released from its substrate. In turn, this polarization rotation modifies the
lattice parameter mismatch between the superlattice and the thin SrRuO3
layer, causing the heterostructure to curl up into microtubes. Through a
combination of synchrotron-based scanning X-ray diffraction imaging, Raman
scattering, piezoresponse force microscopy, and scanning transmission electron microscopy, the crystalline structure and domain patterns of the curved
superlattices are investigated, revealing a strong anisotropy in the domain
structure and a complex mechanism for strain accommodation