882 research outputs found
Chiral Electronics
We consider the properties of electric circuits involving Weyl semimetals.
The existence of the anomaly-induced chiral magnetic current in a Weyl
semimetal subjected to magnetic field causes an interesting and unusual
behavior of such circuits. We consider two explicit examples: i) a circuit
involving the "chiral battery" and ii) a circuit that can be used as a "quantum
amplifier" of magnetic field. The unique properties of these circuits stem from
the chiral anomaly and may be utilized for creating "chiral electronic"
devices.Comment: 5 pages, 2 figures; final version to appear in Physical Review
Surface-wave-enabled darkfield aperture for background suppression during weak signal detection
Sensitive optical signal detection can often be confounded by the presence of a significant background, and, as such, predetection background suppression is substantively important for weak signal detection. In this paper, we present a novel optical structure design, termed surface-wave-enabled darkfield aperture (SWEDA), which can be directly incorporated onto optical sensors to accomplish predetection background suppression. This SWEDA structure consists of a central hole and a set of groove pattern that channels incident light to the central hole via surface plasmon wave and surface-scattered wave coupling. We show that the surface wave component can mutually cancel the direct transmission component, resulting in near-zero net transmission under uniform normal incidence illumination. Here, we report the implementation of two SWEDA structures. The first structure, circular-groove-based SWEDA, is able to provide polarization-independent suppression of uniform illumination with a suppression factor of 1230. The second structure, linear-groove-based SWEDA, is able to provide a suppression factor of 5080 for transverse-magnetic wave and can serve as a highly compact (5.5 micrometer length) polarization sensor (the measured transmission ratio of two orthogonal polarizations is 6100). Because the exact destructive interference balance is highly delicate and can be easily disrupted by the nonuniformity of the localized light field or light field deviation from normal incidence, the SWEDA can therefore be used to suppress a bright background and allow for sensitive darkfield sensing and imaging (observed image contrast enhancement of 27 dB for the first SWEDA)
Nucleon Form Factors and Hidden Symmetry in Holographic QCD
The vector dominance of the electromagnetic form factors both for mesons and
baryons arises naturally in holographic QCD, where both the number of colors
and the 't Hooft coupling are taken to be very large, offering a bona-fide
derivation of the notion of vector dominance. The crucial ingredient for this
is the infinite tower of vector mesons in the approximations made which share
features that are characteristic of the quenched approximation in lattice QCD.
We approximate the infinite sum by contributions from the lowest four vector
mesons of the tower which turn out to saturate the charge and magnetic moment
sum rules within a few percent and compute them totally free of unknown
parameters for momentum transfers Q^2 less than 1GeV^2. We identify certain
observables that can be reliably computed within the approximations and others
that are not, and discuss how the improvement of the latter can enable one to
bring holographic QCD closer to QCD proper.Comment: 18 pages, 4 figures, revtex4; one reference added, final version to
appear in Phys. Rev.
Have You Tried This? Field-Configuring Spaces and Implementing Moral Mandates
Organizational theorists and strategy scholars are both interested in how organizations deal with ambiguity, especially in relation to implementation. This chapter examines one source of ambiguity that organizations face, which is based on their efforts to implement moral mandates. These mandates, which are related to areas such as environmental sustainability and diversity, are inherently ambiguous, as they lack a shared understanding regarding their scope and associated practices. They are also often broad and systemic and may be unclearly aligned with an organization’s strategy. Due to these challenges, in this chapter, we theorize that collective action at the field level is necessary for organizations to advance and concretize moral mandates. We examine this theorizing through the case of the implementation of sustainability in higher education. We hypothesize and find support for the idea that when an organization’s members engage in collective action at the field level, those organizations have an increased likelihood of achieving sustainability implementation. To gain insight into this field-to-organization relationship, we qualitatively examine 18 years of conversations from an online forum to develop a process model of moral mandate implementation. We theorize that collective action functions as a field-configuring space, in which actors from a variety of organizations come together to (1) refine the scope of the mandate and (2) create an implementation repertoire that actors can draw on when seeking to bring sustainability to their own organizations.</p
Coexistence of charge density wave and spin-Peierls orders in quarter-filled quasi-one dimensional correlated electron systems
Charge and spin-Peierls instabilities in quarter-filled (n=1/2) compounds
consisting of coupled ladders and/or zig-zag chains are investigated. Hubbard
and t-J models including local Holstein and/or Peierls couplings to the lattice
are studied by numerical techniques. Next nearest neighbor hopping and magnetic
exchange, and short-range Coulomb interactions are also considered. We show
that, generically, these systems undergo instabilities towards the formation of
Charge Density Waves, Bond Order Waves and (generalized) spin-Peierls modulated
structures. Moderate electron-electron and electron-lattice couplings can lead
to a coexistence of these three types of orders. In the ladder, a zig-zag
pattern is stabilized by the Holstein coupling and the nearest-neighbor Coulomb
repulsion. In the case of an isolated chain, bond-centered and site-centered
2k_F and 4k_F modulations are induced by the local Holstein coupling. In
addition, we show that, in contrast to the ladders, a small charge ordering in
the chains, strongly enhances the spin-Peierls instability. Our results are
applied to the NaV_2O_5 compound (trellis lattice) and various phases with
coexisting charge disproportionation and spin-Peierls order are proposed and
discussed in the context of recent experiments. The role of the long-range
Coulomb potential is also outlined.Comment: 10 pages, Revtex, 10 encapsulated figure
Microscopy analysis and production rate data for needleless vertical rods electrospinning parameters
AbstractA multiple vertical rod setup for needless electrospinning was used to fabricate submicron polymer fibers. The design with multiple vertical rods is a new concept for increased production of electrospun fibers. Different geometries and operating conditions are possible. The effects of varying the number of rods in the array have been studied and reported [1]. The goal of this work was a proof of concept of the threaded rod design by exploring the effects of variations in applied voltage and gap distance for a fixed array of rods. Effects on fiber diameter and production rate of fibers are reported. More extensive experiments are needed to quantify the interrelations between parameters and to guide the design and operation of the method. No attempt was made to optimize the operating parameters or the geometry in terms of production rates or fiber diameters
Plasmon tunability in metallodielectric metamaterials
The dielectric properties of metamaterials consisting of periodically
arranged metallic nanoparticles of spherical shape are calculated by rigorously
solving Maxwell's equations. Effective dielectric functions are obtained by
comparing the reflectivity of planar surfaces limiting these materials with
Fresnel's formulas for equivalent homogeneous media, showing mixing and
splitting of individual-particle modes due to inter-particle interaction.
Detailed results for simple cubic and fcc crystals of aluminum spheres in
vacuum, silver spheres in vacuum, and silver spheres in a silicon matrix are
presented. The filling fraction of the metal f is shown to determine the
position of the plasmon modes of these metamaterials. Significant deviations
are observed with respect to Maxwell-Garnett effective medium theory for large
f, and multiple plasmons are predicted to exist in contrast to Maxwell-Garnett
theory.Comment: 6 pages, 4 figure
Syntheses of spiro[cyclopropane-1,3\u27-oxindole]-2-carboxylic acid and cyclopropa[c]quinoline-7b-carboxylic acid and their derivatives
The synthesis of spiro[cyclopropane-1,3′-oxindole]-2-carboxylic acid, including novel 3-(2- and 3-pyridyl)-substituted analogues and the novel cyclopropa[c]quinoline-7b-carboxylic acid and their ester and amide derivatives is described. These syntheses involve diastereoselective cyclopropanation reactions of methyl 2-(2-nitrophenyl)acrylate and (3E)-(pyridin-2-ylmethylene)- and (3E)-(pyridin-3-ylmethylene)-1,3-dihydro-2H-indol-2-one with ethyl (dimethyl sulfuranylidene) acetate (EDSA). The synthesis of methyl cyclopropa[c]quinoline-7b-carboxylate involves a regioselective reductive cyclization of a nitro-diester precursor. The relative stereochemistry of key compounds has been determined by single-crystal X-ray structural analysis
Production of n-propyl acetate by reactive distillation : experimental and theoretical study
First steps of the development of a catalytic reactive distillation process for the production
of n-propyl acetate based on experiments and simulations are proposed. The kinetics for homogeneously (sulphuric acid) and heterogeneously (Amberlyst 15) catalysed reaction
were investigated and the constants for a pseudo-homogeneous model are presented. Pilot plant experiments were performed using a homogeneous strong acid catalyst in a packed column. A top-column decanter is used to withdraw the aqueous phase and to reflux the organic phase. Simulation results are in good agreement with experimental data. Thermodynamics nonidealities are taken into account using VLE and LLE NRTL interaction parameters. Alcohol conversion and n-propyl acetate purity may be dramatically increased just by adding to the pilot plant a stripping section in an additional column: six different configurations are identified to achieve such a production. The startup is studied in order to determine the best strategy to achieve steady-state conditions. The strong influence of the composition of the initial charging in the decanter can be seen and an initial charging of the two-phase top product leads to the fastest startup
Assimilation of IASI partial tropospheric columns with an Ensemble Kalman Filter over Europe
Partial lower tropospheric ozone columns provided by the IASI (Infrared Atmospheric Sounding Interferometer) instrument have been assimilated into a chemistry-transport model at continental scale (CHIMERE) using an Ensemble Square Root Kalman Filter (EnSRF). Analyses are made for the month of July 2007 over the European domain. Launched in 2006, aboard the MetOp-A satellite, IASI shows high sensitivity for ozone in the free troposphere and low sensitivity at the ground; therefore it is important to evaluate if assimilation of these observations can improve free tropospheric ozone, and possibly surface ozone. The analyses are validated against independent ozone observations from sondes, MOZAIC<sup>1</sup> aircraft and ground based stations (AIRBASE – the European Air quality dataBase) and compared with respect to the free run of CHIMERE. These comparisons show a decrease in error of 6 parts-per-billion (ppb) in the free troposphere over the Frankfurt area, and also a reduction of the root mean square error (respectively bias) at the surface of 19% (33%) for more than 90% of existing ground stations. This provides evidence of the potential of data assimilation of tropospheric IASI columns to better describe the tropospheric ozone distribution, including surface ozone, despite the lower sensitivity. <br><br> The changes in concentration resulting from the observational constraints were quantified and several geophysical explanations for the findings of this study were drawn. The corrections were most pronounced over Italy and the Mediterranean region, we noted an average reduction of 8–9 ppb in the free troposphere with respect to the free run, and still a reduction of 5.5 ppb at ground, likely due to a longer residence time of air masses in this part associated to the general circulation pattern (i.e. dominant western circulation) and to persistent anticyclonic conditions over the Mediterranean basin. This is an important geophysical result, since the ozone burden is large over this area, with impact on the radiative balance and air quality. <br><br><br> <sup>1</sup> Measurements of OZone, water vapour, carbon monoxide and nitrogen oxides by in-service AIrbus airCraft (<a href="http://mozaic.aero.obs-mip.fr/web/"target="_blank">http://mozaic.aero.obs-mip.fr/web/</a>)
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