Effect of organic compounds on nanoparticle formation in diluted diesel exhaust

International audienceThe nucleation of nanoparticles in the exhaust of a modern light-duty diesel vehicle was investigated on a chassis dynamometer. This laboratory study is focused on the influence of volatile organic compounds (VOCs) on nucleation of volatile nanoparticles. Different organic compounds were added to the dilution air of the particle sampling under different sampling conditions. Sample temperature and relative sample humidity were varied in a wide range. The number size distribution of the particles was measured with a scanning mobility particle sizer (SMPS) and showed significant differences in response to the added organic compounds. While the nucleation mode particles showed a large variation in concentration, the accumulation mode particles remained unchanged for all compounds. Depending on the functional group, organic compounds were capable of initiating and increasing (alcohols and toluene) or decreasing (acetone, aniline, and methyl tert-butyl ether (MTBE)) nucleation mode particles. Short volatile aliphatic hydrocarbons (hexane and cyclohexane) turned out to be without effect on nucleation of nanoparticles. Possible reasons for the differences are discussed

Which complexity of regional climate system models is essential for downscaling anthropogenic climate change in the Northwest European shelf

Climate change impact studies for the Northwest European Shelf (NWES) make use of various dynamical downscaling strategies in the experimental setup of regional ocean circulation models. Projected change signals from coupled and uncoupled downscalings with different domain sizes and forcing global and regional models show substantial uncertainty. In this paper, we investigate influences of the downscaling strategy on projected changes in the physical and biogeochemical conditions of the NWES. Our results indicate that uncertainties due to different downscaling strategies are similar to uncertainties due to the choice of the parent global model and the downscaling regional model. Downscaled change signals reveal to depend stronger on the downscaling strategy than on the model skills in simulating present-day conditions. Uncoupled downscalings of sea surface temperature (SST) changes are found to be tightly constrained by the atmospheric forcing. The incorporation of coupled air-sea interaction, by contrast, allows the regional model system to develop independently. Changes in salinity show a higher sensitivity to open lateral boundary conditions and river runoff than to coupled or uncoupled atmospheric forcings. Dependencies on the downscaling strategy for changes in SST, salinity, stratification and circulation collectively affect changes in nutrient import and biological primary production

RCP8.5-projected changes in German Bight storm surge characteristics from regionalized ensemble simulations for the end of the twenty-first century

This study investigates climate-induced changes in height, frequency and duration of storm surges in the German Bight. The regionally coupled climate model system MPIOM-REMO with a focus on the North Sea has been utilized to dynamically downscale 30 members of the global climate model system MPI-ESM1.1-LR for the historical period 1950–2005 and a continuation until 2099 with the RCP8.5 scenario. Results of all members have been collected into the historical (1970–1999) and the rcp85 (2070–2099) data pools amounting to 900 years of the corresponding climate state. The global mean sea level rise was not considered. Nevertheless, the mean ensemble German Bight SSH trend amounts to about 13 ± 1 cm/century (PI control: 3 cm/century) due to adaptation of the ocean circulation to the changing climatic conditions. Storm surges were defined as SSH above mean high tidal water plus 1.5, 2.5, 3.5 m for “regular”, heavy, extreme storm surges, and then clustered to events. Our simulated storm surge events show a clear location-dependent increase in frequency (6–11), median duration (4–24), and average duration (9–20) in the German Bight. Only along the central German Bight coast (Cuxhaven), longer lasting events gain more relevance. Heavy storm surge events show also a strong increase in frequency (7–34) and average duration (10–22). Maximum sea levels during storm events increase strongest and most significant along the northern German Bight and Danish coasts with more than 30 cm/century for the 60-year return period at Hörnum and 10–15 cm/century for shorter return periods. Levels of return periods shorter than a few years significantly increase everywhere along the southern German Bight coasts (around 5 cm/century for the 2-year return period). Highest SSH maxima do not change, and consequently, extreme storm surge events show hardly any response to climate change. Furthermore, our results indicate a shift of seasonality from the last to the first quarter of a year. As the main driver for the encountered alteration of German Bight storm surge characteristics, we identified a change in wind conditions with a pronounced increase of frequency of strong westerly winds

The comet 17P/Holmes 2007 outburst: the early motion of the outburst material

Context. On October 24, 2007 the periodic comet 17P/Holmes underwent an astonishing outburst that increased its apparent total brightness from magnitude V\sim17 up to V\sim2.5 in roughly two days. We report on Wendelstein 0.8 m telescope (WST) photometric observations of the early evolution stages of the outburst. Aims. We studied the evolution of the structure morphology, its kinematic, and estimated the ejected dust mass. Methods. We analized 126 images in the BVRI photometric bands spread between 26/10/2007 and 20/11/2007. The bright comet core appeared well separated from that one of a quickly expanding dust cloud in all the data, and the bulk of the latter was contained in the field of view of our instrument. The ejected dust mass was derived on the base of differential photometry on background stars occulted by the moving cloud. Results. The two cores were moving apart from each other at a relative projected constant velocity of (9.87 +/- 0.07) arcsec/day (0.135 +/-0.001 km/sec). In the inner regions of the dust cloud we observed a linear increase in size at a mean constant velocity of (14.6+/-0.3) arcsec/day (0.200+/-0.004 km/sec). Evidence of a radial velocity gradient in the expanding cloud was also found. Our estimate for the expanding coma's mass was of the order of 10^{-2}-1 comet's mass implying a significant disintegration event. Conclusions. We interpreted our observations in the context of an explosive scenario which was more probably originated by some internal instability processes, rather than an impact with an asteroidal body. Due to the peculiar characteristics of this event, further observations and investigations are necessary in order to enlight the nature of the physical processes that determined it.Comment: 5 pages, 3 figures, A&A accepte

Video analysis of the locomotory behaviour of Aedes aegypti and Ae. japonicus mosquitoes under different temperature regimes in a laboratory setting

Mosquito-borne diseases impose a high burden on human and animal health. Temperature strongly influences the physiology and life cycle of mosquitoes, but also the development and/or propagation of the pathogens they transmit. Thus, the vector capacity of mosquitoes depends strongly on temperature and their behavioural thermoregulation through microhabitat selection. Expanding on a previous study of static thermal preferences, the locomotory dynamics of temperate Aedes japonicus (reared from eggs collected in the field) and tropical Ae. aegypti (from a laboratory colony) was investigated at constant temperatures (10 °C, 25 °C, 40 °C) and in temperature gradients (10-20 °C, 20-30 °C, 30-40 °C). Blood-fed or non-blood-fed female mosquitoes were released in groups of 15 individuals into a Plexiglas box positioned on two thermoregulators connected by an aluminium plate to automatically monitor by video analysis mosquito flying, walking and resting duration, covered distances and velocity. Mosquitoes were predominantly resting, followed by walking and flying. At constant 10 °C, flights were rare and brief, and walking was slow. Most activity was observed at 25 °C for Ae. japonicus and 40 °C for Ae. aegypti. In the 30-40 °C gradient, activity of Ae. aegypti increased towards the cold end, suggesting active avoidance of very high temperatures. In the 20-30 °C gradient, edge effects were prominent, nevertheless revealing a greater proportion of mosquitoes gathered at the cooler end. Video analysis showed that this effect was not caused by a cold trap but represents true thermal preference. In the coolest gradient (10-20 °C), mosquitoes were active in all sectors without displaying a preference for either side. Overall, both the tropical and temperate mosquito species preferred cooler temperatures and actively avoided the hottest temperatures. Further studies with infected mosquitoes should provide important insights for developing models of vector-borne disease outbreaks

Photo-double-ionization of water at 20 eV above threshold

The photodouble ionization of the water molecule is studied at 20 eV excess energy in a combined experimental and theoretical investigation. In the experiments, two photoelectrons of equal kinetic energy are detected in coincidence after energy and angular selection. On the theoretical side, a generalized Sturmian function approach is implemented to describe accurately the correlated two-electron continuum, while separable products of Moccia orbitals [J. Chem. Phys. 40, 2164 (1964)JCPSA60021-960610.1063/1.1725489] are used for the initial electronic state of the water molecule. The theoretical triple-differential cross sections (TDCSs) are averaged over all possible molecular orientations in order to be compared with the experiments. The measured TDCSs display rich angular distributions that are in large part well reproduced by the adopted first-order treatment of the interaction with a two-active-electron target.Fil: Randazzo, Juan Martin. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Turri, G.. Embry-riddle Aeronautical University, Physical Sciences; Estados UnidosFil: Bolognesi, P.. CNR-Istituto di Struttura della Materia; ItaliaFil: Mathis, J.. Embry-riddle Aeronautical University, Physical Sciences; Estados UnidosFil: Ancarani, L. U.. Université de Lorraine; FranciaFil: Avaldi, L.. CNR-Istituto di Struttura della Materia; Itali

Tracing the sites of obscured star formation in the Antennae galaxies with Herschel-PACS

FIR imaging of interacting galaxies allows locating even hidden sites of star formation and measuring of the relative strength of nuclear and extra-nuclear star formation. We want to resolve the star-forming sites in the nearby system of the Antennae. Thanks to the unprecedented sharpness and depth of the PACS camera onboard ESA's Herschel Space Observatory, it is possible for the first time to achieve a complete assessment of individual star-forming knots in the FIR with scan maps at 70, 100, and 160 um. We used clump extraction photometry and SED diagnostics to derive the properties related to star-forming activity. The PACS 70, 100, and 160 um maps trace the knotty structure of the most recent star formation along an arc between the two nuclei in the overlap area. The resolution of the starburst knots and additional multi-wavelength data allow their individual star formation history and state to be analysed. In particular, the brightest knot in the mid-infrared (K1), east of the southern nucleus, exhibits the highest activity by far in terms of dust heating and star formation rate, efficiency, and density. With only 2 kpc in diameter, this area has a 10-1000 um luminosity, which is as high as that of our Milky Way. It shows the highest deficiency in radio emission in the radio-to-FIR luminosity ratio and a lack of X-ray emission, classifying it as a very young complex. The brightest 100 and 160 um emission region (K2), which is close to the collision front and consists of 3 knots, also shows a high star formation density and efficiency and lack of X-ray emission in its most obscured part, but an excess in the radio-to-FIR luminosity ratio. This suggests a young stage, too, but different conditions in its interstellar medium. Our results provide important checkpoints for numerical simulations of interacting galaxies when modelling the star formation and stellar feedback.Comment: 4 pages, 4 figures, 2 tables (A&A Herschel special issue

A Combined Experimental and Theoretical Study of Photodouble Ionization of Water at 32 eV Excess Energy and Unequal Energy Sharing

In this paper we present a part of our investigation of the photodouble ionization (PDI) of gaseous water. Synchrotron radiation from ELETTRA storage ring was used to ionize the water molecule, and the two emitted electrons were collected in coincidence after angle and energy selection. We have compared the measured dication states with those known from literature and showed the angular distributions of the two photoelectrons measured for the first time, for different excess energies and under different energy sharing conditions. A detailed comparison with theoretical calculations is given to help understand some details of the PDI mechanism.Fil: Penson, Conner. Embry-riddle Aeronautical University; Estados UnidosFil: Turri, Giorgio. Full Sail University; Estados UnidosFil: Avaldi, Lorenzo. Consiglio Nazionale delle Ricerche; ItaliaFil: Randazzo, Juan Martin. Comisión Nacional de Energí­a Atómica. Gerencia del Area Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Balseiro). División Colisiones Atómicas; Argentina. University of Central Florida; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Ancarani, Lorenzo Ugo. Université de Lorraine; FranciaFil: Bolognesi, Paola. Consiglio Nazionale delle Ricerche; Itali

Dual Microsporidial Infection Due to Vittaforma corneae and Encephalitozoon hellem in a Patient with AIDS

A 46-year-old human immunodeficiency virus-infected Swiss citizen living in Tanzania presented with respiratory, abdominal, and urogenital complaints. Microsporidial spores were isolated from urine and a sinunasal aspirate and were propagated in MRC-5 cell cultures. Western blot analysis and riboprinting identified the sinunasal isolate as Encephalitozoon hellem. Electron microscopic investigation of the urine isolate revealed spores with diplokaryotic nuclei and five to six isofilar coils of the polar tube and sporonts with two or three diplokarya. All stages were enveloped by two membranes, corresponding to a cisterna of host endoplasmic reticulum studded with ribosomes. These characteristics have been described for the genus Vittaforma. Western blot analysis of this isolate revealed a banding pattern identical to that of the Vittaforma corneae reference isolate. Part of the small subunit rRNA gene was amplified, sequenced (239 base pairs), and found to be identical to that of V. corneae. This is the second isolation of V. corneae and the first description of urinary tract infection due to V. corneae in a patient with AID