Water chemistry reveals a significant decline in coral calcification rates in the southern Red Sea

Experimental and field evidence support the assumption that global warming and ocean acidification is decreasing rates of calcification in the oceans. Local measurements of coral growth rates in reefs from various locations have suggested a decline of ~6–10% per decade since the late 1990's. Here, by measuring open water strontium-to-alkalinity ratios along the Red Sea, we show that the net contribution of hermatypic corals to the CaCO3 budget of the southern and central Red Sea declined by ~100% between 1998 and 2015 and remained low between 2015 and 2018. Measured differences in total alkalinity of the Red Sea surface water indicate a 26 ± 16% decline in total CaCO3 deposition rates along the basin. These findings suggest that coral reefs of the southern Red Sea are under severe stress and demonstrate the strength of geochemical measurements as cost-effective indicators for calcification trends on regional scales

Sulfur isotope patterns of iron sulfide and barite nodules in the Upper Cretaceous Chalk of England and their regional significance in the origin of coloured chalks

The relationship between the development of iron sulfide and barite nodules in the Cenomanian Chalk of England and the presence of a red hematitic pigment has been investigated using sulfur isotopes. In southern England where red and pink chalks are absent, iron sulfide nodules are widespread. Two typical large iron sulfide nodules exhibit δ34S ranging from −48.6‰ at their core to −32.6‰ at their outer margins. In eastern England, where red and pink chalks occur in three main bands, there is an antipathetic relationship between the coloured chalks and the occurrence of iron sulfide or barite nodules. Here iron sulfide, or its oxidised remnants, are restricted to two situations: (1) in association with hard grounds that developed originally in chalks that contained the hematite pigment or its postulated precursor FeOH3, or (2) in regional sulfidization zones that cut across the stratigraphy. In the Cenomanian Chalk exposed in the cliffs at Speeton, Yorkshire, pyrite and marcasite (both iron sulfide) nodules range in δ34S from −34.7‰ to +40.0‰. In the lower part of the section δ34S vary from −34.8‰ to +7.8‰, a single barite nodule has δ34S between +26.9‰ and +29.9‰. In the middle part of the section δ34S ranges from +23.8‰ to +40.0‰. In the sulfidization zones that cut across the Cenomanian Chalk of Lincolnshire the iron sulfide nodules are typically heavily weathered but these may contain patches of unoxidised pyrite. In these zones, δ34S ranges from −32.9‰ to +7.9‰. The cross-cutting zones of sulfidization in eastern England are linked to three basement faults – the Flamborough Head Fault Zone, the Caistor Fault and the postulated Wash Line of Jeans (1980) – that have affected the deposition of the Chalk. It is argued that these faults have been both the conduits by which allochthonous fluids – rich in hydrogen sulfide/sulfate, hydrocarbons and possibly charged with sulfate-reducing bacteria – have penetrated the Cenomanian Chalk as the result of movement during the Late Cretaceous or Cenozoic. These invasive fluids are associated with (1) the reduction of the red hematite pigment or its praecursor, (2) the subsequent development of both iron sulfides and barite, and (3) the loss of overpressure in the Cenomanian Chalk and its late diagenetic hardening by anoxic cementation. Evidence is reviewed for the origin of the red hematite pigment of the coloured chalks and for the iron involved in the development of iron sulfides, a hydrothermal or volcanogenic origin is favoured

The quasistatics thermal stress analysis in coated half-space with mixed boundary heating conditions

Побудовано розв’язок плоскої квазістатичної задачі термопружності для півпростору з покриттям, на границі якого в смузі певної ширини задана температура, а зовні відбувається теплообмін за законом Ньютона. Розв’язок отримано із використанням інтегральних перетворень Лагерра й Фур’є та методу рядів Фур’є при розв’язуванні послідовностей парних інтегральних рівнянь. Наведено результати числового аналізу термонапруженого стану в півпросторі та покритті залежно від відносної товщини покриття та інтенсивності охолодження.Analysis of thermal stresses in bodies with coatings is important for many engineering researches. Taking into account the actual operating conditions of these structures frequently leads to mixed heating condition. The steady problem of thermoelasticity with mixed boundary conditions currently is sufficiently investigated. However, the corresponding transient problem, despite its relevance, is poorly understood. This is due to mathematical difficulties that arise in applying the integral Laplace transform. The authors of this paper developed a new effective method of constructing solutions of mixed boundary-value non-stationary problems. The half-space with a coating, on the surface of which on the band of 2d width the temperature distribution is given and outside of this area the heat transfer according to the Newton's law is performed, is analysed in the work. On the surface of separation of materials of half-space and coating the conditions of ideal thermomechanical contact are satisfied. The initial temperature of the coating and half-space is equal to zero. To the heat conductivity problem the Laguerre integral transformation in time variables and integral Fourier transformation in spatial variable are applied. As a result the triangular sequence of ordinary differential equations is obtained. The general solution of these sequences is obtained in the form of algebraic convolution. Taking into account the mixed boundary conditions results in dual integral equations. For solution of this problem the method of Newton's series is proposed. Taking advantage of this method the problem is reduced to the infinite system of algebraic equations, for which the convergence of reduction procedure is proved. The solution of thermoelasticity problem is built using resulting temperature field in the assumption, that the border of coating is free of load. The solution is obtained in the form of series in Laguerre polynomials. Calculations were carried for the half-space made of titanium alloy and ceramic coating

Coupled measurements of δ18O and δD of hydration water and salinity of fluid inclusions in gypsum from the Messinian Yesares Member, Sorbas Basin (SE Spain)

Financial support was provided by Clare College Geological Research Fund to N.P. Evans. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007–2013)/ERC Grant Agreement n. 339694 (Water Isotopes of Hydrated Minerals) to D.A. Hodell.We studied one cycle (Cycle 6) of gypsum-marl deposition from the Messinian Yesares Member in Sorbas Basin, Spain. The objective was to reconstruct the changing environment of deposition and its relation to astronomically-forced climate change. The δ18O and δD of gypsum hydration water (CaSO4 • 2H2O) and salinity of fluid inclusions were measured in the same samples to test if they record the composition of the mother fluid from which gypsum was precipitated. Water isotopes are highly correlated with fluid inclusion salinity suggesting the hydration water has not exchanged after formation. The relatively low water isotope values and fluid inclusion salinities indicate a significant influence of meteoric water, whereas δ34S, δ18OSO4 and 87Sr/86Sr support a dominant marine origin for the gypsum deposits. The discrepancy between water and elemental isotope signatures can be reconciled if meteoric water dissolved previously deposited marine sulfates supplying calcium and sulfate ions to the basin which maintained gypsum saturation. This recycling process accounts for the marine δ34S, δ18OSO4 and 87Sr/86Sr signatures, whereas the low δ18O and δD values of gypsum hydration water and fluid inclusion salinities reflect the influence of freshwater. The cyclic deposition of gypsum and marl in the Yesares Member has previously been interpreted to reflect changing climate related to Earth's precession cycle. We demonstrate that the δ18O, δD and salinity of the parent brine increased from low values at the base of the cycle to a maximum in the massive gypsum palisade, and decreased again to lower values in the supercones at the top of the cycle. This pattern, together with changes in mineralogy (calcite-dolomite-gypsum), is consistent with a precession-driven change in climate with wettest conditions (summer insolation maxima) associated with the base of the calcium carbonate marls and driest conditions (summer insolation minima) during formation of the gypsum palisade.Publisher PDFPeer reviewe

Impact of Aeolian Dry Deposition of Reactive Iron Minerals on Sulfur Cycling in Sediments of the Gulf of Aqaba

The Gulf of Aqaba is an oligotrophic marine system with oxygen-rich water column and organic carbon-poor sediments (≤0.6% at sites that are not influenced by anthropogenic impact). Aeolian dust deposition from the Arabian, Sinai, and Sahara Deserts is an important source of sediment, especially at the deep-water sites of the Gulf, which are less affected by sediment transport from the Arava Desert during seasonal flash floods. Microbial sulfate reduction in sediments is inferred from the presence of pyrite (although at relatively low concentrations), the presence of sulfide oxidation intermediates, and by the sulfur isotopic composition of sulfate and solid-phase sulfides. Saharan dust is characterized by high amounts of iron minerals such as hematite and goethite. We demonstrated, that the resulting high sedimentary content of reactive iron(III) (hydr)oxides, originating from this aeolian dry deposition of desert dust, leads to fast re-oxidation of hydrogen sulfide produced during microbial sulfate reduction and limits preservation of reduced sulfur in the form of pyrite. We conclude that at these sites the sedimentary sulfur cycle may be defined as cryptic

Improving Patent Quality Through Post-Grant Claim Amendments: A Comparison of European Opposition Proceedings and U.S. Post-Grant Proceedings

Congress enacted the Leahy-Smith America Invents Act to encourage innovation, strengthen U.S. patents, and achieve greater uniformity with foreign patent systems. The America Invents Act introduced two new post-grant patent validity proceedings: inter partes review and post-grant review. The new U.S. proceedings are similar to European opposition proceedings, but there are significant differences in the extent of the patent owner’s ability to amend claims, the patent’s claim construction, the patent owner’s evidentiary burden, and the procedural requirements. The U.S. proceedings result in a very limited opportunity for amendment and a high percentage of invalidated patents. In contrast, European opposition proceedings are generally more conducive to upholding patents, whether in original or amended form. The current U.S. practice for amending claims in post-grant proceedings should be changed to both achieve balance between claim vitality and extent of opportunity to amend, and to serve the America Invents Act’s goals of strengthening patents and encouraging innovation. A full adoption of the European opposition claim amendment practice, particularly the claim construction standard and expansive opportunity for amendment, would fail to balance claim vitality and ease of amendment, favor patent owners, and disserve the goals of the America Invents Act. This Note nevertheless advocates for adoption of certain European characteristics to improve U.S. post-grant proceedings