Large scale modeling of the transport, chemical transformation and mass budget of the sulfur emitted during the April 2007 eruption of Piton de la Fournaise

In April 2007, the Piton de la Fournaise volcano (Réunion island) entered into its biggest eruption recorded in the last century. Due to the absence of a sensors network in the vicinity of the volcano, an estimation of degassing during the paroxysmal phase of the event has not been performed. Nevertheless, the SO<sub>2</sub> plume and aerosols have been observed by the OMI and CALIOP space sensors, respectively. The mesoscale chemical model MesoNH-C simulates the observed bulk mass of SO<sub>2</sub> and the general shape of the SO<sub>2</sub> plume spreading over the Indian Ocean. Moreover, an analysis of the SO<sub>2</sub> plume budget estimates a total SO<sub>2</sub> release of 230 kt, among of which 60 kt have been transformed into H<sub>2</sub>SO<sub>4</sub>. 27 kt of SO<sub>2</sub> and 21 kt of H<sub>2</sub>SO<sub>4</sub> have been deposited at the surface by dry deposition. With this top down approach, the temporal evolution of the SO<sub>2</sub> emission has been estimated during the most active period of the eruption. The peak of degassing was estimated at 1800 kg s<sup>−1</sup> in the morning of 6~April. The temporal evolution of SO<sub>2</sub> emission presented here can also be used for local studies

3D direct impacts of urgan aerosols on dynamics during the CAPITOUL field experiment

International audienceEvaluating the radiative impacts of aerosol particles is of great interest for understanding atmospheric physics and processes feedbacks. To respond to such objectives, the online fully coupled model Meso-NH is applied to a real case during a two-day Intensive Observation Period (IOP) of the CAPITOUL campaign. The aerosol optical properties are computed from the chemical composition and the size distribution of the particle population, and are compared to observations and analysed at local and regional scales. The differences between two simulations are then studied in order to isolate the direct radiative impacts of aerosols on dynamics. Results show that the aerosol particles generate a forcing on shortwave flux by a decrease of the amount reaching the surface up to 30 Wm−2. The resulting feedbacks lead to a cooling up to 0.6 K on the 2-meter temperature over the city of Toulouse and over the larger 125 km by 125 km area around Toulouse. This cooling is also modeled along the whole boundary layer, leading to a decrease of the boundary layer height up to −50 m during the afternoon and a decrease of the vertical velocities with an average of −3 %

Les frères ennemis : antagonismes entre grands planteurs et exportateurs de café sur la Costa Cuca (Guatemala)

Les relations entre grands planteurs et exportateurs de café de l'oligarchie guatémaltèque manifestent des intérêts contradictoires, le café étant le produit moteur de l'économie agricole d'exportation et le principal pourvoyeur du pays en devises. Les mutations qu'a connues la région depuis un siècle révèlent des dynamiques socio-économiques qui loin d'être isolées structurent le pays. (Résumé d'auteur

Numerical study of tracers transport by a mesoscale convective system over West Africa

A three-dimensional cloud-resolving model is used to investigate the vertical transport from the lower to the upper troposphere in a mesoscale convective system (MCS) that occurred over Niger on 15 August 2004. The redistribution of five passive tracers initially confined in horizontally homogeneous layers is analyzed. The monsoon layer tracer (0–1.5 km) is the most efficiently transported in the upper troposphere with concentrations 3 to 4 times higher than the other tracers in the anvil. On the contrary the African Easterly Jet tracer (~3 km) has the lowest contribution above 5 km. The vertical profiles of the mid-troposphere tracers (4.5–10 km) in the MCS exhibit two peaks: one in their initial layers, and the second one at 13–14 km altitude, underlying the importance of mid-tropospheric air in feeding the upper troposphere. Mid-tropospheric tracers also experience efficient transport by convective downdrafts with a consequent increase of their concentrations at the surface. The concentration of the upper troposphere–lower stratosphere tracer exhibits strong gradients at the edge of the cloud, meaning almost no entrainment of this tracer into the cloud. No downward transport from the upper troposphere is simulated below 5 km. A proxy for lightning produced NO_x is transported preferentially in the forward anvil in the upper troposphere. Additionally, lateral inflows significantly contribute to the updraft and downdraft airflows emphasizing the three-dimensional structure of the West African MCSs

Space optical instruments optimisation thanks to CMOS image sensor technology

Today, both CCD and CMOS sensors can be envisaged for nearly all visible sensors and instruments designed for space needs. Indeed, detectors built with both technologies allow excellent electro-optics performances to be reached, the selection of the most adequate device being driven by their functional and technological features and limits. The first part of the paper presents electro-optics characterisation results of CMOS Image Sensors (CIS) built with an optimised CMOS process, demonstrating the large improvements of CIS electro-optics performances. The second part reviews the advantages of CMOS technology for space applications, illustrated by examples of CIS developments performed by EADS Astrium and Supaéro/CIMI for current and short term coming space programs

Modeling secondary organic aerosol formation through cloud processing of organic compounds

Interest in the potential formation of secondary organic aerosol (SOA) through reactions of organic compounds in condensed aqueous phases is growing. In this study, the potential formation of SOA from irreversible aqueous-phase reactions of organic species in clouds was investigated. A new proposed aqueous-phase chemistry mechanism (AqChem) is coupled with the existing gas-phase Caltech Atmospheric Chemistry Mechanism (CACM) and the Model to Predict the Multiphase Partitioning of Organics (MPMPO) that simulate SOA formation. AqChem treats irreversible organic reactions that lead mainly to the formation of carboxylic acids, which are usually less volatile than the corresponding aldehydic compounds. Zero-dimensional model simulations were performed for tropospheric conditions with clouds present for three consecutive hours per day. Zero-dimensional model simulations show that 48-h average SOA formation is increased by 27% for a rural scenario with strong monoterpene emissions and 7% for an urban scenario with strong emissions of aromatic compounds, respectively, when irreversible organic reactions in clouds are considered. AqChem was also incorporated into the Community Multiscale Air Quality Model (CMAQ) version 4.4 with CACM/MPMPO and applied to a previously studied photochemical episode (3–4 August 2004) focusing on the eastern United States. The CMAQ study indicates that the maximum contribution of SOA formation from irreversible reactions of organics in clouds is 0.28 μg m<sup>−3</sup> for 24-h average concentrations and 0.60 μg m<sup>−3</sup> for one-hour average concentrations at certain locations. On average, domain-wide surface SOA predictions for the episode are increased by 9% when irreversible, in-cloud processing of organics is considered. Because aldehydes of carbon number greater than four are assumed to convert fully to the corresponding carboxylic acids upon reaction with OH in cloud droplets and this assumption may overestimate carboxylic acid formation from this reaction route, the present study provides an upper bound estimate of SOA formation via this pathway

High performances monolithic CMOS detectors for space applications

During the last 10 years, research about CMOS image sensors (also called APS -Active Pixel Sensors) has been intensively carried out, in order to offer an alternative to CCDs as image sensors. This is particularly the case for space applications as CMOS image sensors feature characteristics which are obviously of interest for flight hardware: parallel or semi-parallel architecture, on chip control and processing electronics, low power dissipation, high level ofradiation tolerance... Many image sensor companies, institutes and laboratories have demonstrated the compatibility of CMOS image sensors with consumer applications: micro-cameras, video-conferencing, digital-still cameras. And recent designs have shown that APS is getting closer to the CCD in terms ofperformance level. However, the large majority ofthe existing products do not offer the specific features which are required for many space applications. ASTRI1JM and SUPAERO/CIMI have decided to work together in view of developing CMOS image sensors dedicated to space business. After a brief presentation of the team organisation for space image sensor design and production, the latest results of a high performances 512x512 pixels CMOS device characterisation are presented with emphasis on the achieved electro-optical performance. Finally, the on going and short-term coming activities of the team are discussed

Development of high-performances monolithic CMOS detectors for space applications

This paper describes the development of a 750x750 pixels CMOS image sensor for star tracker applications. A first demonstrator of such a star tracker called SSM star tracker built around a 512x512 detector has been recently developed and proves the feasibility of such instrument. In order to take fully advantage of the CMOS image sensor step, the 750x750 device called SSM CMOS detector which will take part of the final star tracker, can be considered as a major technical breakthrough that gives a decisive advantage in terms of on satellite implementation cost and flexibility (sensor mass and power consumption minimisation, electronics and architecture flexibility). Indeed, built using the 0.5μm Alcatel Microelectronics standard CMOS technology, the SSM CMOS detector will feature on-chip temperature sensor and on-chip sequencer. In order to evaluate the radiation tolerance of such manufacturing technology, a radiation campaign that contains studies of total dose and latch-up effects has been led on a specific test vehicle