159 research outputs found
ArchĂ©polis. ArchĂ©ologie et histoire de lâespace public Ă Â Thasos
DonnĂ©es scientifiques produites : WebSIG de ThasosGuillaume Biard, Julien Fournier, Marjolaine Imbs, « Lâautel des CĂ©sars sur lâagora de Thasos », BCH 142, 2018, p. 725â769Natacha TrippĂ©, « Nouvelles recherches sur lâagora de Thasos : de la topographie Ă lâhistoire », BCH 143.1, 2019, p. 195-224 Natacha TrippĂ©, Marjolaine Imbs, « Lâautel du sanctuaire de Zeus sur lâagora de Thasos », BCH 145.2, 2021, p. 15-41. Natacha TrippĂ©, « Lâarticulation de lâespace religieux et de lâespace civique : lâ..
Tetrathiafulvalene-Based Architectures: From Guests Recognition to Self-Assembly
The tetrathiafulvalene (TTF) unit has been successfully used for an incredibly broad range of applications. Beyond the well-established conducting properties of the corresponding cation-radical salts, this unit has appeared as a key redox-active component for various applications supported by its remarkable redox properties: a high Ï-donating ability and occurrence of three stable redox states. This article reviews the main contribution of the group of Angers to this field, highlighting results obtained in terms of redox-sensing as well as efforts carried out to reach new self-assembled TTF-based architectures
4,6,7,9,10,12-Hexahydro-1,3-dithiolo[4,5-f][1,4,9]oxadithiaÂcycloÂundecine-2-thione
In the title molÂecule, C9H12S5O, the five-membered ring and attached S atom are essentially coplanar [mean deviation from the mean plane = 0.020â
(1)â
Ă
]. The two S atoms belonging to the macrocycle deviate from this plane by 1.005â
(1) and 1.337â
(2)â
Ă
. In the crystal, ÏâÏ interÂactions link the molÂecules into centrosymmetric dimers with a short distance of 3.753â
(5)â
Ă
between the centroids of the five-membered rings
Methyl 2,3-(3,6,9-trioxaundecane-1,11-diyldithio)-1,4,5,8-tetraÂthiaÂfulvalene-6-carboxylÂate
In the title molÂecule, C16H20O5S6, the two five-membered rings form a dihedral angle of 4.7â
(3)°. The crystal packing exhibits weak interÂmolecular CâHâŻO hydrogen bonds, which link the molÂecules into chains propagating in [10], and ÏâÏ interÂactions, indicated by the short distances [3.756â
(5)â
Ă
] between the centroids of five-membered rings from molÂecules related by translation along the b axis
An extended tetrathiafulvalene redox-ligand incorporating a thiophene spacer
An extended tetrathiafulvalene derivative incorporating a thiophene spacer and a fused crown-ether unit has been synthesized. This highly delocalized system exhibits remarkable electrochemical recognition properties for Na+ and Ba2+ as shown by cyclic voltammetry in methylene chloride. This result is attributed to the proximity between the guest metal cation and the positive charge of the oxidized ligand, which is located on the central conjugated thiophenic part
Taming Friedrich-Wintgen interference in resonant metasurface: vortex laser emitting at on-demand tilted-angle
Friedrich-Wintgen (FW) interference is an atypical coupling mechanism that
grants loss exchange between leaky resonances in non-Hermitian classical and
quantum systems. Intriguingly, such an mechanism makes it possible for
destructive interference scenario in which a radiating wave becomes a bound
state in the continuum (BIC) by giving away all of its losses. Here we propose
and demonstrate experimentally an original concept to tailor FW-BICs as
polarization singularity at on-demand wavevectors in optical metasurface. As a
proof-of-concept, using hybrid organic-inorganic halide perovskite as active
material, we empower this novel polarization singularity to obtain lasing
emission exhibiting both highly directional emission at oblique angles and
polarization vortex in momentum space. Our results pave the way to steerable
coherent emission with tailored polarization pattern for applications in
optical communication/manipulation in free-space, high-resolution imaging
/focusing and data storage
Multinuclear NMR as a tool for studying local order and dynamics in CH3NH3PbX3 (X = Cl, Br, I) hybrid perovskites
International audienceWe report on Pb, Br, N, H, C and H NMR experiments for studying the local order and dynamics in hybrid perovskite lattices. Pb NMR experiments conducted at room temperature on a series of MAPbX compounds (MA = CHNH; X = Cl, Br and I) showed that the isotropic Pb NMR shift is strongly dependent on the nature of the halogen ions. Therefore Pb NMR appears to be a very promising tool for the characterisation of local order in mixed halogen hybrid perovskites. Pb NMR on MAPbBrI served as a proof of concept. Proton, C and N NMR experiments confirmed the results previously reported in the literature. Low temperature deuterium NMR measurements, down to 25 K, were carried out to investigate the structural phase transitions of MAPbBr. Spectral lineshapes allow following the successive phase transitions of MAPbBr. Finally, quadrupolar NMR lineshapes recorded in the orthorhombic phase were compared with simulated spectra, using DFT calculated electric field gradients (EFG). Computed data do not take into account any temperature effect. Thus, the discrepancy between the calculated and experimental EFG evidences the fact that MA cations are still subject to significant dynamics, even at 25 K
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