Autonomous motility of polymer films coupled to stimuli gradients

Adaptive soft materials exhibit a diverse set of behaviors including reconfiguration, actuation, and locomotion. These responses are typically optimized in isolation. Here, we explore the interrelation between these behaviors by developing a behavioral phase diagram for hygromorphic polymer films. We determine that the dynamic behaviors are a result of not only a response to, but also an interaction with a humidity gradient, which can be tuned via control of the environment and film characteristics, including size, permeability and coefficient of hygroscopic expansion to target a desired behavior such as multi-modal locomotion. Using the improved understanding of stimuli interactive materials gained from our study of monolithic polymer films, we demonstrate how robust composites can be designed to exhibit autonomous, environmentally-responsive behaviors, and how these concepts can be incorporated into origami structures to engineer the extent and sequence of motions

Laser writing of electronic circuitry in thin film molybdenum disulfide: A transformative manufacturing approach

Electronic circuits, the backbone of modern electronic devices, require precise integration of conducting, insulating, and semiconducting materials in two- and three-dimensional space to control the flow of electric current. Alternative strategies to pattern these materials outside of a cleanroom environment, such as additive manufacturing, have enabled rapid prototyping and eliminated design constraints imposed by traditional fabrication. In this work, a transformative manufacturing approach using laser processing is implemented to directly realize conducting, insulating, and semiconducting phases within an amorphous molybdenum disulfide thin film precursor. This is achieved by varying the incident visible (514 nm) laser intensity and raster-scanning the thin film a-MoS2 sample (900 nm thick) at different speeds for micro-scale control of the crystallization and reaction kinetics. The overall result is the transformation of select regions of the a-MoS2 film into MoO2, MoO3, and 2H-MoS2 phases, exhibiting conducting, insulating, and semiconducting properties, respectively. A mechanism for this precursor transformation based on crystallization and oxidation is developed using a thermal model paired with a description of the reaction kinetics. Finally, by engineering the architecture of the three crystalline phases, electrical devices such as a resistor, capacitor, and chemical sensor were laser-written directly within the precursor film, representing an entirely transformative manufacturing approach for the fabrication of electronic circuitry

Prioritizing Land and Sea Conservation Investments to Protect Coral Reefs

Background: Coral reefs have exceptional biodiversity, support the livelihoods of millions of people, and are threatened by multiple human activities on land (e.g. farming) and in the sea (e.g. overfishing). Most conservation efforts occur at local scales and, when effective, can increase the resilience of coral reefs to global threats such as climate change (e.g. warming water and ocean acidification). Limited resources for conservation require that we efficiently prioritize where and how to best sustain coral reef ecosystems

Increasing frailty is associated with higher prevalence and reduced recognition of delirium in older hospitalised inpatients: results of a multi-centre study

Purpose: Delirium is a neuropsychiatric disorder delineated by an acute change in cognition, attention, and consciousness. It is common, particularly in older adults, but poorly recognised. Frailty is the accumulation of deficits conferring an increased risk of adverse outcomes. We set out to determine how severity of frailty, as measured using the CFS, affected delirium rates, and recognition in hospitalised older people in the United Kingdom. Methods: Adults over 65 years were included in an observational multi-centre audit across UK hospitals, two prospective rounds, and one retrospective note review. Clinical Frailty Scale (CFS), delirium status, and 30-day outcomes were recorded. Results: The overall prevalence of delirium was 16.3% (483). Patients with delirium were more frail than patients without delirium (median CFS 6 vs 4). The risk of delirium was greater with increasing frailty [OR 2.9 (1.8–4.6) in CFS 4 vs 1–3; OR 12.4 (6.2–24.5) in CFS 8 vs 1–3]. Higher CFS was associated with reduced recognition of delirium (OR of 0.7 (0.3–1.9) in CFS 4 compared to 0.2 (0.1–0.7) in CFS 8). These risks were both independent of age and dementia. Conclusion: We have demonstrated an incremental increase in risk of delirium with increasing frailty. This has important clinical implications, suggesting that frailty may provide a more nuanced measure of vulnerability to delirium and poor outcomes. However, the most frail patients are least likely to have their delirium diagnosed and there is a significant lack of research into the underlying pathophysiology of both of these common geriatric syndromes

Physical and chemical processing methods for producing nanocrystal films with properties by design

As quantum dot (QD) synthesis techniques and device architectures advance, it has become increasingly apparent that new ways of connecting QDs with each other and the external environment are required in order to realize the considerable potential of QDs for optoelectronic applications. Throughout my PhD studies at Cornell, I have worked to establish the scientific and engineering foundation for processing techniques to produce designer materials from QD building blocks. Specifically, I have investigated two general processing methods, thermal annealing and solution based chemical treatments to remove or replace the insulating native ligands and produce electronically coupled thin films. In a series of studies on thermal annealing of QD films across 10 orders of magnitude in time, I show how nonequilibrium laser annealing over ns and μs can be used to precisely control the structure of QD thin films to increase electronic coupling while maintaining quantum confinement, how in situ studies of QDs arranged in a periodic nanoreactor can shed light on QD fusion at the second to minute time scale, and how spatial temperature gradients during nonequilibrium laser annealing can be exploited to reveal that QD sintering is a thermally activated process with a constant activation energy over two orders of magnitude of QD growth rate. My work on chemical processing of QD films focuses on low temperature solution processing methods. I demonstrate how simultaneous cation and ligand exchange at the surface of QDs can electronically couple and passivate QD films in a single step, leading to a 4 fold increase in Förster resonant energy transfer rate and order of magnitude reduction in trap density. Through controlled removal of ligands and post assembly QD growth, I show how building epitaxial bonds among QDs in a long range ordered assembly can lead to a ~3 order of magnitude increase in the mobility of carriers in QD films. This work is an illustration of how detailed understanding of the processing-structure-property relationships in QD assemblies over multiple length scales can produce functional thin films with properties by design. Further advances that build on this work and others will take full advantage of the unprecedented flexibility provided by the size tunable properties of QDs to expand the periodic table into another dimension and drive materials innovation

Estimating the potential for coral adaptation to global warming across the Indo-West Pacific

The potential of reef-building corals to adapt to increasing sea-surface temperatures is often debated but has rarely been comprehensively modeled on a region-wide scale. We used individual-based simulations to model adaptation to warming in a coral metapopulation comprising 680 reefs and representing the whole of the Central Indo-West Pacific. Encouragingly, some reefs-most notably Vietnam, Japan, Taiwan, New Caledonia and the southern half of the Great Barrier Reef-exhibited high capacity for adaptation and, in our model, maintained coral cover even under a rapid "business-as-usual" warming scenario throughout the modeled period (200 years). Higher resilience of these reefs was observed under all tested parameter settings except the models prohibiting selection and/or migration during warming. At the same time, the majority of reefs in the region tended to collapse within the first 100 years of warming. The adaptive potential (odds of maintaining high coral cover) of a given reef could be predicted based on two metrics: the reef's present-day temperature, and the proportion of recruits immigrating from warmer locations. The latter metric explains the most variation in adaptive potential, and significantly correlates with actual coral cover changes observed throughout the region between the 1970s and the early 2000s. These findings will help prioritize coral conservation efforts and plan assisted gene flow interventions to boost the adaptive potential of specific coral populations

Marine Geospatial Ecology Tools: An integrated framework for ecological geoprocessing with ArcGIS, Python, R, MATLAB, and C++

With the arrival of GPS, satellite remote sensing, and personal computers, the last two decades have witnessed rapid advances in the field of spatially-explicit marine ecological modeling. But with this innovation has come complexity. To keep up, ecologists must master multiple specialized software packages, such as ArcGIS for display and manipulation of geospatial data, R for statistical analysis, and MATLAB for matrix processing. This requires a costly investment of time and energy learning computer programming, a high hurdle for many ecologists. To provide easier access to advanced analytic methods, we developed Marine Geospatial Ecology Tools (MGET), an extensible collection of powerful, easy-to-use, open-source geoprocessing tools that ecologists can invoke from ArcGIS without resorting to computer programming. Internally, MGET integrates Python, R, MATLAB, and C++, bringing the power of these specialized platforms to tool developers without requiring developers to orchestrate the interoperability between them.In this paper, we describe MGET's software architecture and the tools in the collection. Next, we present an example application: a habitat model for Atlantic spotted dolphin (Stenella frontalis) that predicts dolphin presence using a statistical model fitted with oceanographic predictor variables. We conclude by discussing the lessons we learned engineering a highly integrated tool framework