717 research outputs found
Hydroxyapatite-based cements induce different apatite formation in radicular dentin
Objectives. To investigate crystallinity and ultrastructure of the formed hydroxyapatite at radicular cervical and apical dentin after being treated with three different canal sealers.
Methods. Cervical and apical root dentin surfaces were treated with two experimental hydroxyapatite-based sealers, containing sodium hydroxide (calcypatite) or zinc oxide (oxipatite) and an epoxy resin-based canal sealer (AH Plus); gutta-percha without sealer was included as control. Dentin surfaces were studied by X-ray diffraction and transmission electron microscopy through selected area diffraction and bright-field imaging after 24 h and 12 m of storage.
Results. Root cervical dentin treated with calcypatite and oxipatite produced poor crystallinity of new minerals, wide amorphous phase and non-stoichiometry. Reflections at the 002 plane and the corresponding diffraction rings attained lower values in the Scherrer equation and the Scherrer-Wilson equation in samples treated with both HAp-based sealers than in specimens without sealer or with AH Plus. At root cervical dentin treated with calcypatite, shorter and wider crystallite size formations and lower crystals grain size were found, if compared to those encountered at oxipatite treated dentin. Oxipatite attained improved crystallographic atomic order and less structural variation in both distances and angles. Apical dentin treated with oxipatite attained preferred grain orientation with polycrystalline lattices.
Significance. The immature crystallites formed in dentin treated with calcypatite and oxipatite will account for high hydroxyapatite solubility and remineralizing activity. New polycrystalline formations encountered in apical dentin treated with oxipatite may also produce high mechanical performance.This work was supported by the Ministry of Economy and Competitiveness (MINECO) and European Regional Development Fund (FEDER) Project MAT2017-85999-P
Stability conditions and Stokes factors
Let A be the category of modules over a complex, finite-dimensional algebra.
We show that the space of stability conditions on A parametrises an
isomonodromic family of irregular connections on P^1 with values in the Hall
algebra of A. The residues of these connections are given by the holomorphic
generating function for counting invariants in A constructed by D. Joyce.Comment: Very minor changes. Final version. To appear in Inventione
Finite strain Landau theory of high pressure phase transformations
The properties of materials near structural phase transitions are often
successfully described in the framework of Landau theory. While the focus is
usually on phase transitions, which are induced by temperature changes
approaching a critical temperature T-c, here we will discuss structural phase
transformations driven by high hydrostatic pressure, as they are of major
importance for understanding processes in the interior of the earth. Since at
very high pressures the deformations of a material are generally very large,
one needs to apply a fully nonlinear description taking physical as well as
geometrical nonlinearities (finite strains) into account. In particular it is
necessary to retune conventional Landau theory to describe such phase
transitions. In Troster et al (2002 Phys. Rev. Lett. 88 55503) we constructed a
Landau-type free energy based on an order parameter part, an order
parameter-(finite) strain coupling and a nonlinear elastic term. This model
provides an excellent and efficient framework for the systematic study of phase
transformations for a wide range of materials up to ultrahigh pressures
Buckling Instabilities of a Confined Colloid Crystal Layer
A model predicting the structure of repulsive, spherically symmetric,
monodisperse particles confined between two walls is presented. We study the
buckling transition of a single flat layer as the double layer state develops.
Experimental realizations of this model are suspensions of stabilized colloidal
particles squeezed between glass plates. By expanding the thermodynamic
potential about a flat state of confined colloidal particles, we derive
a free energy as a functional of in-plane and out-of-plane displacements. The
wavevectors of these first buckling instabilities correspond to three different
ordered structures. Landau theory predicts that the symmetry of these phases
allows for second order phase transitions. This possibility exists even in the
presence of gravity or plate asymmetry. These transitions lead to critical
behavior and phases with the symmetry of the three-state and four-state Potts
models, the X-Y model with 6-fold anisotropy, and the Heisenberg model with
cubic interactions. Experimental detection of these structures is discussed.Comment: 24 pages, 8 figures on request. EF508
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Optical properties of aerosol mixtures derived from sun-sky radiometry during SAMUM-2
The SAMUM-2 experiment took place in the Cape Verde is lands in JanuaryâFebruary 2008. The colocated ground-based and airborne instruments allow the study of desert dust optical and microphysical properties in a closure experiment. The Meteorological Institute of the University of Munich deployed one sun-sky photometer and two tropospheric lidar systems. A travelling AERONET-Cimel sun-sky radiometer was also deployed. During the measurement period the aerosol scenario over Cape Verde mostly consisted of a dust layer below 2 km and a smoke-dust layer above 2â4 km a.s.l. The Saharan dust arrived at the site from the NE, whereas the smoke originated in the African equatorial region. This paper describes the main results of the Sun photometer observations, supported by lidar information. An analysis of the variations in the aerosol optical depth (AOD) in the range 340â1550 nm, the Ă
ngström exponent, volume size distributions and single scattering albedo is presented. The aerosol mixtures are analysed by means of the fine mode fraction of the AOD provided by the sun-sky inversion data and the Spectral Deconvolution Algorithm. The mean AOD (500 nm) was 0.31, with associated low Ă„ngström exponent of 0.46. Several types of events were detected within the data set, with prevalence of dust or mixtures as characterized by the Ă
ngstršom exponents of extinction and absorption and the fine mode fraction. Aerosol properties derived from sunphotometry were compared to in situ measurements of size distribution, effective radius and single scattering albedo
On critical behavior of phase transitions in certain antiferromagnets with complicated ordering
Within the four-loop \ve expansion, we study the critical behavior of
certain antiferromagnets with complicated ordering. We show that an anisotropic
stable fixed point governs the phase transitions with new critical exponents.
This is supported by the estimate of critical dimensionality
obtained from six loops via the exact relation established
for the real and complex hypercubic models.Comment: Published versio
EGIAâevolutionary optimisation of gene regulatory networks, an integrative approach
Quantitative modelling of gene regulatory networks (GRNs)
is still limited by data issues such as noise and the restricted length of available time series, creating an under-determination problem. However, large amounts of other types of biological data and knowledge are available, such as knockout experiments, annotations and so on, and it
has been postulated that integration of these can improve model quality. However, integration has not been fully explored, to date. Here, we present a novel integrative framework for different types of data that aims
to enhance model inference. This is based on evolutionary computation and uses different types of knowledge to introduce a novel customised initialisation and mutation operator and complex evaluation criteria, used
to distinguish between candidate models. Specifically, the algorithm uses information from (i) knockout experiments, (ii) annotations of transcription factors, (iii) binding site motifs (expressed as position weight matrices) and (iv) DNA sequence of gene promoters, to drive the algorithm
towards more plausible network structures. Further, the evaluation basis is also extended to include structure information included in these additional data. This framework is applied to both synthetic and real
gene expression data. Models obtained by data integration display both quantitative and qualitative improvement
Tin telluride: a weakly co-elastic metal
We report resonant ultrasound spectroscopy (RUS),
dilatometry/magnetostriction, magnetotransport, magnetization, specific heat,
and Sn M\"ossbauer spectroscopy measurements on SnTe and
SnCrTe. Hall measurements at K indicate that our
Bridgman-grown single crystals have a -type carrier concentration of cm and that our Cr-doped crystals have an -type
concentration of cm. Although our SnTe crystals are
diamagnetic over the temperature range , the Cr-doped crystals are room temperature ferromagnets with a Curie
temperature of 294 K. For each sample type, three-terminal capacitive
dilatometry measurements detect a subtle 0.5 micron distortion at K. Whereas our RUS measurements on SnTe show elastic hardening near the
structural transition, pointing to co-elastic behavior, similar measurements on
SnCrTe show a pronounced softening, pointing to
ferroelastic behavior. Effective Debye temperature, , values of SnTe
obtained from Sn M\"ossbauer studies show a hardening of phonons in the
range 60--115K ( = 162K) as compared with the 100--300K range
( = 150K). In addition, a precursor softening extending over
approximately 100 K anticipates this collapse at the critical temperature, and
quantitative analysis over three decades of its reduced modulus finds with , a value
indicating a three-dimensional softening of phonon branches at a temperature
K, considerably below . We suggest that the differences in
these two types of elastic behaviors lie in the absence of elastic domain wall
motion in the one case and their nucleation in the other
Nobeyama Cygnus-X Survey: Physical Properties of CO clumps in DR-6(W), DR-9 and DR-13S regions
Cygnus-X is considered a region of interest for high-energy astrophysics,
since the Cygnus OB2 association has been confirmed as a PeVatron in the Cygnus
cocoon. In this research note, we present new high-resolution (16'')
CO(J=10) and CO (J=10) observations
obtained with the Nobeyama 45-m radiotelescope, to complement the Nobeyama
Cygnus-X Survey. We discovered 19 new CO clumps associated with the
star-forming regions DR-6W, DR-9, and DR13S. We present the physical parameters
of these clumps, which are consistent with the neighboring covered regions. We
confirm the clumpy nature of these regions and of a filament located between
DR6 and DR6W. These results strongly suggest that star formation occurs in
these regions with clumps of sizes 10 pc, masses 10
M, and H densities of 10 cm.Comment: 8 pages, 3 Figures, 1 Table. https://pos.sissa.it/444/631/pd
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