Bright fireballs associated with the potentially hazardous asteroid 2007LQ19

We analyse here two very bright fireballs produced by the ablation in the atmosphere of two large meteoroids in 2009 and 2010. These slow-moving and deep-penetrating events were observed over Spain in the framework of our Spanish Fireball Network continuous meteor monitoring campaign. The analysis of the emission spectrum imaged for one of these fireballs has provided the first clues about the chemical nature of the progenitor meteoroids. The orbital parameters of these particles suggest a likely association with the recently identified July ρ-Herculid (JRH) meteoroid stream. In addition, considerations about the likely parent body of this stream are also made on the basis of orbital dissimilarity criteria. This orbital analysis reveals that both meteoroids and PHA 2007LQ19 exhibit a similar evolution during a time period of almost 8000 years, which suggests that either this near Earth object (NEO) is the potential parent of these particles or that this NEO and both meteoroids had a common progenitor in the past.España, Ministerio de Ciencia e Innovación YA2011-26522Junta de Andalucía P09-FQM-455

A counterfactual impact evaluation of a bilingual program on students’ grade point average at a spanish university

This observational study intends to estimate the causal effects of an English as a Medium of Instruction (EMI) program (as predictor) on students Grade Point Average (GPA) (as outcome) at a particular University in Spain by using a Counterfactual Impact Evaluation (CIE). The need to address the crucial question of causal inferences in EMI programs to produce credible evidences of successful interventions contrasts, however, with the absence of experimental or quasi-experimental research and evaluation designs in the field. CIE approach is emerging as a methodologically viable solution to bridge that gap. The program evaluated here consisted in delivering an EMI program in a Primary Education Teacher Training Degree group. After achieving balance on the observed covariates and recreating a situation that would have been expected in a randomized experiment, three matching approaches such as genetic matching, nearest neighbor matching and Coarsened Exact Matching were used to analyze observational data from a total of 1288 undergraduate students, including both treatment and control group. Results show unfavorable effects of the bilingual group treatment condition. Potential interpretations and recommendations are provided in order to strengthen future causal evidences of bilingual education programs’ effectiveness in Higher Education.This work was supported by the Junta de Andalucía-funded Proyecto de Excelencia: “Análisis y Garantía de Calidad de la Educación Superior Plurilingüe en la Educación Superior de Andalucía [Junta de Andalusia-funded Project of Excelence: Analysis and Warrantee of the Quality of Plurilingual Higher Education in Andalucia] (AGCEPESA; Grant Agreement No. P12-SEJ − 1588)

Mn-Containing N-Doped Monolithic Carbon Aerogels with Enhanced Macroporosity as Electrodes for Capacitive Deionization

We propose the use of siliceous diatomite as an antishrinkage additive for the synthesis of monolithic carbon aerogel electrodes with enhanced electrochemical response for capacitive deionization of NaCl solutions. Hybrid N- and Mn-doped carbon aerogels with improved electrical conductivity and wettability in the aqueous electrolyte are prepared by introducing modifications in the synthesis (carbon black and/or diatomite loading before the polymerization sol–gel polycondensation of the monomers, followed by manganese infiltration). The textural and morphological characterizations of the materials reveal that the presence of the additives does not impede the cross-linking of the monomers to form branched clusters and colloidal aggregates leading to a highly porous structure. Furthermore, the aerogel materials display an open macroporous network inherited by the diatomite, even after its lixiviation. As a result, the monolithic carbon aerogel electrodes present good electrochemical performance in terms of low polarization resistance, high capacitance, and fast electroadsorption.The authors are indebted to the MINECO (Contract IPT-2011-1450-310000 (ADECAR) and FEDER cofunding, and CTM2014-56770-R) for the financial support. We also thank the fruitful collaboration of Isolux Ingeniería, S.A., Fundación Imdea Energía and Proingesa.University of Cordoba thanks to SCAI and IUIQFN for technical support and Junta de Andalucía (FQM-288) for financial support.Peer reviewe

Electrochemical Interaction of Few-Layer Molybdenum Disulfide Composites vs Sodium: New Insights on the Reaction Mechanism

The direct observation of real time electrochemical processes is of great importance for fundamental research on battery materials. Here, we use electron paramagnetic resonance (EPR) spectroscopy to monitor the electrochemical reaction of sodium ions with few-layer MoS2 and its composite with carbon nanotubes (CNTs), thereby uncovering new details of the reaction mechanism. We propose that the sodiation reaction takes place initially in structural defects at the MoS2 surface that have been created during the synthetic process (ultrasonic exfoliation), leading to a decrease in the density of Mo5+ at low symmetry sites that can be related to the electrochemical irreversibility of the process. In the case of the few-layer MoS2/CNTs composite, we found metallic-type conduction behavior for the electrons associated with the Mo paramagnetic centers and improved electrochemical reversibility. The reversible nature of the EPR spectra implies that adsorption/desorption of Na+ ions occurs on the Mo5+ defects, or that they are neutralized during sodiation and subsequently created upon Na+ extraction. These effects help us to understand the higher capacities obtained in the exfoliated samples, as the sum of electrosorption of ions and faradaic effects, and support the suggestion of a different reaction mechanism in the few-layer chalcogenide, which is not exclusively an insertion process

Review and new perspectives on non-layered manganese compounds as electrode material for Sodium-Ion batteries

After more than 30 years of delay compared to lithium-ion batteries, sodium analogs are now emerging in the market. This is a result of the concerns regarding sustainability and production costs of the former, as well as issues related to safety and toxicity. Electrode materials for the new sodium-ion batteries may contain available and sustainable elements such as sodium itself, as well as iron or manganese, while eliminating the common cobalt cathode compounds and copper anode current collectors for lithium-ion batteries. The multiple oxidation states, abundance, and availability of manganese favor its use, as it was shown early on for primary batteries. Regarding structural considerations, an extraordinarily successful group of cathode materials are layered oxides of sodium, and transition metals, with manganese being the major component. However, other technologies point towards Prussian blue analogs, NASICON-related phosphates, and fluorophosphates. The role of manganese in these structural families and other oxide or halide compounds has until now not been fully explored. In this direction, the present review paper deals with the different Mn-containing solids with a non-layered structure already evaluated. The study aims to systematize the current knowledge on this topic and highlight new possibilities for further study, such as the concept of entatic state applied to electrodes

Synthesis of Porous and Mechanically Compliant Carbon Aerogels Using Conductive and Structural Additives

We report the synthesis of conductive and mechanically compliant monolithic carbon aerogels prepared by sol-gel polycondensation of melamine-resorcinol-formaldehyde (MRF) mixtures by incorporating diatomite and carbon black additives. The resulting aerogels composites displayed a well-developed porous structure, confirming that the polymerization of the precursors is not impeded in the presence of either additive. The aerogels retained the porous structure after etching off the siliceous additive, indicating adequate cross-linking of the MRF reactants. However, the presence of diatomite caused a significant fall in the pore volumes, accompanied by coarsening of the average pore size (predominance of large mesopores and macropores). The diatomite also prevented structural shrinkage and deformation of the as-prepared monoliths upon densification by carbonization, even after removal of the siliceous framework. The rigid pristine aerogels became more flexible upon incorporation of the diatomite, favoring implementation of binderless monolithic aerogel electrodes.This work was partially funded by the Spanish MINECO (CTM2014/56770-R, IPT-2011-1450-310000 ADECAR) and Junta de Andalucía (FQM288). The help of D.L. García in the preparation of the specimens is greatly appreciated. C.O.A. thanks the financial support of the European Research Council through a Consolidator Grant (ERC-CoG-648161-PHOROSOL).Peer reviewe

The 2011 October Draconids outburst. I. Orbital elements, meteoroid fluxes and 21P/Giacobini-Zinner delivered mass to Earth

On October 8th, 2011 the Earth crossed the dust trails left by comet 21P/Giacobini-Zinner during its XIX and XX century perihelion approaches with the comet being close to perihelion. The geometric circumstances of that encounter were thus favorable to produce a meteor storm, but the trails were much older than in the 1933 and 1946 historical encounters. As a consequence the 2011 October Draconid display exhibited several activity peaks with Zenithal Hourly Rates of about 400 meteors per hour. In fact, if the display had been not forecasted, it could have passed almost unnoticed as was strongly attenuated for visual observers due to the Moon. This suggests that most meteor storms of a similar nature could have passed historically unnoticed under unfavorable weather and Moon observing conditions. The possibility of obtaining information on the physical properties of cometary meteoroids penetrating the atmosphere under low-geocentric velocity encounter circumstances motivated us to set up a special observing campaign. Added to the Spanish Fireball Network wide-field all-sky and CCD video monitoring, other high-sensitivity 1/2" black and white CCD video cameras were attached to modified medium-field lenses for obtaining high resolution orbital information. The trajectory, radiant, and orbital data of 16 October Draconid meteors observed at multiple stations are presented. The results show that the meteors appeared from a geocentric radiant located at R.A.=263.0+-0.4 deg. and Dec.=+55.3+-0.3 deg. that is in close agreement with the radiant predicted for the 1873-1894 and the 1900 dust trails. The estimated mass of material from 21P/Giacobini-Zinner delivered to Earth during the six-hours outburst was around 950+-150 kg.Comment: Manuscript in press in Monthly Notices of the Royal Astronomical Society, submitted to MNRAS on November 16th, 2012 Accepted for publication in MNRAS on April 28th, 2013 Manuscript Pages: 21 Tables: 8 Figures: 4 Manuscript associated: "The 2011 October Draconids outburst. II. Meteoroid chemical abundances from fireball spectroscopy" by J.M. Madiedo is also in press in the same journa

The 2011 October Draconids outburst-II. Meteoroid chemical abundances from fireball spectroscopy

On 2011 October 8, the Earth crossed dust trails ejected from comet 21P/Giacobini-Zinner in the late 19th and early 20th Century. This gave rise to an outburst in the activity of the October Draconid meteor shower, and an international team was organized to analyse this event. The SPanish Meteor Network (SPMN) joined this initiative and recorded the October Draconids by means of low-light level CCD cameras. In addition, spectroscopic observations were carried out. Tens of multistation meteor trails were recorded, including an extraordinarily bright October Draconid fireball (absolute magnitude-10.5) that was simultaneously imaged from three SPMN meteor observing stations located in Andalusia. Its spectrum was obtained, showing a clear evolution in the relative intensity of emission lines as the fireball penetrated deeper into the atmosphere. Here, we focus on the analysis of this remarkable spectrum, but also discuss the atmospheric trajectory, atmospheric penetration and orbital data computed for this bolide which was probably released during 21P/Giacobini-Zinner return to perihelion in 1907. The spectrum is discussed together with the tensile strength for the October Draconid meteoroids. The chemical profile evolution of the main rocky elements for this extremely bright bolide is compared with the elemental abundances obtained for five October Draconid fireballs also recorded during our spectroscopic campaign but observed only at a single station. Significant chemical heterogeneity between the small meteoroids is found as we should expect for cometary aggregates being formed by diverse dust components.Ministerio de Ciencia e Innovación AYA2009-13227, AYA2009-14000-C03- 01, AYA2011-26522Junta de Andalucía P09-FQM4555CSIC 201050I04

The 2011 October Draconids outburst-II. Meteoroid chemical abundances from fireball spectroscopy

On 2011 October 8, the Earth crossed dust trails ejected from comet 21P/Giacobini-Zinner in the late 19th and early 20th Century. This gave rise to an outburst in the activity of the October Draconid meteor shower, and an international team was organized to analyse this event. The SPanish Meteor Network (SPMN) joined this initiative and recorded the October Draconids by means of low-light level CCD cameras. In addition, spectroscopic observations were carried out. Tens of multistation meteor trails were recorded, including an extraordinarily bright October Draconid fireball (absolute magnitude-10.5) that was simultaneously imaged from three SPMN meteor observing stations located in Andalusia. Its spectrum was obtained, showing a clear evolution in the relative intensity of emission lines as the fireball penetrated deeper into the atmosphere. Here, we focus on the analysis of this remarkable spectrum, but also discuss the atmospheric trajectory, atmospheric penetration and orbital data computed for this bolide which was probably released during 21P/Giacobini-Zinner return to perihelion in 1907. The spectrum is discussed together with the tensile strength for the October Draconid meteoroids. The chemical profile evolution of the main rocky elements for this extremely bright bolide is compared with the elemental abundances obtained for five October Draconid fireballs also recorded during our spectroscopic campaign but observed only at a single station. Significant chemical heterogeneity between the small meteoroids is found as we should expect for cometary aggregates being formed by diverse dust components.Ministerio de Ciencia e Innovación AYA2009-13227, AYA2009-14000-C03- 01, AYA2011-26522Junta de Andalucía P09-FQM4555CSIC 201050I04