194 research outputs found
The Relationship between the Optical Depth of the 9.7 micron Silicate Absorption Feature and Infrared Differential Extinction in Dense Clouds
We have examined the relationship between the optical depth of the 9.7 micron
silicate absorption feature (tau_9.7) and the near-infrared color excess,
E(J-Ks) in the Serpens, Taurus, IC 5146, Chameleon I, Barnard 59, and Barnard
68 dense clouds/cores. Our data set, based largely on Spitzer IRS spectra,
spans E(J-Ks)=0.3 to 10 mag (corresponding to visual extinction between about 2
and 60 mag.). All lines of sight show the 9.7 micron silicate feature. Unlike
in the diffuse ISM where a tight linear correlation between the 9.7 micron
silicate feature optical depth and the extinction (Av) is observed, we find
that the silicate feature in dense clouds does not show a monotonic increase
with extinction. Thus, in dense clouds, tau_9.7 is not a good measure of total
dust column density. With few exceptions, the measured tau_9.7 values fall well
below the diffuse ISM correlation line for E(J-Ks) > 2 mag (Av >12 mag). Grain
growth via coagulation is a likely cause of this effect.Comment: 11 pages including 2 figures, 1 table. Accepted for publication in
ApJ Letters, 23 July 200
Erratum: ''High-resolution IR Absorption Spectroscopy of Polycyclic Aromatic Hydrocarbons: The Realm of Anharmonicity'' (2015, ApJ, 814, 23)
Laboratory astrophysics and astrochemistr
High-resolution IR absorption spectroscopy of polycyclic aromatic hydrocarbons: The realm of anharmonicity
We report on an experimental and theoretical investigation of the importance of anharmonicity in the 3-μm CH stretching region of polycyclic aromatic hydrocarbon (PAH) molecules. We present mass-resolved, high-resolution spectra of the gas-phase cold (∼4 K) linear PAH molecules naphthalene, anthracene, and tetracene. The measured IR spectra show a surprisingly high number of strong vibrational bands. For naphthalene, the observed bands are well separated and limited by the rotational contour, revealing the band symmetries. Comparisons are made to the harmonic and anharmonic approaches of the widely used Gaussian software. We also present calculated spectra of these acenes using the computational program SPECTRO, providing anharmonic predictions with a Fermi-resonance treatment that utilizes intensity redistribution. We demonstrate that the anharmonicity of the investigated acenes is strong, dominated by Fermi resonances between the fundamental and double combination modes, with triple combination bands as possible candidates to resolve remaining discrepancies. The anharmonic spectra as calculated with SPECTRO lead to predictions of the main bands that fall within 0.5% of the experimental frequencies. The implications for the aromatic infrared bands, specifically the 3-μm band, are discussed.Laboratory astrophysics and astrochemistr
Nitrogen hydrides in the cold envelope of IRAS16293-2422
Nitrogen is the fifth most abundant element in the Universe, yet the
gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen
hydrides are key molecules of nitrogen chemistry. Their abundance ratios place
strong constraints on the production pathways and reaction rates of
nitrogen-bearing molecules. We observed the class 0 protostar IRAS16293-2422
with the heterodyne instrument HIFI, covering most of the frequency range from
0.48 to 1.78~THz at high spectral resolution. The hyperfine structure of the
amidogen radical o-NH2 is resolved and seen in absorption against the continuum
of the protostar. Several transitions of ammonia from 1.2 to 1.8~THz are also
seen in absorption. These lines trace the low-density envelope of the
protostar. Column densities and abundances are estimated for each hydride. We
find that NH:NH2:NH3=5:1:300. {Dark clouds chemical models predict steady-state
abundances of NH2 and NH3 in reasonable agreement with the present
observations, whilst that of NH is underpredicted by more than one order of
magnitude, even using updated kinetic rates. Additional modelling of the
nitrogen gas-phase chemistry in dark-cloud conditions is necessary before
having recourse to heterogen processes
RC J0311+0507: A Candidate for Superpowerful Radio Galaxies in the Early Universe at Redshift z=4.514
A strong emission line at 6703A has been detected in the optical spectrum for
the host galaxy (R=23.1) of the radio source RC J0311+0507 (4C+04.11). This
radio galaxy, with a spectral index of 1.31 in the frequency range 365-4850
MHz, is one of the ultrasteep spectrum objects from the deep survey of a sky
strip conducted with RATAN-600 in 1980-1981. We present arguments in favor of
the identification of this line with Ly\alpha at redshift z=4.514. In this
case, the object belongs to the group of extremely distant radio galaxies of
ultrahigh radio luminosity (P_{1400}=1.3 x 10^{29}W Hz^{-1}). Such power can be
provided only by a fairly massive black hole (~10^9M_\sun}) that formed in a
time less than the age of the Universe at the observed z(1.3 Gyr) or had a
primordial origin.Comment: 8 pages, 3 figure
The distribution of water in the high-mass star-forming region NGC 6334I
We present observations of twelve rotational transitions of H2O-16, H2O-18,
and H2O-17 toward the massive star-forming region NGC 6334 I, carried out with
Herschel/HIFI as part of the guaranteed time key program Chemical HErschel
Surveys of Star forming regions (CHESS). We analyze these observations to
obtain insights into physical processes in this region.
We identify three main gas components (hot core, cold foreground, and
outflow) in NGC 6334 I and derive the physical conditions in these components.
The hot core, identified by the emission in highly excited lines, shows a
high excitation temperature of 200 K, whereas water in the foreground component
is predominantly in the ortho- and para- ground states. The abundance of water
varies between 4 10^-5 (outflow) and 10^-8 (cold foreground gas). This
variation is most likely due to the freeze-out of water molecules onto dust
grains. The H2O-18/H2O-17 abundance ratio is 3.2, which is consistent with the
O-18/O-17 ratio determined from CO isotopologues. The ortho/para ratio in water
appears to be relatively low 1.6(1) in the cold, quiescent gas, but close to
the equilibrium value of three in the warmer outflow material (2.5(0.8)).Comment: 7 pages, 3 figures, accepted by A&
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