One-pot microwave-assisted green synthesis of amine-functionalized graphene quantum dots for high visible light photocatalytic application

Nowadays, graphene quantum dots (GQDs) have gained a huge interest in the field of visible-range photocatalysts because of their tunable band gap and stable photochemical properties. In this work, amine-functionalized GQDs (AGQDs) were successfully prepared by one-step microwave-assisted conversion of glucose, H2O2, and NH3 solution. The obtained quantum dots possess the high quality of graphene structure with the average size of 3.78 nm as well as exhibit a strong green fluorescence with a high quantum yield. Interestingly, the amine-functionalized dots perform outstanding visible-light absorption. To further investigate photocatalytic properties, a composite of AGQDs and TiO2 was then prepared by a simple mixing route. The hybrid material showed high catalytic activity of dye degradation under visible light irradiation, which indicates the key role of AGQDs in enhancing light absorption and induced electron–hole separation. The current study may open a new way for construction of effective visible light photocatalytic systems with a cost-effective, simple approach.Scopu

Metal enrichment of the neutral gas of blue compact dwarf galaxies: the compelling case of Pox 36

We present the analysis of the interstellar spectrum of Pox 36 with the Far Ultraviolet Spectroscopic Explorer (FUSE). Pox 36 was selected because of the relatively low foreground gas content that makes it possible to detect absorption-lines weak enough that unseen components should not be saturated. Interstellar lines of HI, NI, OI, SiII, PII, ArI, and FeII are detected. Column densities are derived directly from the observed line profiles except for HI, whose lines are contaminated by stellar absorption. We used the TLUSTY models to remove the stellar continuum and isolate the interstellar component. The best fit indicates that the dominant stellar population is B0. The fit of the interstellar HI line gives a column density of 10^{20.3\pm0.4} cm-2. Chemical abundances were then computed from the column densities using the dominant ionization stage in the neutral gas. Our abundances are compared to those measured from emission-line spectra in the optical. Our results suggest that the neutral gas of Pox 36 is metal-deficient by a factor ~7 as compared to the ionized gas, and they agree with a metallicity of ~1/35 Z$_\odot$. Conclusions: The abundance discontinuity between the neutral and ionized phases implies that most of the metals released by consecutive star-formation episodes mixes with the HI gas. The volume extent of the enrichment is so large that the metallicity of the neutral gas increases only slightly. The star-forming regions could be enriched only by a small fraction (~1%), but it would greatly enhance its metallicity. Our results are compared to those of other BCDs. We confirm the overall underabundance of metals in their neutral gas, with perhaps only the lowest metallicity BCDs showing no discontinuity.Comment: Accepted for publication in A&

NGC 7468: a galaxy with an inner polar disk

We present our spectroscopic observations of the galaxy NGC 7468 performed at the 6-m Special Astrophysical Observatory telescope using the UAGS long-slit spectrograph, the multipupil fiber spectrograph MPFS, and the scanning Fabry-Perot interferometer (IFP). We found no significant deviations from the circular rotation of the galactic disk in the velocity field in the regions of brightness excess along the major axis of the galaxy (the putative polar ring). Thus, these features are either tidal structures or weakly developed spiral arms. However, we detected a gaseous disk at the center of the galaxy whose rotation plane is almost perpendicular to the plane of the galactic disk. The central collision of NGC 7468 with a gas-rich dwarf galaxy and their subsequent merging seem to be responsible for the formation of this disk.Comment: 8 pages, 6 figures, accepted in Astronomy Letters, 2004, vol 30., N 9, p. 58

Relation Between the Thickness of Stellar Disks and the Relative Mass of Dark Halo in Galaxies

We consider a thickness of stellar disks of late-type galaxies by analyzing the R and K_s band photometric profiles for two independent samples of edge-on galaxies. The main goal is to verify a hypotesis that a thickness of old stellar disks is related to the relative masses of the spherical and disk components of galaxies. We confirm that the radial-to-vertical scale length ratio for galactic disks increases (the disks become thinner) with the increasing of total mass-to-light ratio of the galaxies, which characterize the contribution of dark halo to the total mass, and with the decreasing of central deprojected disk brightness (surface density). Our results are in good agreement with numerical models of collisionless disks evolved from subcritical velocity dispersion state to a marginally stable equilibrium state. This suggests that in most galaxies the vertical stellar velocity dispersion, which determine the equilibrium disk thickness, is close to the minimum value, that ensures disk stability. The thinnest edge-on disks appear to be low brightness galaxies (after deprojection) in which a dark halo mass far exceeds a mass of the stellar disk.Comment: 13 pages. To be Published in Astronomy Letters, v.28(2002

Gut Microbiome of Patients With Breast Cancer in Vietnam

PURPOSE: Gut microbiota play an important role in human health, including cancer. Cancer and its treatment, in turn, may alter the gut microbiome. To understand this complex relationship, we profiled the gut microbiome of 356 Vietnamese patients with breast cancer. MATERIALS AND METHODS: Stool samples were collected before chemotherapy, with 162 pre- and 194 postsurgery. The gut microbiome was measured by shotgun metagenomic sequencing. Associations of gut microbial diversity, taxa abundance, and gut microbiome health index (GMHI) with sociodemographic, clinical factors, and tumor characteristics were evaluated. RESULTS: Postsurgery samples were associated with significantly lower α- and β-diversities ( CONCLUSION: Our study revealed that diagnosis delay, high fiber intake, and breast cancer surgery, which is always followed by antibiotic prophylaxis in Vietnam, led to a less diverse and unhealthy gut microbiome among patients with breast cancer

The Gas Content in Galactic Disks: Correlation with Kinematics

We consider the relationship between the total HI mass in late-type galaxies and the kinematic properties of their disks. The mass $M_HI$ for galaxies with a wide variety of properties, from dwarf dIrr galaxies with active star formation to giant low-brightness galaxies, is shown to correlate with the product $V_c R_0$ ($V_c$ is the rotational velocity, and $R_0$ is the radial photometric disks scale length), which characterizes the specific angular momentum of the disk. This relationship, along with the anticorrelation between the relative mass of HI in a galaxy and $V_c$, can be explained in terms of the previously made assumption that the gas density in the disks of most galaxies is maintained at a level close to the threshold (marginal) stability of a gaseous layer to local gravitational perturbations. In this case, the regulation mechanism of the star formation rate associated with the growth of local gravitational instability in the gaseous layer must play a crucial role in the evolution of the gas content in the galactic disk.Comment: revised version to appear in Astronomy Letters, 8 pages, 5 EPS figure