Oxidation of biogenic and water-soluble compounds in aqueous and organic aerosol droplets by ozone: a kinetic and product analysis approach using laser Raman tweezers

The results of an experimental study into the oxidative degradation of proxies for atmospheric aerosol are presented. We demonstrate that the laser Raman tweezers method can be used successfully to obtain uptake coeffcients for gaseous oxidants on individual aqueous and organic droplets, whilst the size and composition of the droplets is simultaneously followed. A laser tweezers system was used to trap individual droplets containing an unsaturated organic compound in either an aqueous or organic ( alkane) solvent. The droplet was exposed to gas- phase ozone and the reaction kinetics and products followed using Raman spectroscopy. The reactions of three different organic compounds with ozone were studied: fumarate anions, benzoate anions and alpha pinene. The fumarate and benzoate anions in aqueous solution were used to represent components of humic- like substances, HULIS; a alpha- pinene in an alkane solvent was studied as a proxy for biogenic aerosol. The kinetic analysis shows that for these systems the diffusive transport and mass accommodation of ozone is relatively fast, and that liquid- phase di. ffusion and reaction are the rate determining steps. Uptake coe. ffcients, g, were found to be ( 1.1 +/- 0.7) x 10(-5), ( 1.5 +/- 0.7) x 10 (-5) and ( 3.0 - 7.5) x 10 (-3) for the reactions of ozone with the fumarate, benzoate and a- pinene containing droplets, respectively. Liquid- phase bimolecular rate coe. cients for reactions of dissolved ozone molecules with fumarate, benzoate and a- pinene were also obtained: k(fumarate) = ( 2.7 +/- 2) x 10 (5), k(benzoate) = ( 3.5 +/- 3) x 10 (5) and k(alpha-pinene) = ( 1-3) x 10(7) dm(3) mol (-1) s (- 1). The droplet size was found to remain stable over the course of the oxidation process for the HULIS- proxies and for the oxidation of a- pinene in pentadecane. The study of the alpha- pinene/ ozone system is the first using organic seed particles to show that the hygroscopicity of the particle does not increase dramatically over the course of the oxidation. No products were detected by Raman spectroscopy for the reaction of benzoate ions with ozone. One product peak, consistent with aqueous carbonate anions, was observed when following the oxidation of fumarate ions by ozone. Product peaks observed in the reaction of ozone with alpha- pinene suggest the formation of new species containing carbonyl groups

Rosie: A mobile worksystem for decontamination and dismantlement operations

RedZone Robotics, Inc. and Carnegie Mellon University`s Field Robotics Center have undertaken a contract to develop a next-generation worksystem for decommissioning and dismantlement tasks in Department of Energy (DOE) facilities. Currently, the authors are closing the second phase of this three phase effort and have completed the design and fabrication of the worksystem: Rosie. Rosie includes a locomotor, heavy manipulator, control center, and control system for robot operation. The locomotor is an omni-directional platform with tether management and hydraulic power capabilities. The heavy manipulator is a high-payload, long-reach system intended to deploy tools into the work area. The heavy manipulator is capable of deploying systems such as the Dual-Arm Work Module--a five degree-of-freedom platform supporting two highly dexterous manipulators--or a single manipulator for performing simpler, less dexterous tasks. Rosie is telerobotic to the point of having servo-controlled motions which can be operated and coordinated through the control center

Rosie: remote work system for decontamination and dismantlement

The Rosie worksystem includes a locomotor, heavy manipulator,operator console, and control system for remote operations. The locomotor is a highly mobile platform with tether management and hydraulic power onboard. The heavy manipulator is a high-payload, long-reach boom used to deploy a wide variety of tools and/or sensors into the work area. Rosie`s advanced control system, broad work capabibilites, and hardening/reliability for hazardous duty make it a new and unique capability that facilitates completion of significant cleanup projects throughout DOE and the private sector. Endurance testing of Rosie during last year has proven its capabilities and appropriateness for D&D applications. Design enhancements are being implemented to improve and add features necessary for deployment at an upcoming DOE facility decommissioning. A second Rosie unit is being fabricated fro use in the decommissioning of ANL`s CP-5 reactor facility starting late 1996. This paper overviews the Rosie system, testing results, design enhancements, and plans for use of this technology at CP-5

Houdini: a remote mobile platform for tank waste retrieval tasks

RedZone has developed Houdini{trademark}, a folding frame vehicle for work in waste storage tanks and other confined-access areas. Houdini is a tethered, hydraulically-powered platform that folds to fit through small openings. Once deployed, the vehicle unfolds to provide a substantial work platform for the deployment of a wide variety of tools. The Houdini system will perform wheel removal, waste retrieval, waste mobilization, waste size reduction, and other tank waste retrieval and decommissioning tasks. Within the DOE Complex, 332 underground storage tanks have been used to process and store radioactive and chemical mixed waste generated from weapon materials production. The ultimate goal of the program is to develop and commercialize the Houdini system for broad application throughout the DOE Complex

Information Presentation

The goal of the Information Presentation Directed Research Project (DRP) is to address design questions related to the presentation of information to the crew. The major areas of work, or subtasks, within this DRP are: 1) Displays, 2) Controls, 3) Electronic Procedures and Fault Management, and 4) Human Performance Modeling. This DRP is a collaborative effort between researchers at Johnson Space Center and Ames Research Center

Surface modification for enhanced silanation of zirconia ceramics

AbstractObjectiveThe overall goal of this research was to develop a practical method to chemically modify the surface of high strength dental ceramics (i.e. zirconia) to facilitate viable, robust adhesive bonding using commercially available silanes and resin cements.MethodsInvestigation focused on a novel approach to surface functionalize zirconia with a SixOy "seed" layer that would promote chemical bonding with traditional silanes. ProCAD and ZirCAD blocks were bonded to a dimensionally similar composite block using standard techniques designed for silica-containing materials (silane and resin cement). ZirCAD blocks were treated with SiCl4 by vapor deposition under two different conditions prior to bonding. Microtensile bars were prepared and subjected to tensile forces at a crosshead speed of 1mm/min scanning electron microscopy was used to analyze fracture surfaces and determine failure mode; either composite cohesive failure (partial or complete cohesive failure within composite) or adhesive failure (partial or complete adhesive failure).ResultsPeak stress values were analyzed using single-factor ANOVA (pxOy thick "seed" layer was similar in strength to the porcelain group (control). Analysis of failure modes indicated the above groups displayed higher percentages of in-composite failures. Other groups tested had lower strength values and displayed adhesive failure characteristics.ConclusionMechanical data support that utilizing a gas-phase chloro-silane pretreatment to deposit ultra-thin silica-like seed layers can improve adhesion to zirconia using traditional silanation and bonding techniques. This technology could have clinical impact on how high strength dental materials are used today

Computational advances in gravitational microlensing: a comparison of CPU, GPU, and parallel, large data codes

To assess how future progress in gravitational microlensing computation at high optical depth will rely on both hardware and software solutions, we compare a direct inverse ray-shooting code implemented on a graphics processing unit (GPU) with both a widely-used hierarchical tree code on a single-core CPU, and a recent implementation of a parallel tree code suitable for a CPU-based cluster supercomputer. We examine the accuracy of the tree codes through comparison with a direct code over a much wider range of parameter space than has been feasible before. We demonstrate that all three codes present comparable accuracy, and choice of approach depends on considerations relating to the scale and nature of the microlensing problem under investigation. On current hardware, there is little difference in the processing speed of the single-core CPU tree code and the GPU direct code, however the recent plateau in single-core CPU speeds means the existing tree code is no longer able to take advantage of Moore's law-like increases in processing speed. Instead, we anticipate a rapid increase in GPU capabilities in the next few years, which is advantageous to the direct code. We suggest that progress in other areas of astrophysical computation may benefit from a transition to GPUs through the use of "brute force" algorithms, rather than attempting to port the current best solution directly to a GPU language -- for certain classes of problems, the simple implementation on GPUs may already be no worse than an optimised single-core CPU version.Comment: 11 pages, 4 figures, accepted for publication in New Astronom

Single-Proton Removal Reaction Study of 16B

The low-lying level structure of the unbound system $^{16}$B has been investigated via single-proton removal from a 35 MeV/nucleon $^{17}$C beam. The coincident detection of the beam velocity $^{15}$B fragment and neutron allowed the relative energy of the in-flight decay of $^{16}$B to be reconstructed. The resulting spectrum exhibited a narrow peak some 85 keV above threshold. It is argued that this feature corresponds to a very narrow ($\Gamma \ll$100 keV) resonance, or an unresolved multiplet, with a dominant $\pi (p_{3/2})^{-1} \otimes \nu (d_{5/2}^3)_{J=3/2^+}$ + $\pi (p_{3/2})^{-1} \otimes \nu (d_{5/2}^2,s_{1/2})_{J=3/2^+}$ configuration which decays by d-wave neutron emission.Comment: 16 pages, 5 figures, 1 table, submitted to Phys. Lett.

B(E1) Strengths from Coulomb Excitation of 11Be

The $B$(E1;$1/2^+\to1/2^-$) strength for $^{11}$Be has been extracted from intermediate energy Coulomb excitation measurements, over a range of beam energies using a new reaction model, the extended continuum discretized coupled channels (XCDCC) method. In addition, a measurement of the excitation cross section for $^{11}$Be+$^{208}$Pb at 38.6 MeV/nucleon is reported. The $B$(E1) strength of 0.105(12) e$^2$fm$^2$ derived from this measurement is consistent with those made previously at 60 and 64 MeV/nucleon, i n contrast to an anomalously low result obtained at 43 MeV/nucleon. By coupling a multi-configuration description of the projectile structure with realistic reaction theory, the XCDCC model provides for the first time a fully quantum mechanical description of Coulomb excitation. The XCDCC calculations reveal that the excitation process involves significant contributions from nuclear, continuum, and higher-order effects. An analysis of the present and two earlier intermediate energy measurements yields a combined B(E1) strength of 0.105(7) e$^2$fm$^2$. This value is in good agreement with the value deduced independently from the lifetime of the $1/2^-$ state in $^{11}$Be, and has a comparable p recision.Comment: 5 pages, 2 figures, accepted for publication in Phys. Lett.

Superconducting fluctuations and the Nernst effect: A diagrammatic approach

We calculate the contribution of superconducting fluctuations above the critical temperature $T_c$ to the transverse thermoelectric response $\alpha_{xy}$, the quantity central to the analysis of the Nernst effect. The calculation is carried out within the microscopic picture of BCS, and to linear order in magnetic field. We find that as $T \to T_c$, the dominant contribution to $\alpha_{xy}$ arises from the Aslamazov-Larkin diagrams, and is equal to the result previously obtained from a stochastic time-dependent Ginzburg-Landau equation [Ussishkin, Sondhi, and Huse, arXiv:cond-mat/0204484]. We present an argument which establishes this correspondence for the heat current. Other microscopic contributions, which generalize the Maki-Thompson and density of states terms for the conductivity, are less divergent as $T \to T_c$.Comment: 11 pages, 5 figure