Text Organiztion and Structure in Science Textbooks

This study examined the text organization and structure of fourth and sixth grade science textbooks. This included prereading questions, advance organizers, margin notes, and type of text structure. In addition, chapter activities were classified as to the degree of problem solving skills developed by ranking the activities according to Bloom\u27s (1956) taxonomy of cognitive skills

A pendant proton shuttle on [Fe4N(CO)12]- alters product selectivity in formate vs. H2 production via the hydride [H-Fe4N(CO)12].

Proton relays are known to increase reaction rates for H2 evolution and lower overpotentials in electrocatalytic reactions. In this report we describe two electrocatalysts, [Fe4N(CO)11(PPh3)]- (1-) which has no proton relay, and hydroxyl-containing [Fe4N(CO)11(Ph2P(CH2)2OH)]- (2-). Solid state structures indicate that these phosphine-substituted clusters are direct analogs of [Fe4N(CO)12]- where one CO ligand has been replaced by a phosphine. We show that the proton relay changes the selectivity of reactions: CO2 is reduced selectively to formate by 1- in the absence of a relay, and protons are reduced to H2 under a CO2 atmosphere by 2-. These results implicate a hydride intermediate in the mechanism of the reactions and demonstrate the importance of controlling proton delivery to control product selectivity. Thermochemical measurements performed using infrared spectroelectrochemistry provided pKa and hydricity values for [HFe4N(CO)11(PPh3)]-, which are 23.7, and 45.5 kcal mol-1, respectively. The pKa of the hydroxyl group in 2- was determined to fall between 29 and 41, and this suggests that the proximity of the proton relay to the active catalytic site plays a significant role in the product selectivity observed, since the acidity alone does not account for the observed results. More generally, this work emphasizes the importance of substrate delivery kinetics in determining the selectivity of CO2 reduction reactions that proceed through metal-hydride intermediates

Absolute radiometric calibration of the EUNIS-06 170-205 A channel and calibration update for CDS/NIS

The Extreme-Ultraviolet Normal-Incidence Spectrograph sounding-rocket payload was flown on 2006 April 12 (EUNIS-06), carrying two independent imaging spectrographs covering wave bands of 300-370 A in first order and 170-205 A in second order, respectively. The absolute radiometric response of the EUNIS-06 long-wavelength (LW) channel was directly measured in the same facility used to calibrate CDS prior to the SOHO launch. Because the absolute calibration of the short-wavelength (SW) channel could not be obtained from the same lab configuration, we here present a technique to derive it using a combination of solar LW spectra and density- and temperature-insensitive line intensity ratios. The first step in this procedure is to use the coordinated, cospatial EUNIS and SOHO/CDS spectra to carry out an intensity calibration update for the CDS NIS-1 waveband, which shows that its efficiency has decreased by a factor about 1.7 compared to that of the previously implemented calibration. Then, theoretical insensitive line ratios obtained from CHIANTI allow us to determine absolute intensities of emission lines within the EUNIS SW bandpass from those of cospatial CDS/NIS-1 spectra after the EUNIS LW calibration correction. A total of 12 ratios derived from intensities of 5 CDS and 12 SW emission lines from Fe Fe X - Fe XIII yield an instrumental response curve for the EUNIS-06 SW channel that matches well to a relative calibration which relied on combining measurements of individual optical components. Taking into account all potential sources of error, we estimate that the EUNIS-06 SW absolute calibration is accurate to about 20%.Comment: 11 pages, 10 figures, 4 tables. 2010, ApJ Suppl. In pres

Underflight calibration of SOHO/CDS and Hinode/EIS with EUNIS-07

Flights of Goddard Space Flight Center's Extreme-Ultraviolet Normal-Incidence Spectrograph (EUNIS) sounding rocket in 2006 and 2007 provided updated radiometric calibrations for SOHO/CDS and Hinode/EIS. EUNIS carried two independent imaging spectrographs covering wavebands of 300-370 A in first order and 170-205 A in second order. After each flight, end-to-end radiometric calibrations of the rocket payload were carried out in the same facility used for pre-launch calibrations of CDS and EIS. During the 2007 flight, EUNIS, SOHO CDS and Hinode EIS observed the same solar locations, allowing the EUNIS calibrations to be directly applied to both CDS and EIS. The measured CDS NIS 1 line intensities calibrated with the standard (version 4) responsivities with the standard long-term corrections are found to be too low by a factor of 1.5 due to the decrease in responsivity. The EIS calibration update is performed in two ways. One is using the direct calibration transfer of the calibrated EUNIS-07 short wavelength (SW) channel. The other is using the insensitive line pairs, in which one member was observed by EUNIS-07 long wavelength (LW) channel and the other by EIS in either LW or SW waveband. Measurements from both methods are in good agreement, and confirm (within the measurement uncertainties) the EIS responsivity measured directly before the instrument's launch. The measurements also suggest that the EIS responsivity decreased by a factor of about 1.2 after the first year of operation. The shape of the EIS SW response curve obtained by EUNIS-07 is consistent with the one measured in laboratory prior to launch. The absolute value of the quiet-Sun He II 304 A intensity measured by EUNIS-07 is consistent with the radiance measured by CDS NIS in quiet regions near the disk center and the solar minimum irradiance obtained by CDS NIS and SDO/EVE recently.Comment: 16 pages, 14 figures, 5 tables, accepted by ApJ Supplement (Sep. 2011

The impact of greyscale inversion for nodule detection in an anthropomorphic chest phantom: a free-response observer study

Objective: The aim of this work was to assess the impact of greyscale inversion on nodule detection on poster- oanterior chest X-ray images. Previous work has attemp- ted this, with no consensus opinion formed. We assessed the value of “fast-flicking” between standard and inverted display modes for nodule detection. Methods: Six consultant radiologists (with 5–32 years’ reporting experience) completed an observer task under the free-response paradigm. An anthropomorphic chest phantom was loaded with 50 different configurations of simulated nodules (1–4 nodules per case) measuring 5, 8, 10 and 12mm in spherical diameter; each configuration represented a single case. In addition, 25 cases contained no nodules. Images were displayed in three modes: (i) standard, (ii) inverted and (iii) fast-flicking between standard and inverted display modes. Each observer completed the study in a different order of display (i, ii, iii) using a calibrated 5-megapixel monitor. Nodules were localized with mouse clicks and ratings assigned using a 1–10 discrete slider-bar confidence scale. Rjafroc (Pitts- burgh, PA) was used for data analysis; differences in nodule detection performance were considered significant at 0.05. Results: The observer-averaged weighted jackknife alter- native free-response receiver-operating characteristic figures of merit were 0.715 (standard), 0.684 (inverted) and 0.717 (fast-flicking). Random-reader fixed-case anal- ysis revealed no statistically significant difference be- tween any treatment pair [F(2,8) 5 1.22; p 5 0.345]. Conclusion: No statistically significant difference in nodule detection was found for the three display conditions. Advances in knowledge: We have investigated the impact of fast-flicking between standard and inverted display modes for the detection of nodules. We found no benefit

Draft genomes of three closely related low light-adapted <i>Prochlorococcus</i>

OBJECTIVES: The marine cyanobacterium Prochlorococcus is a critical part of warm ocean ecosystems and a model for studying microbial evolution and ecology. To expand the representation of this organism's vast wild diversity in sequence collections, we performed a set of isolation efforts targeting low light-adapted Prochlorococcus. Three genomes resulting from this larger body of work are described here.DATA DESCRIPTION: We present draft-quality Prochlorococcus genomes from enrichment cultures P1344, P1361, and P1363, sampled in the North Pacific. The genomes were built from Illumina paired reads assembled de novo. Supporting datasets of raw reads, assessments, and sequences from co-enriched heterotrophic marine bacteria are also provided. These three genomes represent members of the low light-adapted LLIV Prochlorococcus clade that are closely related, with 99.9% average nucleotide identity between pairs, yet vary in gene content. Expanding the powerful toolkit of Prochlorococcus genomes, these sequences provide an opportunity to study fine-scale variation and microevolutionary processes.</p

FLIC Fermions and Hadron Phenomenology

A pedagogical overview of the formulation of the Fat Link Irrelevant Clover (FLIC) fermion action and its associated phenomenology is described. The scaling analysis indicates FLIC fermions provide a new form of nonperturbative O(a) improvement where near-continuum results are obtained at finite lattice spacing. Spin-1/2 and spin-3/2, even and odd parity baryon resonances are investigated in quenched QCD, where the nature of the Roper resonance and Lambda(1405) are of particular interest. FLIC fermions allow efficient access to the light quark-mass regime, where evidence of chiral nonanalytic behavior in the Delta-baryon mass is observed.Comment: Invited plenary session talk at QNP 2002, International Conference on Quark-Nuclear Physics, 9-14 June 2002, Forschungszentrum Julich, German