A source of extended HCO+ emission in young stellar objects

Anomalous molecular line profile shapes are the strongest indicators of the presence of the infall of gas that is associated with star formation. Such profiles are seen for well-known tracers, such as HCO+, CS and H2CO. In certain cases, optically thick emission lines with appropriate excitation criteria may possess the asymmetric double-peaked profiles that are characteristic of infall. However, recent interpretations of the HCO+ infall profile observed towards the protostellar infall candidate B335 have revealed a significant discrepancy between the inferred overall column density of the molecule and that which is predicted by standard dark cloud chemical modelling. This paper presents a model for the source of the HCO+ emission excess. Observations have shown that, in low-mass star-forming regions, the collapse process is invariably accompanied by the presence of collimated outflows; we therefore propose the presence of an interface region around the outflow in which the chemistry is enriched by the action of jets. This hypothesis suggests that the line profiles of HCO+, as well as other molecular species, may require a more complex interpretation than can be provided by simple, chemically quiescent, spherically symmetric infall models. The enhancement of HCO+ depends primarily on the presence of a shock-generated radiation field in the interface. Plausible estimates of the radiation intensity imply molecular abundances that are consistent with those observed. Further, high-resolution observations of an infall-outflow source show HCO+ emission morphology that is consistent with that predicted by this model

Topological strings on noncommutative manifolds

We identify a deformation of the N=2 supersymmetric sigma model on a Calabi-Yau manifold X which has the same effect on B-branes as a noncommutative deformation of X. We show that for hyperkahler X such deformations allow one to interpolate continuously between the A-model and the B-model. For generic values of the noncommutativity and the B-field, properties of the topologically twisted sigma-models can be described in terms of generalized complex structures introduced by N. Hitchin. For example, we show that the path integral for the deformed sigma-model is localized on generalized holomorphic maps, whereas for the A-model and the B-model it is localized on holomorphic and constant maps, respectively. The geometry of topological D-branes is also best described using generalized complex structures. We also derive a constraint on the Chern character of topological D-branes, which includes A-branes and B-branes as special cases.Comment: 36 pages, AMS latex. v2: a reference to a related work has been added. v3: An error in the discussion of the Fourier-Mukai transform for twisted coherent sheaves has been fixed, resulting in several changes in Section 2. The rest of the paper is unaffected. v4: an incorrect statement concerning Lie algebroid cohomology has been fixe

Atomic and nano-scale characterization of a 50-year-old hydrated C3S paste

This paper investigates the atomic and nano-scale structures of a 50-year-old hydrated alite paste. Imaged by TEM, the outer product C-S-H fibers are composed of particles that are 1.5-2 nm thick and several tens of nanometers long. 29Si NMR shows 47.9% Q1 and 52.1% Q2, with a mean SiO4 tetrahedron chain length (MCL) of 4.18, indicating a limited degree of polymerization after 50 years' hydration. A Scanning Transmission X-ray Microscopy (STXM) study was conducted on this late-age paste and a 1.5 year old hydrated C3S solution. Near Edge X-ray Absorption Fine Structure (NEXAFS) at Ca L3,2-edge indicates that Ca2 + in C-S-H is in an irregular symmetric coordination, which agrees more with the atomic structure of tobermorite than that of jennite. At Si K-edge, multi-scattering phenomenon is sensitive to the degree of polymerization, which has the potential to unveil the structure of the SiO44 - tetrahedron chain

Intercultural mediation at the end of life. Different perceptions of the same process

The aim of this study was to identify the perceptions of palliative care professionals with regards to the management of patients from a different culture, and if there is a need to incorporate an intercultural mediator. To understand the influence of the intercultural mediator as a facilitator in the decision making of the patient and family at the end of life. The methodological approach is centered in pluralism, reinforced by triangulation of data and information. The intercultural mediator is crucial because they can provide light in a multitude of conflict situations caused by lack of knowledge about the patient's culture. (C) 2017 The Authors. Published by Elsevier Ltd