5,808 research outputs found
Preparation and characterization of magnetite (Fe3O4) nanoparticles By Sol-Gel method
The magnetite (Fe3O4) nanoparticles were successfully synthesized and annealed under vacuum at different temperature. The Fe3O4 nanoparticles prepared via sol-gel assisted method and annealed at 200-400ºC were characterized by Fourier Transformation Infrared Spectroscopy (FTIR), X-ray Diffraction spectra (XRD), Field Emission Scanning Electron Microscope (FESEM) and Atomic Force Microscopy (AFM). The XRD result indicate the presence of Fe3O4 nanoparticles, and the Scherer`s Formula calculated the mean particles size in range of 2-25 nm. The FESEM result shows that the morphologies of the particles annealed at 400ºC are more spherical and partially agglomerated, while the EDS result indicates the presence of Fe3O4 by showing Fe-O group of elements. AFM analyzed the 3D and roughness of the sample; the Fe3O4 nanoparticles have a minimum diameter of 79.04 nm, which is in agreement with FESEM result. In many cases, the synthesis of Fe3O4 nanoparticles using FeCl3 and FeCl2 has not been achieved, according to some literatures, but this research was able to obtained Fe3O4 nanoparticles base on the characterization results
Comparative Investigation of Microbial Communities Associated with Hydrothermal Activities in the Okinawa Trough
Hsp90 picks PIKKs via R2TP and Tel2
Phosphatidylinositol-3 kinase-like kinases (PIKKs) are dependent on Hsp90 for their activation via the R2TP complex and Tel2. In this issue of Structure, Pal and colleagues present the molecular mechanism by which PIKKs are recruited to Hsp90
Charge transfer and weak bonding between molecular oxygen and graphene zigzag edges at low temperatures
Electron paramagnetic resonance (EPR) study of air-physisorbed defective
carbon nano-onions evidences in favor of microwave assisted formation of
weakly-bound paramagnetic complexes comprising negatively-charged O2- ions and
edge carbon atoms carrying pi-electronic spins. These complexes being located
on the graphene edges are stable at low temperatures but irreversibly
dissociate at temperatures above 50-60 K. These EPR findings are justified by
density functional theory (DFT) calculations demonstrating transfer of an
electron from the zigzag edge of graphene-like material to oxygen molecule
physisorbed on the graphene sheet edge. This charge transfer causes changing
the spin state of the adsorbed oxygen molecule from S = 1 to S = 1/2 one. DFT
calculations show significant changes of adsorption energy of oxygen molecule
and robustness of the charge transfer to variations of the graphene-like
substrate morphology (flat and corrugated mono- and bi-layered graphene) as
well as edges passivation. The presence of H- and COOH- terminated edge carbon
sites with such corrugated substrate morphology allows formation of ZE-O2-
paramagnetic complexes characterized by small (<50 meV) binding energies and
also explains their irreversible dissociation as revealed by EPR.Comment: 28 pages, 8 figures, 2 tables, accepted in Carbon journa
Kondo effect in CeX (X=S, Se, Te) studied by electrical resistivity under high pressure
We have measured the electrical resistivity of cerium monochalcogenices, CeS,
CeSe, and CeTe, under high pressures up to 8 GPa. Pressure dependences of the
antiferromagnetic ordering temperature , crystal field splitting, and
the anomaly of the Kondo effect have been studied to cover the whole
region from the magnetic ordering regime at low pressure to the Fermi liquid
regime at high pressure. initially increases with increasing pressure,
and starts to decrease at high pressure as expected from the Doniach's diagram.
Simultaneously, the behavior in the resistivity is enhanced, indicating
the enhancement of the Kondo effect by pressure. It is also characteristic in
CeX that the crystal field splitting rapidly decreases at a common rate
of K/GPa. This leads to the increase in the degeneracy of the state
and further enhancement of the Kondo effect. It is shown that the pressure
dependent degeneracy of the state is a key factor to understand the
pressure dependence of , Kondo effect, magnetoresistance, and the peak
structure in the temperature dependence of resistivity.Comment: 9 pages, 5 figures, accepted for publication in J. Phys. Soc. Jp
Novel electronic wave interference patterns in nanographene sheets
Superperiodic patterns with a long distance in a nanographene sheet observed
by STM are discussed in terms of the interference of electronic wave functions.
The period and the amplitude of the oscillations decrease spatially in one
direction. We explain the superperiodic patterns with a static linear potential
theoretically. In the k-p model, the oscillation period decreases, and agrees
with experiments. The spatial difference of the static potential is estimated
as 1.3 eV for 200 nm in distance, and this value seems to be reasonable in
order that the potential difference remains against perturbations, for example,
by phonon fluctuations and impurity scatterings. It turns out that the
long-distance oscillations come from the band structure of the two-dimensional
graphene sheet.Comment: Published as a LETTER in J. Phys.: Condens. Matter; 8 pages; 6
figures; Online version at
http://www.iop.org/EJ/S/3/1256/0hJAmc5sCL6d.7sOO.BtLw/abstract/0953-8984/14/3
6/10
Preparation of high performance conductive Polyaniline Magnetite (PANI/Fe3O4) nanocomposites by sol-gel method
The conductivities of polyaniline magnetite (PANI/Fe3O4) nanocomposites prepared by sol-gel method were measured by standard van der Pauw DC 4-point probe method. PANI/Fe3O4 conductivity was measured as a function of wt % (5, 10, 15, 20 and 25 wt %) of Fe3O4 nanoparticles. It was observed that the conductivity of polyaniline containing certain percentage of Fe3O4 nanoparticles is slightly lower than the bulk PANI nanotubes and drastically decreases with increase of wt % Fe3O4 nanoparticles. The high conductivities of PANI/ Fe3O4 nanocomposites was observed due to high concentration of dopant (oxidants) used in the polymerization process and the optimization of these composites allows this being use as a parameter for the production of nanofibers. Fourier transform infrared spectra, field emission scanning electron microscope, X-ray diffraction and ultraviolet-visible absorption spectra are used to characterize the phase structure, morphologies and functional group of the PANI/Fe3O4 composites samples. Fourier transform infrared analysis indicates the presence of PANI containing Fe3O4 nanoparticles and the field emission scanning electron microscope (FESEM) results has proven that the formation of nanofibers in the PANI/Fe3O4 nanocomposites. The crystalline phase of PANI/Fe3O4 nanocomposites studied by X-ray diffraction indicated that the Fe3O4 nanoparticles was present in the PANI matrices
A Nuclear Physics Program at the ATLAS Experiment at the CERN Large Hadron Collider
The ATLAS collaboration has significant interest in the physics of
ultra-relativistic heavy ion collisions. We submitted a Letter of Intent to the
United States Department of Energy in March 2002. The following document is a
slightly modified version of that LOI. More details are available at:
http://atlas.web.cern.ch/Atlas/GROUPS/PHYSICS/SM/ionsComment: Letter of Intent submitted to the United States Department of Energy
Nuclear Physics Division in March 2002 (revised version
Metacarpophalangeal pattern profile analysis of a sample drawn from a North Wales population
This is tha author's PDF version of an article published in Annals of human biology© 2001. The definitive version is available at http://www.tandf.co.uk/journalsSexual dimorphism and population differences were investigated using metacarpophalangeal pattern profile (MCPP) analysis. Although it is an anthropmetric technique, MCPP analysis is more frequently used in genetic syndrome analysis and has been under-used in the study of human groups. The present analysis used a series of hand radiographics from Gwynedd, North Wales, to make comparisons, first, between the sexes within the sample and then with previously reported data from Japan. The Welsh sexes showed MCPP analyses that indicated size and shape differences but certain similarities in shape were also evident. Differences with the Japanese data were more marked. MCPP anlysis is a potentially useful anthropmetric technique but requires further statistical development
Large-scale Synthesis of Monodisperse PbS Quantum Dots
PbS quantum dots (QDs) are a promising material for designing of modern solar energy convertors. Yet, their reproducible synthesis is still intractable, since typical methods do not allow controlling the growth of PbS nanocrystals due to the high reaction rates. Here we propose the two-step synthetic procedure, which allows controlling precisely nanocrystal growth on the second stage. The first step allows obtaining small PbS QDs by the standard hot injection method, which are then slowly grown to a desired size on the second stage. By use of this method, we were able to obtain gram-scale batches of PbS QDs with high reproducibility of the photoluminescence properties of the synthesis product.
Keywords: PbS quantum dots, nanoparticles growth, infrared luminescenc
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