Etudes in situ de la formation du carbonate de calcium CaCO3 synthétisé en milieu aqueux sous pression de CO2

National audienc

IGRJ17361-4441: a possible new accreting X-ray binary in NGC6388

IGRJ17361-4441 is a newly discovered INTEGRAL hard X-ray transient, located in the globular cluster NGC6388. We report here the results of the X-ray and radio observations performed with Swift, INTEGRAL, RXTE, and the Australia Telescope Compact Array (ATCA) after the discovery of the source on 2011 August 11. In the X-ray domain, IGRJ17361-4441 showed virtually constant flux and spectral parameters up to 18 days from the onset of the outburst. The broad-band (0.5-100 keV) spectrum of the source could be reasonably well described by using an absorbed power-law component with a high energy cut-off (N_H\simeq0.8x10^(22) cm^(-2), {\Gamma}\simeq0.7-1.0, and E_cut\simeq25 keV) and displayed some evidence of a soft component below \sim2 keV. No coherent timing features were found in the RXTE data. The ATCA observation did not detect significant radio emission from IGRJ17361-4441, and provided the most stringent upper limit (rms 14.1 {\mu}Jy at 5.5 GHz) to date on the presence of any radio source close to the NGC6388 center of gravity. The improved position of IGRJ17361-4441 in outburst determined from a recent target of opportunity observation with Chandra, together with the X-ray flux and radio upper limits measured in the direction of the source, argue against its association with the putative intermediate-mass black hole residing in the globular cluster and with the general hypothesis that the INTEGRAL source is a black hole candidate. IGRJ17361-4441 might be more likely a new X-ray binary hosting an accreting neutron star. The ATCA radio non-detection also permits us to derive an upper limit to the mass of the suspected intermediate massive black hole in NGC6388 of <600 M\odot. This is a factor of 2.5 lower than the limit reported previously.Comment: Accepted for publication on A&A lette

Microencapsulation of Proteins within Polymeric and Inorganic Particles using Supercritical CO2 Media

International audienc

Microencapsulation of proteins within CaCO3 microspheres using supercritical CO2 media

International audienc

Encapsulation de proteins thérapeutiques dans des microspheres de CaCO3 élaborées en milieu CO2 supercritique

National audienc

Synthesis of hollow vaterite CaCO(3) microspheres in supercritical carbon dioxide medium

We here describe a rapid method for synthesizing hollow core, porous crystalline calcium carbonate microspheres composed of vaterite using supercritical carbon dioxide in aqueous media, without surfactants. We show that the reaction in alkaline media rapidly conducts to the formation of microspheres with an average diameter of 5 mu m. SEM, TEM and AFM observations reveal that the microspheres have a hollow core of around 0.7 mu m width and are composed of nanograins with an average diameter of 40 nm. These nanograins are responsible for the high specific surface area of 16 m(2) g(-1) deduced from nitrogen absorption/desorption isotherms, which moreover confers an important porosity to the microspheres. We believe this work may pave the way for the elaboration of a biomaterial with a large potential for therapeutic as well as diagnostic applications

Encapsulation of growth factors into calcium carbonate microparticles elaborated in supercritical CO2 medium

National audienc

The discovery of the 401 Hz accreting millisecond pulsar IGR J17498-2921 in a 3.8 hr orbit

We report on the detection of a 400.99018734(1) Hz coherent signal in the Rossi X-ray Timing Explorer light curves of the recently discovered X-ray transient, IGR J17498-2921. By analysing the frequency modulation caused by the orbital motion observed between August 13 and September 8, 2011, we derive an orbital solution for the binary system with a period of 3.8432275(3) hr. The measured mass function, f(M_2, M_1, i)=0.00203807(8) Msun, allows to set a lower limit of 0.17 Msun on the mass of the companion star, while an upper limit of 0.48 Msun is set by imposing that the companion star does not overfill its Roche lobe. We observe a marginally significant evolution of the signal frequency at an average rate of -(6.3 +/- 1.9)E-14 Hz/s. The low statistical significance of this measurement and the possible presence of timing noise hampers a firm detection of any evolution of the neutron star spin. We also present an analysis of the spectral properties of IGR J17498-2921 based on the observations performed by the Swift-X-ray Telescope and the RXTE-Proportional Counter Array between August 12 and September 22, 2011. During most of the outburst, the spectra are modeled by a power-law with an index Gamma~1.7-2, while values of ~3 are observed as the source fades into quiescence.Comment: 5 pages, 2 figures, accepted for publication by A&A Letters on 7/11/201