Combined ground and aerial measurements resolve vent-specific gas fluxes from a multi-vent volcano

Volcanoes with multiple summit vents present a methodological challenge for determining vent-specific gas emissions. Here, using a novel approach combining multiple ultraviolet cameras with synchronous aerial measurements, we calculate vent-specific gas compositions and fluxes for Stromboli volcano. Emissions from vent areas are spatially heterogeneous in composition and emission rate, with the central vent area dominating passive emissions, despite exhibiting the least explosive behaviour. Vents exhibiting Strombolian explosions emit low to negligible passive fluxes and are CO2-dominated, even during passive degassing. We propose a model for the conduit system based on contrasting rheological properties between vent areas. Our methodology has advantages for resolving contrasting outgassing dynamics given that measured bulk plume compositions are often intermediate between those of the distinct vent areas. We therefore emphasise the need for a vent-specific approach at multi-vent volcanoes and suggest that our approach could provide a transformative advance in volcano monitoring applications

Conduit dynamics and post-explosion degassing on Stromboli:a combined UV camera and 1 numerical modelling treatment

Recent gas flux measurements have shown that strombolian explosions are often followed by periods of elevated flux, or ‘gas codas’, with durations of order a minute. Here, we present UV camera data from 200 events recorded at Stromboli volcano to constrain the nature of these codas for the first time, providing estimates for combined explosion plus coda SO2 masses of ≈ 18 – 225 kg. Numerical simulations of gas slug ascent show that substantial proportions of the initial gas mass can be distributed into a train of ‘daughter bubbles’ released from the base of the slug, which we suggest, generate the codas, on bursting at the surface. This process could also cause transitioning of slugs into cap bubbles, significantly reducing explosivity. This study is the first attempt to combine high temporal resolution gas flux data with numerical simulations of conduit gas flow to investigate volcanic degassing dynamics

Dynamics of mild strombolian activity on Mt. Etna

Here we report the first measurements of gas masses released during a rare period of strombolian activity at the Bocca Nuova crater, Mt. Etna, Sicily. UV camera data acquired for 195 events over an ≈27 minute period (27th July 2012) indicate erupted SO2 masses ranging from ≈0.1 to ≈14 kg per event, with corresponding total gas masses of ≈0.1 to 74 kg. Thus, the activity was characterised by more frequent and smaller events than typically associated with strombolian activity on volcanoes such as Stromboli. Events releasing larger measured gas masses were followed by relatively long repose periods before the following burst, a feature not previously reported on from gas measurement data. If we assume that gas transport within the magma can be represented by a train of rising gas pockets or slugs, then the high frequency of events indicates that these slugs must have been in close proximity. In this case the longer repose durations associated with the larger slugs would be consistent with interactions between adjacent slugs leading to coalescence, a process expedited close to the surface by rapid slug expansion. We apply basic modelling considerations to the measured gas masses in order to investigate potential slug characteristics governing the observed activity.We also cross correlated the acquired gas fluxes with contemporaneously obtained seismic data but found no relationship between the series in line with the mild form of manifest explosivity

Temporal variability in gas emissions at Bagana volcano revealed by aerial, ground, and satellite observations

Bagana is a remote, highly active volcano, located on Bougainville Island in southeastern Papua New Guinea. The volcano has exhibited sustained and prodigious sulfur dioxide gas emissions in recent decades, accompanied by frequent episodes of lava extrusion. The remote location of Bagana and its persistent activity have made it a valuable case study for satellite observations of active volcanism. This remoteness has also left many features of Bagana relatively unexplored. Here, we present the first measurements of volcanic gas composition, achieved by unoccupied aerial system (UAS) flights through the volcano's summit plume, and a payload comprising a miniaturized MultiGAS. We combine our measurements of the molar CO2/SO2 ratio in the plume with coincident remote sensing measurements (ground- and satellite-based) of SO2 emission rate to compute the first estimate of CO2 flux at Bagana. We report low SO2 and CO2 fluxes at Bagana from our fieldwork in September 2019, ∼320 ± 76 td−1 and ∼320 ± 84 td−1, respectively, which we attribute to the volcano's low level of activity at the time of our visit. We use satellite observations to demonstrate that Bagana's activity and emissions behavior are highly variable and advance the argument that such variability is likely an inherent feature of many volcanoes worldwide and yet is inadequately captured by our extant volcanic gas inventories, which are often biased to sporadic measurements. We argue that there is great value in the use of UAS combined with MultiGAS-type instruments for remote monitoring of gas emissions from other inaccessible volcanoes

Azetidinium lead iodide for perovskite solar cells

Azetidinium lead iodide has been prepared for the first time; it is a stable, bright orange material that can act as the absorber layer in solar cells.</p

Comparison of 1.0 M gadobutrol and 0.5 M gadopentate dimeglumine-enhanced MRI in 471 patients with known or suspected renal lesions: Results of a multicenter, single-blind, interindividual, randomized clinical phase III trial

The purpose of this phase III clinical trial was to compare two different extracellular contrast agents, 1.0 M gadobutrol and 0.5 M gadopentate dimeglumine, for magnetic resonance imaging (MRI) in patients with known or suspected focal renal lesions. Using a multicenter, single-blind, interindividual, randomized study design, both contrast agents were compared in a total of 471 patients regarding their diagnostic accuracy, sensitivity, and specificity to correctly classify focal lesions of the kidney. To test for noninferiority the diagnostic accuracy rates for both contrast agents were compared with CT results based on a blinded reading. The average diagnostic accuracy across the three blinded readers ('average reader') was 83.7% for gadobutrol and 87.3% for gadopentate dimeglumine. The increase in accuracy from precontrast to combined precontrast and postcontrast MRI was 8.0% for gadobutrol and 6.9% for gadopentate dimeglumine. Sensitivity of the average reader was 85.2% for gadobutrol and 88.7% for gadopentate dimeglumine. Specificity of the average reader was 82.1% for gadobutrol and 86.1% for gadopentate dimeglumine. In conclusion, this study documents evidence for the noninferiority of a single i.v. bolus injection of 1.0 M gadobutrol compared with 0.5 M gadopentate dimeglumine in the diagnostic assessment of renal lesions with CE-MRI

Correlation of oscillatory behaviour in Matlab using wavelets

Here we present a novel computational signal processing approach for comparing two signals of equal length and sampling rate, suitable for application across widely varying areas within the geosciences. By performing a continuous wavelet transform (CWT) followed by Spearman's rank correlation coefficient analysis, a graphical depiction of links between periodicities present in the two signals is generated via two or three dimensional images. In comparison with alternate approaches, e.g., wavelet coherence, this technique is simpler to implement and provides far clearer visual identification of the inter-series relationships. In particular, we report on a Matlab® code which executes this technique, and examples are given which demonstrate the programme application with artificially generated signals of known periodicity characteristics as well as with acquired geochemical and meteorological datasets. © 2014 Elsevier Ltd

High time resolution fluctuations in volcanic carbon dioxide degassing from Mount Etna

We report here on thefirst record of carbon dioxide gas emission rates from a volcano, captured at≈1 Hz. These data were acquired with a novel technique, based on the integration of UV camera observations (to measure SO2 emission rates) and field portable gas analyser readings of plume CO2/SO2 ratios. Our measurements were performedat the North East crater of Mount Etna, southern Italy, and the data reveal strong variability in CO2 emissions over timescales of tens to hundreds of seconds, spanning two orders of magnitude. This carries importantimplications for attempts to constrain global volcanic CO2 release to the atmosphere, and will lead to an increased insight into short term CO2 degassing trends. A common oscillation in CO2 and SO2 emission rates in addition to the CO2/SO2 ratios was observed at periods of ≈89 s. Our results are furthermore suggestive of an intriguing temporal lag between oscillations in CO2 emissions and seismicity at periods of ≈300–400 s, with peaks and troughs in the former series leading those in the latter by ≈150 s. This work opens the way to the acquisition of further datasets with this methodology across a range of basaltic systems to better our understandingof deep magmatic processes and of degassing links to manifest geophysical signalsPublished115–1212V. Dinamiche di unrest e scenari pre-eruttiviJCR Journalrestricte

Micro-Interactions with NFC-Enabled Mobile Phones

Abstract. This paper coins the term micro-interactions to refer to the class of small exchanges between devices that occur almost instantaneously. For example, a mobile payment using near-field communication (NFC) is a micro-interaction. The arrival of NFC on smart phones makes possible a wide array of applications using micro-interactions, from sharing photos between a phone and a TV to checking a car into a valet parking service by touching two phones. This paper addresses the challenge of how to create intuitive, frictionless micro-interactions that require no pre-configuration for a large class of applications. We deliver a consistent tap-and-share interface for many forms of micro-interactions through several concepts. We propose interaction manifests as universal descriptors of multi-party, cross-platform applications. Zero-click overheads are made possible by automatically using the foreground application as the context for the micro-interactions. We extend the concept of connection handovers to allow NFC-enabled applications to run unmodified on devices lacking NFC. We also show how these abstractions make it easy to create a variety of applications. All the application and library code is available as open source. We demonstrate that by focusing on micro-interactions, our mobile phones can provide a single focal point that enables sharing of our digital identity, assets, applications, and personality with friends (with their mobile phones) as well as the larger-screen PCs and TVs all around us.