Heat capacity of α\alpha-GaN: Isotope Effects

Until recently, the heat capacity of GaN had only been measured for polycrystalline powder samples. Semiempirical as well as \textit{first-principles} calculations have appeared within the past few years. We present in this article measurements of the heat capacity of hexagonal single crystals of GaN in the 20-1400K temperature range. We find that our data deviate significantly from the literature values for polycrystalline materials. The dependence of the heat capacity on the isotopic mass has also been investigated recently for monatomic crystals such as diamond, silicon, and germanium. Multi-atomic crystals are expected to exhibit a different dependence of these heat capacities on the masses of each of the isotopes present. These effects have not been investigated in the past. We also present \textit{first-principles} calculations of the dependence of the heat capacities of GaN, as a canonical binary material, on each of the Ga and N masses. We show that they are indeed different, as expected from the fact that the Ga mass affects mainly the acoustic, that of N the optic phonons. It is hoped that these calculations will encourage experimental measurements of the dependence of the heat capacity on isotopic masses in binary and more complex semiconductors.Comment: 12 pages, 5 Figures, submitted to PR

The Short Range RVB State of Even Spin Ladders: A Recurrent Variational Approach

Using a recursive method we construct dimer and nondimer variational ansatzs of the ground state for the two-legged ladder, and compute the number of dimer coverings, the energy density and the spin correlation functions. The number of dimer coverings are given by the Fibonacci numbers for the dimer-RVB state and their generalization for the nondimer ones. Our method relies on the recurrent relations satisfied by the overlaps of the states with different lengths, which can be solved using generating functions. The recurrent relation method is applicable to other short range systems. Based on our results we make a conjecture about the bond amplitudes of the 2-leg ladder.Comment: REVTEX file, 32 pages, 10 EPS figures inserted in text with epsf.st

Green criminology: shining a critical lens on environmental harm

Green criminology provides for inter-disciplinary and multi-disciplinary engagement with environmental crimes and wider environmental harms. Green criminology applies a broad ‘‘green’’ perspective to environmental harms, ecological justice, and the study of environmental laws and criminality, which includes crimes affecting the environment and non-human nature. Within the ecological justice and species justice perspectives of green criminology there is a contention that justice systems need to do more than just consider anthropocentric notions of criminal justice, they should also consider how justice systems can provide protection and redress for the environment and other species. Green criminological scholarship has, thus, paid direct attention to theoretical questions of whether and how justice systems deal with crimes against animals and the environment; it has begun to conceptualize policy perspectives that can provide contemporary ecological justice alongside mainstream criminal justice. Moving beyond mainstream criminology’s focus on individual offenders, green criminology also explores state failure in environmental protection and corporate offending and environmentally harmful business practices. A central discussion within green criminology is that of whether environmental harm rather than environmental crime should be its focus, and whether green ‘‘crimes’’ should be seen as the focus of mainstream criminal justice and dealt with by core criminal justice agencies such as the police, or whether they should be considered as being beyond the mainstream. This article provides an introductory overview that complements a multi- and inter-disciplinary article collection dedicated to green criminological thinking and research

Cancer metastasis networks and the prediction of progression patterns

Other Research Uni

Nucleation and crystallization in bio-based immiscible polyester blends

Bio-based thermoplastic polyesters are highly promising materials as they combine interesting thermal and physical properties and in many cases biodegradability. However, sometimes the best property balance can only be achieved by blending in order to improve barrier properties, biodegradability or mechanical properties. Nucleation, crystallization and morphology are key factors that can dominate all these properties in crystallizable biobased polyesters. Therefore, their understanding, prediction and tailoring is essential. In this work, after a brief introduction about immiscible polymer blends, we summarize the crystallization behavior of the most important bio-based (and immiscible) polyester blends, considering examples of double-crystalline components. Even though in some specific blends (e.g., polylactide/polycaprolactone) many efforts have been made to understand the influence of blending on the nucleation, crystallization and morphology of the parent components, there are still many points that have yet to be understood. In the case of other immiscible polyester blends systems, the literature is scarce, opening up opportunities in this environmentally important research topic.The authors would like to acknowledge funding by the BIODEST project ((RISE) H2020-MSCA-RISE-2017-778092

Inter-laboratory test on thermophysical properties of the ITER grade heat sink material copper-chromium-zirconium

Copper-chromium-zirconium (CuCrZr) is a commercially available, precipitation-strengthened alloy. The combination of its good thermal conductivity and mechanical strength at low and moderate temperatures made it of interest for use as a heat sink material in high heat flux components in actual and future fusion facilities. Its only drawback is the microstructural modification and thereby, particularly, the loss of mechanical strength at temperatures above 500 A degrees C. This limits the allowable operational temperatures and the temperature range in which cyclic and reproducible measurements of thermophysical properties can be performed. These difficulties and the international significance of the material makes it an excellent object of study for an interlaboratory test of several independent European thermophysical laboratories, in which the quality and the comparability of thermophysical measurements were determined. The main outcome (result, conclusion) of this study is that the different laboratory data are in good agreement providing maximum deviations of similar to 5 % for dilatometry, similar to 2 % for DSC measurements, and up to 10 % for thermal-diffusivity measurements. In addition to the determined high reproducibility within the particular thermophysical laboratories, it was found that the average thermal conductivity of CuCrZr produced in a certain compositional range is identical within a small-scatter band