Origin of the bentonite deposits of eastern Milos, Aegean, Greece: Geological, mineralogical and geochemical evidence

Summarization: The Lower Pleistocene bentonite deposits of Eastern Milos, Greece have been formed at the expense of volcaniclastic rocks under submarine conditions. Systematic variation of the major chemical elements reveals that the deposits were formed from different precursors which were erupted from different volcanic centers belonging to at least two separate volcanic provinces. The volcanic eruptions were probably subaqueous. The major authigenic phases are smectite, K-feldspar, opal-CT and the zeolites mordenite and clinoptilolite. The deposits have a complex history and have been affected by hydrothermal alteration. The geological features ofbentonites coupled by the presence of abundant authigenic K-feldspar indicate that alteration of the parent volcanoclastic rocks took place under low temperatures and is probably not related to hydrothermal alteration, which is a separate event. Hydrothermal alteration has modified both the mineralogical characteristics and the properties of bentonites. Alteration of the parent rocks to bentonites was favoured by high water : wall rock ratios and fluid flow and is associated with leaching and subsequent removal of Na, K and Ca. The source of Mg was the parent rocks and only small scale Mguptake from the sea water has probably taken place. The formation of authigenic K-feldspar has probably been favoured by a high K§ + activity ratio and high Si activity of the pore fluid. Such conditions might have been favoured by the pH conditions and the cooling history of the parent rocks.Presented on: Clays and Clay Mineral

Modifications geochimiques d'une granodiorite, pres d'une veine mineralisee dans la region des mines d'Aghios Philippos, Kirki (Grece du Nord).

Kaolinite, illite, montmorillonite and pyrophyllite are the main products of the intense hydrothermal alteration found above the granodiorite body at Aghios Philippos mine, Kirki, NE Greece. The altered granodiorite is in contact with a mineralized vein consisting chiefly of sphalerite, pyrite, galena and chalcopyrite. As result of hydrothermal alteration, the elements Ca, Mg, Na, Fetot and Al are leached out and a relative accumulation of Si is observed from the unaltered granodiorite towards the mineralized vein.-C.N