The effects of space radiation on a chemically modified graphite-epoxy composite material

The effects of the space environment on the engineering properties and chemistry of a chemically modified T300/934 graphite-epoxy composite system are characterized. The material was subjected to 1.0 x 10 to the 10th power rads of 1.0 MeV electron irradiation under vacuum to simulate 30 years in geosynchronous earth orbit. Monotonic tension tests were performed at room temperature (75 F/24 C) and elevated temperature (250 F/121 C) on 4-ply unidirectional laminates. From these tests, inplane engineering and strength properties (E sub 1, E sub 2, Nu sub 12, G sub 12, X sub T, Y sub T) were determined. Cyclic tests were also performed to characterize energy dissipation changes due to irradiation and elevated temperature. Large diameter graphite fibers were tested to determine the effects of radiation on their stiffness and strength. No significant changes were observed. Dynamic-mechanical analysis demonstrated that the glass transition temperature was reduced by 50 F(28 C) after irradiation. Thermomechanical analysis showed the occurrence of volatile products generated upon heating of the irradiated material. The chemical modification of the epoxy did not aid in producing a material which was more radiation resistant than the standard T300/934 graphite-epoxy system. Irradiation was found to cause crosslinking and chain scission in the polymer. The latter produced low molecular weight products which plasticize the material at elevated temperatures and cause apparent material stiffening at low stresses at room temperature

Neutron spectroscopic factors of Ni isotopes from transfer reactions

177 neutron spectroscopic factors for nickel isotopes have been extracted by performing a systematic analysis of the angular distributions measured from (d,p) transfer reactions. A subset of the extracted spectroscopic factors are compared to predictions of large-basis shell models in the full pf model space using the GXPF1A effective interaction, and the (f5/2, p3/2, p1/2, g9/2) model space using the JJ4PNA interaction. For ground states, the predicted spectroscopic factors using the GXPF1A effective interaction in the full pf model space agree very well with the experimental values, while predictions based on several other effective interactions and model spaces are about 30% higher than the experimental values. For low-energy excited states (<3.5 MeV), the agreement between the extracted spectroscopic factors and shell model calculations is not better than a factor of two.Comment: 18 pages, 4 figures, 2 tables. accepted for publication in PR

What works in advocating for food advertising policy change across an english region - a realist evaluation.

With increasing recognition of the role of commercial determinants of health, local areas in England have sought to restrict the advertising of products high in fat, salt and sugar (HFSS) on council-owned spaces, as part of wider strategies to reduce obesity. While there is some evidence of the impact of such policy change on behaviour, little is known about what works in the process of implementing this policy change. Guided by a realist evaluation framework that explores the interaction between context, mechanism and outcomes, this study aims to investigate the factors that influence the restriction of outdoor advertising of HFSS products in one region in England. It refines a programme theory co-produced with stakeholders from 14 local authorities within a region and uses multiple data sources from each area with an in-depth examination of four case study sites. Data sources include longitudinal realist interviews, focus groups and surveys with policy advocates and policy stakeholders. Data were analysed retroductively to understand the causal link between context, mechanism and outcomes. Outcomes were driven by five dominant mechanisms: a strategic and staggered approach to stakeholder engagement, gathering intelligence, identifying policy champions, building relationships, reframing the issue; and two secondary mechanisms of amplifying the issue and increasing public will. These led to varied outcomes with no changes in formal policy position within the evaluation period but draft policy guidance in place and changes in political will demonstrated. Dominant context factors influencing change included having a named and resourced policy advocate in place supported by an external Community of Improvement and having existing aligned local objectives. Organisational complexity and change, financial concerns, lack of local examples, ideological positions and the pandemic were also influencing contextual factors. Effecting policy change in this area requires the commitment of an extended period and the valuing of short-term policy outcomes, such as increasing political will. The importance of a resourced and well-supported policy advocate to lead this work is fundamental and the commercially sensitive nature of this policy change means that a complex interplay of mechanisms is required which may be dominated by a strategically staggered approach to stakeholder engagement. [Abstract copyright: © 2023. BioMed Central Ltd., part of Springer Nature.

Simulation and Measurement of Transient Fluid Phenomena within Diesel Injection

Rail pressures of modern diesel fuel injection systems have increased significantly over recent years, greatly improving atomisation of the main fuel injection event and air utilisation of the combustion process. Continued improvement in controlling the process of introducing fuel into the cylinder has led to focussing on fluid phenomena related to transient response. High-speed microscopy has been employed to visualise the detailed fluid dynamics around the near nozzle region of an automotive diesel fuel injector, during the opening, closing and post injection events. Complementary computational fluid dynamic (CFD) simulations have been undertaken to elucidate the interaction of the liquid and gas phases during these highly transient events, including an assessment of close-coupled injections. Microscopic imaging shows the development of a plug flow in the initial stages of injection, with rapid transition into a primary breakup regime, transitioning to a finely atomised spray and subsequent vaporisation of the fuel. During closuring of the injector the spray collapses, with evidence of swirling breakup structures together with unstable ligaments of fuel breaking into large slow-moving droplets. This leads to sub-optimal combustion in the developing flame fronts established by the earlier, more fully-developed spray. The simulation results predict these observed phenomena, including injector surface wetting as a result of large slow-moving droplets and post-injection discharge of liquid fuel. This work suggests that post-injection discharges of fuel play a part in the mechanism of the initial formation, and subsequent accumulation of deposits on the exterior surface of the injector. For multiple injections, opening events are influenced by the dynamics of the previous injection closure; these phenomena have been investigated within the simulations

Site percolation and random walks on d-dimensional Kagome lattices

The site percolation problem is studied on d-dimensional generalisations of the Kagome' lattice. These lattices are isotropic and have the same coordination number q as the hyper-cubic lattices in d dimensions, namely q=2d. The site percolation thresholds are calculated numerically for d= 3, 4, 5, and 6. The scaling of these thresholds as a function of dimension d, or alternatively q, is different than for hypercubic lattices: p_c ~ 2/q instead of p_c ~ 1/(q-1). The latter is the Bethe approximation, which is usually assumed to hold for all lattices in high dimensions. A series expansion is calculated, in order to understand the different behaviour of the Kagome' lattice. The return probability of a random walker on these lattices is also shown to scale as 2/q. For bond percolation on d-dimensional diamond lattices these results imply p_c ~ 1/(q-1).Comment: 11 pages, LaTeX, 8 figures (EPS format), submitted to J. Phys.

Phases of granular segregation in a binary mixture

We present results from an extensive experimental investigation into granular segregation of a shallow binary mixture in which particles are driven by frictional interactions with the surface of a vibrating horizontal tray. Three distinct phases of the mixture are established viz; binary gas (unsegregated), segregation liquid and segregation crystal. Their ranges of existence are mapped out as a function of the system's primary control parameters using a number of measures based on Voronoi tessellation. We study the associated transitions and show that segregation can be suppressed is the total filling fraction of the granular layer, $C$, is decreased below a critical value, $C_{c}$, or if the dimensionless acceleration of the driving, $\gamma$, is increased above a value $\gamma_{c}$.Comment: 12 pages, 12 figures, submitted to Phys. Rev.