Effect of RF power on the structural, optical and gas sensing properties of RF-​sputtered Al doped ZnO thin films

The effect of Radio Frequency (RF) power on the properties of magnetron sputtered Al doped ZnO thin films and the related sensor properties are investigated. A series of 2 wt​% Al doped ZnO; Zn0.98Al0.02O (AZO) thin films prepd. with magnetron sputtering at different RF powers, are examd. The structural results reveal a good adhesive nature of thin films with quartz substrates as well as increasing thickness of the films with increasing RF power. Besides, the increasing RF power is found to improve the crystallinity and grain growth as confirmed by X-​ray diffraction. On the other hand, the optical transmittance is significantly influenced by the RF power, where the transparency values achieved are higher than 82​% for all the AZO thin films and the estd. optical band gap energy is found to decrease with RF power due to an increase in the crystallite size as well as the film thickness. In addn., the defect induced luminescence at low temp. (77 K) and room temp. (300 K) was studied through photoluminescence spectroscopy, it is found that the defect d. of electronic states of the Al3+ ion increases with an increase of RF power due to the increase in the thickness of the film and the crystallite size. The gas sensing behavior of AZO films was studied for NO2 at 350 °C. The AZO film shows a good response towards NO2 gas and also a good relationship between the response and the NO2 concn., which is modeled using an empirical formula. The sensing mechanism of NO2 is discussed

Luminescence studies during combustion synthesis of a long afterglow phosphor Sr₄Al₁₄O₂₅:Eu²⁺, Dy³⁺

178-180The long glow persistent phosphor Sr4Al14O25:Eu2+, Dy3+ has been synthesized through combustion route. SrAl4O7 and SrAl2O4 are identified as the intermediate products formed at different temperatures during the synthesis of Sr4Al14O25:Eu2+,Dy3+. The photoluminescence and afterglow emission of the intermediate products have been systematically studied. The photoluminescence and afterglow emission profiles of the intermediate products varied with the temperature of synthesis. For a sample with similar aluminate phases (at a particular synthesis temperature) the λAGL and λPL are different. However, for Sr4Al14O25:Eu2+,Dy3+ annealed at 1200-1300ºC, the AGL and PL emissions are similar

Synthesis, characterization and optical properties of hybrid PVA-ZnO nanocomposite: A composition dependent study

Nanocomposites of poly vinyl alcohol (PVA) and ZnO have been synthesized using the solution casting technique for different concentrations of nano ZnO powder prepared by low temperature solution combustion method. The formation of polymer nanocomposite and changes in the structural and micro structural properties of the materials were investigated by X-ray diffraction, Energy dispersive X ray spectroscopy and optical microscopy techniques (FTIR and UV-Visible). The surface morphology of PVA-ZnO nanocomposite films were elucidated using Scanning Electron Microscopy. The optical absorption spectrum of nano ZnO shows blue shift in the optical band gap energy with respect to characteristic bulk ZnO at room temperature, whereas PVA-ZnO hybrid films show red shift with respect to nano ZnO. The photoluminescence studies show that the intensity of the blue emission (470 nm) varies with change in concentration of ZnO with an optimum intensity observed at 10 mol of ZnO. © 2014 Elsevier Ltd

Epigenetic Reprogramming of TGF-β Signaling in Breast Cancer

The Transforming Growth Factor-β (TGF-β) signaling pathway has a well-documented, context-dependent role in breast cancer development. In normal and premalignant cells, it acts as a tumor suppressor. By contrast, during the malignant phases of breast cancer progression, the TGF-β signaling pathway elicits tumor promoting effects particularly by driving the epithelial to mesenchymal transition (EMT), which enhances tumor cell migration, invasion and ultimately metastasis to distant organs. The molecular and cellular mechanisms that govern this dual capacity are being uncovered at multiple molecular levels. This review will focus on recent advances relating to how epigenetic changes such as acetylation and methylation control the outcome of TGF-β signaling and alter the fate of breast cancer cells. In addition, we will highlight how this knowledge can be further exploited to curb tumorigenesis by selective targeting of the TGF-β signaling pathway

Luminescence studies on photostimulable phosphor CsBr:Eu2+

Photostimulable phosphor CsBr:Eu2+ is prepared through a solid-state reaction. The effect of annealing atmosphere on photoluminescence and photostimulated luminescence was investigated. Optimum luminescence intensity was obtained when samples were prepared at 350 degrees C in air atmosphere. The effect of irradiation of gamma and neutron had resulted in the formation of optically stimulable traps with different trap depths. The role of monovalent and divalent dopants on thermoluminescence dosimetric properties has been discussed