8 research outputs found

    The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges

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    An investigation of gaseous and particulate emissions from compression ignition engines operated with alternative fuels, injection technologies, and combustion strategies

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    Whilst the compression ignition (CI) engine exhibits many design advantages relative to its spark ignition engine counterpart; such as: high thermal efficiency, fuel economy and low carbon monoxide and hydrocarbon emissions, the issue of Diesel Particulate Matter (DPM) emissions continues to be an unresolved problem for the CI engine. Primarily, this thesis investigates a range of DPM mitigation strategies such as alternative fuels, injection technologies and combustion strategies conducted with a view to determine their impact on the physico-chemical properties of DPM emissions, and consequently to shed light on their likely human health impacts. Regulated gaseous emissions, Nitric oxide (NO), Carbon monoxide (CO), and Hydrocarbons (HCs), were measured in all experimental campaigns, although the major focus in this research program was on particulate emissions..

    Exit humidity of wet scrubbers for underground coal mines

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    A wet scrubber is a device used in underground coal mines for the exhaust treatment system of various internal combustion engines (generally diesel) primarily as a spark arrestor with a secondary function to remove pollutants from the exhaust gas. A pool of scrubbing liquid (generally water based) is used in conjunction with a Diesel Particulate Filter (DPF). Scrubbers are widely used in underground applications of diesel engines as their exhaust contains high concentration of harmful diesel particulate matter (DPM) and other pollutant gases. Currently the DPFs have to be replaced frequently because moisture output from the wet scrubber blocks the filter media and causes reduced capacity. This paper presents experimental and theoretical studies on the heat and mass transfer mechanisms of the exhaust flow both under and above the water surface, aiming at finding the cause and effects of the moisture reaching the filters and employing a solution to reduce the humidity and DPM output, and to prolong the change-out period of the DPF. By assuming a steady flow condition, heat transfer from the inlet exhaust gas balances energy required for the water evaporation. Hence the exit humidity will decrease with the increase of exit temperature. Experiments on a real scrubber are underway

    Application of Multicriteria Decision Making Methods to Compression Ignition Engine Efficiency and Gaseous, Particulate, and Greenhouse Gas Emissions

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    Compression ignition (CI) engine design is subject to many constraints, which present a multicriteria optimization problem that the engine researcher must solve. In particular, the modern CI engine must not only be efficient but must also deliver low gaseous, particulate, and life cycle greenhouse gas emissions so that its impact on urban air quality, human health, and global warming is minimized. Consequently, this study undertakes a multicriteria analysis, which seeks to identify alternative fuels, injection technologies, and combustion strategies that could potentially satisfy these CI engine design constraints. Three data sets are analyzed with the Preference Ranking Organization Method for Enrichment Evaluations and Geometrical Analysis for Interactive Aid (PROMETHEE-GAIA) algorithm to explore the impact of (1) an ethanol fumigation system, (2) alternative fuels (20% biodiesel and synthetic diesel) and alternative injection technologies (mechanical direct injection and common rail injection), and (3) various biodiesel fuels made from 3 feedstocks (i.e., soy, tallow, and canola) tested at several blend percentages (20–100%) on the resulting emissions and efficiency profile of the various test engines. The results show that moderate ethanol substitutions (∼20% by energy) at moderate load, high percentage soy blends (60–100%), and alternative fuels (biodiesel and synthetic diesel) provide an efficiency and emissions profile that yields the most “preferred” solutions to this multicriteria engine design problem. Further research is, however, required to reduce reactive oxygen species (ROS) emissions with alternative fuels and to deliver technologies that do not significantly reduce the median diameter of particle emissions

    Application of Multicriteria Decision Making Methods to Compression Ignition Engine Efficiency and Gaseous, Particulate, and Greenhouse Gas Emissions

    No full text
    Compression ignition (CI) engine design is subject to many constraints, which present a multicriteria optimization problem that the engine researcher must solve. In particular, the modern CI engine must not only be efficient but must also deliver low gaseous, particulate, and life cycle greenhouse gas emissions so that its impact on urban air quality, human health, and global warming is minimized. Consequently, this study undertakes a multicriteria analysis, which seeks to identify alternative fuels, injection technologies, and combustion strategies that could potentially satisfy these CI engine design constraints. Three data sets are analyzed with the Preference Ranking Organization Method for Enrichment Evaluations and Geometrical Analysis for Interactive Aid (PROMETHEE-GAIA) algorithm to explore the impact of (1) an ethanol fumigation system, (2) alternative fuels (20% biodiesel and synthetic diesel) and alternative injection technologies (mechanical direct injection and common rail injection), and (3) various biodiesel fuels made from 3 feedstocks (i.e., soy, tallow, and canola) tested at several blend percentages (20–100%) on the resulting emissions and efficiency profile of the various test engines. The results show that moderate ethanol substitutions (∼20% by energy) at moderate load, high percentage soy blends (60–100%), and alternative fuels (biodiesel and synthetic diesel) provide an efficiency and emissions profile that yields the most “preferred” solutions to this multicriteria engine design problem. Further research is, however, required to reduce reactive oxygen species (ROS) emissions with alternative fuels and to deliver technologies that do not significantly reduce the median diameter of particle emissions

    Investigation of mercury emissions from burning of Australian eucalypt forest surface fuels using a combustion wind tunnel and field observations

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    Environmental cycling of the toxic metal mercury (Hg) is ubiquitous, and still not completely understood. Volatilisation and emission of mercury from vegetation, litter and soil during burning represents a significant return pathway for previously-deposited atmospheric mercury. Rates of such emission vary widely across ecosystems as they are dependent on species-specific uptake of atmospheric mercury as well as fire return frequencies. Wildfire burning in Australia is currently thought to contribute between 1 and 5% of the global total of mercury emissions, yet no modelling efforts to date have utilised local mercury emission factors (mass of emitted mercury per mass of dry fuel) or local mercury emission ratios (ratio of emitted mercury to another emitted species, typically carbon monoxide). Here we present laboratory and field investigations into mercury emission from burning of surface fuels in dry sclerophyll forests, native to the temperate south-eastern region of Australia. From laboratory data we found that fire behaviour — in particular combustion phase — has a large influence on mercury emission and hence emission ratios. Further, emission of mercury was predominantly in gaseous form with particulate-bound mercury representing\u3c1% of total mercury emission. Importantly, emission factors and emission ratios with respect to carbon monoxide and carbon dioxide, from both laboratory and field data all show that gaseous mercury emission from biomass burning in Australian dry sclerophyll forests is currently overestimated by around 60%. Based on these results, we recommend a mercury emission factor of 28.7 ± 8.1 μg Hg kg−1 dry fuel, and emission ratio of gaseous elemental mercury relative to carbon monoxide of 0.58 ± 0.01×10−7, for estimation of mercury release from the combustion of Australian dry sclerophyll litter

    The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges

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