Biomass power plant feedstock procurement: Modeling transportation cost zones and the potential for competition

Transportation of comminuted (processed) woody biomass from the production site to a utilization point is one of the most costly operational components in feedstock procurement. This study identified potential sources of feedstock based on transportation cost from which three woody biomass power plants in Humboldt County, California, could economically obtain their supply. We conducted service area and location-allocation network analyses for timberlands and sawmills, respectively, and created inclusive and exclusive networks to model three transportation cost zones (TCZs). The area within the $20/bone dry ton TCZ had the highest potential supply of woody biomass in the county (709,565 acres). All sawmills in the county were within an economically viable distance of the power plants. Even though there was no competition for raw materials at the time of this study, a competition risk analysis suggested that this could change with shifts in the demand for biomass or the price of electricity. The methods we developed for this study could be adapted to other regions with managed timberlands and a strong forest products industry

Tuning Between Quenching and Energy Transfer in DNA-Templated Heterodimer Aggregates

Molecular excitons, which propagate spatially via electronic energy transfer, are central to numerous applications including light harvesting, organic optoelectronics, and nanoscale computing; they may also benefit applications such as photothermal therapy and photoacoustic imaging through the local generation of heat via rapid excited-state quenching. Here we show how to tune between energy transfer and quenching for heterodimers of the same pair of cyanine dyes by altering their spatial configuration on a DNA template. We assemble “transverse” and “adjacent” heterodimers of Cy5 and Cy5.5 using DNA Holliday junctions. We find that the transverse heterodimers exhibit optical properties consistent with excitonically interacting dyes and fluorescence quenching, while the adjacent heterodimers exhibit optical properties consistent with nonexcitonically interacting dyes and disproportionately large Cy5.5 emission, suggestive of energy transfer between dyes. We use transient absorption spectroscopy to show that quenching in the transverse heterodimer occurs via rapid nonradiative decay to the ground state (∼31 ps) and that in the adjacent heterodimer rapid energy transfer from Cy5 to Cy5.5 (∼420 fs) is followed by Cy5.5 excited-state relaxation (∼700 ps). Accessing such drastically different photophysics, which may be tuned on demand for different target applications, highlights the utility of DNA as a template for dye aggregation

Tunable Electronic Structure via DNA-Templated Heteroaggregates of Two Distinct Cyanine Dyes

Molecular excitons are useful for applications in light harvesting, organic optoelectronics, and nanoscale computing. Electronic energy transfer (EET) is a process central to the function of devices based on molecular excitons. Achieving EET with a high quantum efficiency is a common obstacle to excitonic devices, often owing to the lack of donor and acceptor molecules that exhibit favorable spectral overlap. EET quantum efficiencies may be substantially improved through the use of heteroaggregates─aggregates of chemically distinct dyes─rather than individual dyes as energy relay units. However, controlling the assembly of heteroaggregates remains a significant challenge. Here, we use DNA Holliday junctions to assemble homo- and heterotetramer aggregates of the prototypical cyanine dyes Cy5 and Cy5.5. In addition to permitting control over the number of dyes within an aggregate, DNA-templated assembly confers control over aggregate composition, i.e., the ratio of constituent Cy5 and Cy5.5 dyes. By varying the ratio of Cy5 and Cy5.5, we show that the most intense absorption feature of the resulting tetramer can be shifted in energy over a range of almost 200 meV (1600 cm–1). All tetramers pack in the form of H-aggregates and exhibit quenched emission and drastically reduced excited-state lifetimes compared to the monomeric dyes. We apply a purely electronic exciton theory model to describe the observed progression of the absorption spectra. This model agrees with both the measured data and a more sophisticated vibronic model of the absorption and circular dichroism spectra, indicating that Cy5 and Cy5.5 heteroaggregates are largely described by molecular exciton theory. Finally, we extend the purely electronic exciton model to describe an idealized J-aggregate based on Förster resonance energy transfer (FRET) and discuss the potential advantages of such a device over traditional FRET relays

26th Annual Computational Neuroscience Meeting (CNS*2017): Part 3 - Meeting Abstracts - Antwerp, Belgium. 15–20 July 2017

This work was produced as part of the activities of FAPESP Research,\ud Disseminations and Innovation Center for Neuromathematics (grant\ud 2013/07699-0, S. Paulo Research Foundation). NLK is supported by a\ud FAPESP postdoctoral fellowship (grant 2016/03855-5). ACR is partially\ud supported by a CNPq fellowship (grant 306251/2014-0)

Biomass power plant feedstock procurement: Modeling transportation cost zones and the potential for competition

Transportation of comminuted (processed) woody biomass from the production site to a utilization point is one of the most costly operational components in feedstock procurement. This study identified potential sources of feedstock based on transportation cost from which three woody biomass power plants in Humboldt County, California, could economically obtain their supply. We conducted service area and location-allocation network analyses for timberlands and sawmills, respectively, and created inclusive and exclusive networks to model three transportation cost zones (TCZs). The area within the $20/bone dry ton TCZ had the highest potential supply of woody biomass in the county (709,565 acres). All sawmills in the county were within an economically viable distance of the power plants. Even though there was no competition for raw materials at the time of this study, a competition risk analysis suggested that this could change with shifts in the demand for biomass or the price of electricity. The methods we developed for this study could be adapted to other regions with managed timberlands and a strong forest products industry

Biomass power plant feedstock procurement: Modeling transportation cost zones and the potential for competition

Transportation of comminuted (processed) woody biomass from the production site to a utilization point is one of the most costly operational components in feedstock procurement. This study identified potential sources of feedstock based on transportation cost from which three woody biomass power plants in Humboldt County, California, could economically obtain their supply. We conducted service area and location-allocation network analyses for timberlands and sawmills, respectively, and created inclusive and exclusive networks to model three transportation cost zones (TCZs). The area within the $20/bone dry ton TCZ had the highest potential supply of woody biomass in the county (709,565 acres). All sawmills in the county were within an economically viable distance of the power plants. Even though there was no competition for raw materials at the time of this study, a competition risk analysis suggested that this could change with shifts in the demand for biomass or the price of electricity. The methods we developed for this study could be adapted to other regions with managed timberlands and a strong forest products industry

An Interactive Simulation Tool for Complex Multilayer Dielectric Devices

Novel devices incorporating multiple layers of new materials increase the complexity of device structures, particularly in field-effect transistors, capacitors, and nonvolatile memory (NVM). The mounting complexity of these devices increases the difficulty of generating energy band diagrams and performing device parameter calculations whether these calculations are done by hand, using spreadsheets, or via mathematical programs. Although finite-element Poisson-Schrodinger equation solvers are available to perform the calculations, the cost and time spent learning them can be a hindrance. A straightforward GUI interactive simulation tool is presented that quickly calculates and displays energy bands, electric fields, potentials, and charge distributions for 1-D metal-multilayered-dielectrics-semiconductor stacks. Fixed charge can be inserted into dielectric layers. The freeware program calculates device parameters, (e.g., effective oxide thickness, flat-band voltage (VFB), threshold voltage (Vt), stack capacitance) and layer parameters (e.g., capacitance, potential, electric field, tunneling distance). Calculated data can be exported. Using the simulation tool, trap-based flash NVM is examined. Device performance characteristics such as the Vt and VFB shifts of three different stacks are examined. Comparisons between the program and a finite-element Poisson-Schrodinger equation solver are performed to validate the program\u27s accuracy