Effect of a surface tension imbalance on a partly submerged cylinder

We perform a static analysis of a circular cylinder that forms a barrier between surfactant-laden and surfactant-free portions of a liquid$-$gas interface. In addition to determining the general implications of the balances for forces and torques, we quantify how the imbalance $\Delta\gamma=\gamma_a-\gamma_b$ between the uniform surface tension $\gamma_a$ of the surfactant-free portion of the interface and the uniform surface tension $\gamma_b$ of the surfactant-laden portion of the interface influences the load-bearing capacity of a hydrophobic cylinder. Moreover, we demonstrate that the difference between surface tensions on either side of a cylinder with a cross-section of arbitrary shape induces a horizontal force component $f^h$ equal to $\Delta \gamma$ in magnitude, when measured per unit length of the cylinder. With an energetic argument, we show that this relation also applies to rod-like barriers with cross-sections of variable shape. In addition, we apply our analysis to amphiphilic Janus cylinders and we discuss practical implications of our findings for Marangoni propulsion and surface pressure measurements

COARSE-GRAINED DYNAMICALLY ACCURATE SIMULATIONS OF IONIC LIQUIDS AT VACUUM-INTERFACE

Ionic liquids, possessing improved properties in many areas of technical application, are excellent candidates as components in development of next-generation technology, including ultra-high energy batteries. If they are thus applied, however, extensive interfacial analysis of any selected ionic configuration will likely be required. Molecular dynamics (MD) provides an advantageous route by which this may be accomplished, but can fall short in observing some phenomena only present at larger time/length scales than it can simulate. Often times this is approached by coarse-graining (CG), with which scope of simulation can be significantly increased. However, coarse-grained MD systems are generally known to produce inaccurately “fast” dynamics. In this work, two different sets of ionic liquid pairs are coarse-grained from atomistic MD reference systems, expanding their system size and time duration capabilities for analysis at vacuum-interface. The dynamics of each system are corrected using the novel in-house probability distribution function coarse-graining (PDF-CG) method. The bonded structure, non-bonded structure and dynamics of each system are developed and proven to match reference system data at two temperature scales. Density profile results of vacuum-interface exposure show effects of both temperature scaling and CG method, varying significantly from bulk behavior. At the interface, a density increase, cation orientations and multilayer ordering are observed

Behavior of self-propelled acetone droplets in a Leidenfrost state on liquid substrates

It is demonstrated that non-coalescent droplets of acetone can be formed on liquid substrates. The fluid flows around and in an acetone droplet hovering on water are recorded to shed light on the mechanisms which might lead to non-coalescence. For sufficiently low impact velocities, droplets undergo a damped oscillation on the surface of the liquid substrate but at higher velocities clean bounce-off occurs. Comparisons of experimentally observed static configurations of floating droplets to predictions from a theoretical model for a small non-wetting rigid sphere resting on a liquid substrate are made and a tentative strategy for determining the thickness of the vapor layer under a small droplet on a liquid is proposed. This strategy is based on the notion of effective surface tension. The droplets show self-propulsion in straight line trajectories in a manner which can be ascribed to a Marangoni effect. Surprisingly, self-propelled droplets can become immersed beneath the undisturbed water surface. This phenomenon is reasoned to be drag-inducing and might provide a basis for refining observations in previous work

The brezis-ekeland-nayroles minimization principle with mixed finite element method for elastoplastic dynamic problems

We propose a modification of the Hamiltonian formalism which can be used for dissipative systems, the Brezis-Ekeland-Nayroles principle. The formalism is specialized to the standard plasticity in small strains and dynamics. We apply it to solve the classical problem of a thin tube in plane strain subjected to an internal pressure. The continuum is discretized with mixed finite elements

The pancreatic beta cell surface proteome

The pancreatic beta cell is responsible for maintaining normoglycaemia by secreting an appropriate amount of insulin according to blood glucose levels. The accurate sensing of the beta cell extracellular environment is therefore crucial to this endocrine function and is transmitted via its cell surface proteome. Various surface proteins that mediate or affect beta cell endocrine function have been identified, including growth factor and cytokine receptors, transporters, ion channels and proteases, attributing important roles to surface proteins in the adaptive behaviour of beta cells in response to acute and chronic environmental changes. However, the largely unknown composition of the beta cell surface proteome is likely to harbour yet more information about these mechanisms and provide novel points of therapeutic intervention and diagnostic tools. This article will provide an overview of the functional complexity of the beta cell surface proteome and selected surface proteins, outline the mechanisms by which their activity may be modulated, discuss the methods and challenges of comprehensively mapping and studying the beta cell surface proteome, and address the potential of this interesting subproteome for diagnostic and therapeutic applications in human diseas

Integración LDAP con el Servicio PAPI

Sección: SolucionesEl servicio PAPI es el protocolo de autenticación que emplea la Red de Bibliotecas del CSIC para que cualquier usuario de la institución pueda acceder a los recursos electrónicos desde cualquier lugar y a cualquier hora bajo reconocimiento de usuario y contraseña. El objetivo es hacer coincidir las credenciales de acceso al Servicio PAPI con los datos que maneja el Directorio de datos de la Institución y por otro lado integrar casi de forma automática al Servicio PAPI a todas las personas que se integren en la plantilla del CSIC.N

Making machine intelligence less scary for criminal analysts: reflections on designing a visual comparative case analysis tool

A fundamental task in Criminal Intelligence Analysis is to analyze the similarity of crime cases, called CCA, to identify common crime patterns and to reason about unsolved crimes. Typically, the data is complex and high dimensional and the use of complex analytical processes would be appropriate. State-of-the-art CCA tools lack flexibility in interactive data exploration and fall short of computational transparency in terms of revealing alternative methods and results. In this paper, we report on the design of the Concept Explorer, a flexible, transparent and interactive CCA system. During this design process, we observed that most criminal analysts are not able to understand the underlying complex technical processes, which decrease the users' trust in the results and hence a reluctance to use the tool}. Our CCA solution implements a computational pipeline together with a visual platform that allows the analysts to interact with each stage of the analysis process and to validate the result. The proposed Visual Analytics workflow iteratively supports the interpretation of the results of clustering with the respective feature relations, the development of alternative models, as well as cluster verification. The visualizations offer an understandable and usable way for the analyst to provide feedback to the system and to observe the impact of their interactions. Expert feedback confirmed that our user-centred design decisions made this computational complexity less scary to criminal analysts

Visual comparative case analytics

Criminal Intelligence Analysis (CIA) faces a challenging task in handling high-dimensional data that needs to be investigated with complex analytical processes. State-of-the-art crime analysis tools do not fully support interactive data exploration and fall short of computational transparency in terms of revealing alternative results. In this paper we report our ongoing research into providing the analysts with such a transparent and interactive system for exploring similarities between crime cases. The system implements a computational pipeline together with a visual platform that allows the analysts to interact with each stage of the analysis process and to validate the result. The proposed Visual Analytics (VA) workflow iteratively supports the interpretation of obtained clustering results, the development of alternative models, as well as cluster verification. The visualizations offer a usable way for the analyst to provide feedback to the system and to observe the impact of their interaction

Lombalgie chronique, COTOREP et reclassement professionnel en Moselle

Objectifs : Décrire les caractéristiques, la prise en charge, les résultats et le coût d\u27un reclassement professionnel concernant les assurés mosellans lombalgiques chroniques bénéficiant d’un accord de la Commission technique d\u27orientation et de reclassement professionnel (COTOREP). Méthodes : Etude descriptive menée entre août 2000 et mars 2001 dans le cadre d\u27un partenariat avec la COTOREP de Moselle intégrant 48 lombalgiques chroniques pour lesquels la COTOREP a donné en 1995 un accord de pré-orientation ou de reclassement professionnels. Résultats : Le lombalgique pris en charge était un homme jeune, de faible niveau scolaire et professionnel, en rupture avec le milieu du travail et souffrant d\u27une pathologie lombaire invalidante. Sur 32 formations suivies, 24 candidats ont réussi leur examen mais seuls dix diplômés ont trouvé un emploi. Huit diplômés ont trouvé un emploi conforme à la formation apprise. Le taux de reprise du travail était semblable pour les diplômés (10/24) et pour les autres lombalgiques (11/24). Le coût global pour l\u27assurance maladie variait de 25 000 en externat à 39 000 en internat. Conclusion : Devant la faible valeur ajoutée du reclassement professionnel que nous avons constatée, il paraît souhaitable de maintenir le lombalgique chronique dans son emploi en restaurant son rachis, en aménageant son poste de travail et, surtout, en gérant ses peurs et croyances liées au couple lombalgietravail